Instantaneous vaporization and expansion of grass slices - osmotic pulping method

A technology of instant vaporization and straw flakes, which is applied to pulping with organic solvents, pulping of cellulose raw materials, and non-woody plant/crop pulping, etc. and other problems, to achieve the effect of improving the reaction rate and equilibrium conversion rate, eliminating feedback inhibition, and good bleachability

Active Publication Date: 2017-12-22
GUANGXI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In the above-mentioned prior art, although it has a better pulping rate, the raw material sodium hydroxide used has a greater impact on the environment, and the waste water after pulping is still treated in a traditional way or requires a large amount of time. Energy and funds are used to deal with it. On the one hand, it will increase the cost of wastewater treatment for enterprises, and on the other hand, it will easily pollute the environment if it is not handled well.

Method used

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  • Instantaneous vaporization and expansion of grass slices - osmotic pulping method
  • Instantaneous vaporization and expansion of grass slices - osmotic pulping method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Weigh grass slices: bagasse 100kg; organic solvent 100kg. The added sugarcane bagasse mass 0.004% surfactant Pingpingjia, 100kg of boiling water at 100°C, put Pingpingjia in boiling water and mix it for later use. Add the grass slices bagasse into the cooking pot, then add the above-mentioned weighed ethanol and evenly mix and infiltrate the bagasse, the soaking time is 10min, then add the above-mentioned 100°C boiling water with surfactant added, the boiling water flow rate is 100kg / min, so that The ethanol that penetrates into the sugarcane fiber cells instantly vaporizes and expands to destroy the cell membrane, and then passes CO into the cooking pot 2 , control reaction pressure 7.1MPa, reaction temperature 80 ℃, reaction time 0.5h, using organic solvent ethanol, surfactant Pingpingjia and supercritical CO 2 Carry out self-catalytic de-lignification between fiber cells of grass slices. During the reaction, ethanol forms steam and the water vapor generated during ...

Embodiment 2

[0035] The method steps of Example 1 were repeated with the components and process parameters specified in Table 1 below.

Embodiment 3

[0037] The method steps of Example 1 were repeated with the components and process parameters specified in Table 1 below.

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Abstract

The invention discloses a method for instantaneous vaporization and expansion inside grass slices-infiltration pulping. Soak the grass slices with an organic solvent for 5 to 120 minutes, then add boiling water at 100°C or water vapor whose temperature is higher than the boiling point of the organic solvent according to the mass ratio of the grass slices to water 1:1 to 1:20, and then under the condition of supercritical CO2 Under cooking pulping. The method of the invention causes the cell membrane to expand and rupture through the instant vaporization of the organic solvent between the fiber cells of the grass slice, so that the rate of removing intercellular lignin by cooking the grass slice is accelerated by 1-5 times, and the consumption of the organic solvent is reduced by 2-10 times.

Description

technical field [0001] The invention relates to a papermaking pulping process, in particular to a method for instantaneous vaporization expansion-infiltration pulping inside a grass slice. Background technique [0002] The total output of paper and paperboard in the world is about 400 million tons per year, and China's paper and paperboard production ranks first in the world. Paper and cardboard are mainly made of pulping, and the pulping process can be divided into: chemical method and mechanical method, as well as chemical mechanical method and semi-chemical method in between. At present, most paper mills in China use the chemical alkaline pulping method. Although the technology of the traditional pulping method is very mature, about 10 tons of black liquor is discharged for every ton of pulp produced, which not only causes waste of plant resources but also easily causes serious damage. environmental pollution problems. Therefore, the transformation and innovation of pap...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D21C3/20D21C3/22D21H11/12
Inventor 陈小鹏梁杰珍王琳琳王华生王剑南
Owner GUANGXI UNIV
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