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Polyvinyl chloride resin composition film

A technology of resin composition and polyvinyl chloride, which is applied in the field of polyvinyl chloride resin composition film, can solve the problems of insufficient low-temperature impact resistance, etc., and achieve the effect of excellent transparency and good appearance

Active Publication Date: 2016-04-20
RIKEN TECHNOS CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when the temperature of the freezer is considered, the low-temperature shock resistance is completely insufficient, and further improvement is expected.

Method used

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  • Polyvinyl chloride resin composition film
  • Polyvinyl chloride resin composition film
  • Polyvinyl chloride resin composition film

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0156] Use complexes containing:

[0157] 100 parts by mass of the above (1-1);

[0158] 35 parts by mass of the above-mentioned (2-1);

[0159] 10 parts by mass of the above (2-2);

[0160] 0.8 parts by mass of the above (3-1);

[0161] 2.0 parts by mass of the above (4-1);

[0162] Using an apparatus equipped with a uniaxial extruder and a T-die, a film having a thickness of 10 μm was produced under conditions of a maximum shear rate of 200 (1 / s) applied during film formation.

[0163] GPC measurement of the thus obtained film was performed to generate component (A). The polystyrene-equivalent molecular weight of the peak top of the component (A) in the GPC curve was 10^6.5. The value of the content of the component (A) calculated from the GPC curve by the formula described in the above paragraph 0028 was 2.8% by mass. In addition, there was no component having a peak top in a region where the polystyrene-equivalent molecular weight exceeded 10^7.0.

[0164] Furthermo...

Embodiment 7~12

[0168] Film production was performed in the same manner as in Example 1 except that the composition of the vinyl chloride-based resin composition used was changed as shown in Table 1. None of the components had a peak top in a region where the polystyrene-equivalent molecular weight exceeded 10^7.0. The results are shown in Table 1.

[0169] Table 1

[0170]

[0171] Table 2

[0172]

[0173] Symbol Description

[0174] 1: Peak of component (A)

[0175] 2: The area regarded as the content of component (A)

[0176] 3: Peak of component (B)

[0177] 4: The area regarded as the content of component (B)

[0178] 5: The position where the slope of the GPC curve is stably 0 near the polystyrene-equivalent molecular weight of 10^3.5

[0179] 6: The position where the differential molecular weight distribution curve (GPC curve) is the minimum value

[0180] 7: The position where the molecular weight in terms of polystyrene is 10^7.0 or more, and the inclination of the GP...

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Abstract

The present invention relates to a polyvinyl chloride resin composition film which has excellent self-adhesion, stretchability, transparency, and low-temperature impact resistance, has good appearance and is suitable for food packaging. A film is provided which comprises a polyvinyl chloride resin composition which includes a polyvinyl chloride resin component (A) in which polystyrene equivalent molecular weight of a differential molecular weight distribution curve measured by gel permeation chromatography has a peak top in a range of 10^6.0 to 10^7.0. This film may further include a polyvinyl chloride resin component (B) in which polystyrene equivalent molecular weight of a differential molecular weight distribution curve measured by gel permeation chromatography has a peak top in a range of 10^3.5 or more to less than 10^6.0. Furthermore, this film preferably does not include a component in which polystyrene equivalent molecular weight of a differential molecular weight distribution curve measured by gel permeation chromatography has a peak top in a range of over 10^7.0.

Description

technical field [0001] The present invention relates to polyvinyl chloride-based resin composition films. More specifically, it relates to a polyvinyl chloride-based resin composition film having excellent low-temperature impact resistance and being suitable for food packaging. Background technique [0002] Polyvinyl chloride-based resin composition films are excellent in self-adhesiveness, stretchability, and transparency, and are often used for food packaging in general households, food sales, food and beverage service, and the like. On the other hand, polyvinyl chloride-based resin composition films have a disadvantage of insufficient low-temperature impact resistance. Therefore, the low-temperature impact resistance is improved according to the type and compounding amount of the plasticizer contained in the polyvinyl chloride-based resin composition (for example, refer to paragraph 0015 of Patent Document 1). However, when the temperature of the freezer is considered, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J5/18C08L27/06
CPCC08J5/18C08J2327/06
Inventor 岩仓和彦佐藤真澄堀井贵央
Owner RIKEN TECHNOS CORP