Method for realizing textile intelligent cleaning function through crosslinking temperature-sensitive copolymer

A technology of copolymers and textiles, which is applied in the field of textile intelligent cleaning functions, can solve the problems such as the difficulty in realizing the hydrophilic/hydrophobic properties of textile materials, and achieve the effect of enhanced self-cleaning function and convenient operation

Active Publication Date: 2016-07-27
ZHEJIANG SCI-TECH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since hydrophilic / hydrophobic properties are opposite to each other, it is not easy to achieve both hydrophilic / hydrophobic properties of textile materials in actual production applications.

Method used

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  • Method for realizing textile intelligent cleaning function through crosslinking temperature-sensitive copolymer
  • Method for realizing textile intelligent cleaning function through crosslinking temperature-sensitive copolymer
  • Method for realizing textile intelligent cleaning function through crosslinking temperature-sensitive copolymer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] A method of realizing the intelligent cleaning function of textiles by cross-linking temperature-sensitive copolymers in this embodiment. The percentages mentioned in this example are all solution mass percentages. Utilize the contained hydroxyl group of temperature-sensitive copolymer and pure cotton fabric, can react with the characteristic of carboxyl group contained in citric acid, temperature-sensitive copolymer is fixed on the surface of pure cotton fabric by cross-linking reaction, comprises the following steps: 1) weigh certain Quantity of untreated cotton fabric, P(MEO 2 MA 136 -co-EGMA 24 ) molecular formula 2%, 2% citric acid, 3% sodium hypophosphite, and 10% water are soaked in 1,4-dioxane solution; 2) Take out the pure cotton fabric; 3) Put it in an oven and bake it at 130°C for 1min; 4) Take out the pure cotton fabric from the oven, wash it with clean water, dry it, weigh it, and its weight gain rate is 2.76%; 5) Soak the prepared pure cotton fabric i...

Embodiment 2

[0035] A method of realizing the intelligent cleaning function of textiles by cross-linking temperature-sensitive copolymers in this embodiment. The percentages mentioned in this example are all solution mass percentages. Utilize the contained hydroxyl group of temperature-sensitive copolymer and pure cotton fabric, can react with the characteristic of carboxyl group contained in citric acid, temperature-sensitive copolymer is fixed on the surface of pure cotton fabric by cross-linking reaction, comprises the following steps: 1) weigh certain Quantity of untreated cotton fabric, P(MEO 2 MA 136 -co-EGMA 24 ) molecular formula 4%, 2% citric acid, 3% sodium hypophosphite, and 10% water soaked in 1,4-dioxane solution; 2) Take out the pure cotton fabric, dipping and rolling twice; 3) Place it in a 60°C Bake in an oven at 130°C for 1 min; 4) Take out the pure cotton fabric from the oven, wash it with clean water, dry it, and weigh it, the weight gain rate is 3.53%; 5) Put the p...

Embodiment 3

[0037] A method of realizing the intelligent cleaning function of textiles by cross-linking temperature-sensitive copolymers in this embodiment. The percentages mentioned in this example are all solution mass percentages. Utilize the contained hydroxyl group of temperature-sensitive copolymer and pure cotton fabric, can react with the characteristic of carboxyl group contained in citric acid, temperature-sensitive copolymer is fixed on the surface of pure cotton fabric by cross-linking reaction, comprises the following steps: 1) weigh certain Quantity of untreated cotton fabric, P(MEO 2 MA 136 -co-EGMA 24 ) molecular formula 8%, citric acid 2%, sodium hypophosphite 3%, water 10% soaked in 1,4-dioxane solution; 2) take out the pure cotton fabric, dipping and rolling twice; 3) put it in an oven at 130 ℃ for 1 min; 4) Take out the pure cotton fabric from the oven, rinse it with clear water, dry and weigh it, and the weight gain rate is 4.62%; 5) Put the prepared pure cotton ...

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Abstract

The invention discloses a method for realizing a textile intelligent cleaning function through a crosslinking temperature-sensitive copolymer. The method comprises the following steps of (1) using the temperature-sensitive copolymer, a crosslinking agent, a catalyst and a solvent to process a textile; (2) carrying out crosslinking reaction on the processed textile through heating and baking. According to the method for realizing thetextile intelligent cleaning function through the crosslinking temperature-sensitive copolymer provided by the invention, the cleaning efficiency of the textile during the washing process is improved, and the self-cleaning effect is achieved during the wearing process; the operation can be carried out conveniently without influencing the original whiteness and flexibility; a covalent bond is formed through reaction of a reactive functional group contained in an acrylate monomer with the reactive functional group at the tail end of a side chain in the temperature-sensitive copolymer and a reactive functional group on the surface of the textile with carboxyl contained in the crosslinking agent, and the temperature-sensitive copolymer is fixed on the surface of the textile, so that the modified textile has a function of hydrophily/hydrophobicity intelligent adjustment.

Description

technical field [0001] The invention relates to a method for realizing the intelligent cleaning function of textiles through a cross-linked temperature-sensitive copolymer. Specifically, it refers to cross-linking temperature-sensitive copolymers on the surface of textiles, using the characteristics that temperature-sensitive copolymers can independently undergo hydrophilic / hydrophobic transitions according to changes in the external environment temperature, so as to achieve a temperature lower than the transition temperature (TT) of the temperature-sensitive copolymers. ), such as in the textile washing process, the copolymer is in a hydrophilic state, and the textile has an excellent cleaning effect; when the temperature is higher than TT, such as in the daily wearing process, the copolymer is in a hydrophobic state, and the textile has a good self-cleaning effect, Therefore, the function of intelligently adjusting the performance of textiles according to different external ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M11/70D06M15/263D06M13/207D06M15/285D06M13/203D06M13/252D06M101/06D06M101/12D06M101/10
CPCD06M11/70D06M13/203D06M13/207D06M13/252D06M15/263D06M15/285D06M2101/06D06M2101/10D06M2101/12
Inventor 钟齐管淑琳陈杨轶王际平
Owner ZHEJIANG SCI-TECH UNIV
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