A wood-plastic composite material board with cross-linked microporous structure and preparation method thereof

A technology of wood-plastic composite material and microporous structure, which is applied in the field of wood-plastic composite material with cross-linked microporous structure and its preparation, and can solve the problems of reduced ductility and impact resistance, limited wide use, and high material brittleness. problem, to achieve the effect of reducing the amount of plastic, not easy to age and change color, and strong wood feeling

Active Publication Date: 2017-09-29
扬州润友复合材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the use of a large amount of wood powder and other fillers in PVC wood-plastic composite materials, its ductility and impact resistance are reduced, the material is brittle, and its density is nearly twice that of traditional wood products, which limits its wide use.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] Polyvinyl chloride plastic particles 100kg, acrylic modified wood powder (particle size 100 mesh) 30kg,

[0040] Benzoic acid 0.2kg, POE-g-MAH (grafting rate 0.8%) 3kg,

[0041] PET fiber (length 3.5mm) 3kg, bis-tert-butyl peroxide cumene 0.2kg,

[0042] Azodicarbonamide 4kg, compound auxiliary blowing agent 4kg,

[0043] Triallyl isocyanurate 5kg, tribasic lead sulfate 6kg,

[0044] Dibutyl phthalate 1.1kg,

[0045] A kind of preparation method of the wood-plastic composite board material with cross-linked microporous structure of the present invention, it comprises the following steps:

[0046] (1) Weigh dichloromethane, acrylic acid, carbonyldiimidazole and wood flour at a mass ratio of 100:15:30:30, dissolve acrylic acid in dichloromethane to form an acrylic acid solution, raise the temperature of the solution to 45°C, and then Add carbonyldiimidazole dropwise to the acrylic acid solution for 45 minutes. After the dropwise addition is complete, continue the reac...

Embodiment 2

[0051] Polyvinyl chloride plastic particles 100kg, acrylic modified wood powder (particle size 80 mesh) 20kg,

[0052] Benzoic acid 0.1kg, POE-g-MAH (grafting rate 0.7%) 2kg,

[0053] PET fiber (length 1mm) 1kg, bis-tert-butyl peroxide cumene 0.1kg,

[0054] Azodicarbonamide 3kg, compound auxiliary blowing agent 2kg,

[0055] Triallyl isocyanurate 2kg, tribasic lead sulfate 4kg,

[0056] Dibutyl phthalate 0.6kg,

[0057] A kind of preparation method of the wood-plastic composite board material with cross-linked microporous structure of the present invention, it comprises the following steps:

[0058] (1) Weigh dichloromethane, acrylic acid, carbonyldiimidazole and wood flour in a mass ratio of 100:10:20:10, dissolve acrylic acid in dichloromethane to form an acrylic acid solution, raise the temperature of the solution to 40°C, and then Add carbonyldiimidazole dropwise to the acrylic acid solution for 30 minutes. After the dropwise addition is complete, continue the reactio...

Embodiment 3

[0063] Polyvinyl chloride plastic particles 100kg, acrylic modified wood flour (particle size 120 mesh) 40kg,

[0064] Benzoic acid 0.3kg, POE-g-MAH (grafting rate 0.9%) 4kg,

[0065] PET fiber (length 6mm) 6kg, bis-tert-butyl peroxide cumene 0.3kg,

[0066] Azodicarbonamide 5kg, compound auxiliary blowing agent 6kg,

[0067] Triallyl isocyanurate 8kg, tribasic lead sulfate 8kg,

[0068] Dibutyl phthalate 1.6kg,

[0069] A kind of preparation method of the wood-plastic composite board material with cross-linked microporous structure of the present invention, it comprises the following steps:

[0070] (1) Weigh dichloromethane, acrylic acid, carbonyldiimidazole and wood flour in a mass ratio of 100:20:40:50, dissolve acrylic acid in dichloromethane to form an acrylic acid solution, raise the temperature of the solution to 50°C, and then Add carbonyldiimidazole dropwise to the acrylic acid solution for 60 minutes. After the dropwise addition is complete, continue the reactio...

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Abstract

The present invention first uses acrylic acid to modify wood powder, and then polyvinyl chloride plastic particles, acrylic acid modified wood powder, benzoic acid, POE-g-MAH, PET fiber, bis-tert-butyl peroxide cumene, and azodimethyl Amide, compound auxiliary foaming agent, triallyl isocyanurate, tribasic lead sulfate and dibutyl phthalate, extruded and foamed to form a wood-plastic board with cross-linked microporous structure. The invention has the advantages of convenient production, low cost, strong wood feeling, no aging and discoloration, no warping and deformation, low density, excellent static bending strength, high impact strength, certain adsorption effect on toxic and harmful gases, stable and firm cells , will not release formaldehyde, easy to install and maintain, recyclable and environmentally friendly. It can be widely used in many occasions such as buildings, halls, home offices, etc. It can be made into door panels, photo frames, picture frames, base lines, hanging gussets, partitions, roofs and other products, and can also be used as suspended beams, rattan racks, and outdoor balconies board etc.

Description

technical field [0001] The invention relates to a plastic-wood composite material, in particular to a plastic-wood composite material plate with a cross-linked microporous structure and a preparation method thereof. Background technique [0002] Various boards are often used in homes, offices, conference rooms, laboratories and other occasions. Because people have an affinity for wood, wooden boards are often used. In order to achieve aesthetics and anti-corrosion purposes, wooden boards are often used Surface painting treatment is required. Wooden panels have some disadvantages, such as easy to shrink and crack, easy to deform when exposed to water, easy to mold when exposed to moisture, and easy to burn when exposed to fire. However, the surface paint layer of spray-painted wooden panels is easily scratched during use. It will leave scratches and affect the appearance, and the heat resistance of the paint layer is poor. If you put hot objects such as teacups with boiling w...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L27/06C08L97/02C08L51/06C08L67/02C08K13/02C08K5/09C08K5/14C08K3/30C08K5/12C08K5/3492C08J3/24C08J9/10
Inventor 徐致伟徐电友蒋霁蓓
Owner 扬州润友复合材料有限公司
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