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A device and method for recovering lithium from scrap lithium batteries

A lithium battery and lithium recovery technology, applied in the field of lithium recovery devices, can solve the problems of low energy consumption, long time consumption, complex process and the like

Active Publication Date: 2017-12-19
贵州中伟资源循环产业发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This process is relatively simple, but it consumes a lot of energy and produces a lot of waste gas, so strict air filtration standards are required
The hydrometallurgy method first uses mechanical methods to break the metal shell of the battery, and then adopts methods such as leaching, precipitation, ion exchange, and adsorption to obtain metal compounds. The recovered metals have high purity and low energy consumption, and are widely used. A method for separating and recovering metal ions, but the process is complicated
The bioleaching method is gradually replacing the hydrometallurgical method due to its advantages of high efficiency, low cost, less industrial demand, and environmental friendliness, but this method takes a long time and bacteria are difficult to cultivate

Method used

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  • A device and method for recovering lithium from scrap lithium batteries

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Embodiment Construction

[0016] The present invention is specifically described below by the embodiment, only for further illustrating the present invention, can not be interpreted as the limitation of protection scope of the present invention, the technical engineer of this field can make some non-essential improvements and improvements to the present invention according to the content of the above-mentioned invention Adjustment.

[0017] like figure 1 Shown, the cobalt ion of the present invention (Co 2+ ), copper ions (Cu2+ ), aluminum ions (Al 3+ ), iron ions (Fe 3+ ) and lithium ions (Li + ) The separation equipment mainly lies in the design of the separation membrane. Here, an enlarged view of the separation membrane is shown. As shown in the figure, the surface of the separation membrane 1 is micro-machined, and countless micro-channels 11 are etched (the channel size can be controlled between 10um and 100um, because the channel pressure is proportional to the -4th power of the pore diamet...

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Abstract

The invention discloses a device and method for recovering lithium from a scrap lithium battery. The device comprises a separating membrane, multiple micron channels uniform in orientation are formed in the separating membrane, the diameter of the micron channels is 10-100 micrometers, a stock solution region communicated with inlet ends of the micron channels is arranged at one side of the separating membrane, a separating region communicated with the outlet ends of the micron channels is arranged at the other side of the separating membrane, a section of anion-exchange membrane is arranged on the inner wall of each micron channel, and the outer surfaces of the anion-exchange membranes are communicated with cavities of the micron channels; a first electrode is arranged at the side, opposite to the stock solution region, of the separating membrane, a second electrode is arranged at the side, opposite to the separating region, of the separating membrane, the first electrode and the second electrode are used for generating field intensity covering the portion from the separating region to the stock solution region in the field intensity direction of the micron channels, and a third electrode is arranged on each anion-exchange membrane. The device has the advantages that only the hundred-micron order pore diameter requirement needs to be met, and operation pressure and manufacturing difficulty are reduced, so that separating cost is reduced, and the device is beneficial for industry popularization.

Description

technical field [0001] The invention belongs to the technical field of metal ion separation and treatment, and in particular relates to a device and method for recovering lithium from scrap lithium batteries. Background technique [0002] With the development of science and technology, electronic products have penetrated into every corner of people's lives. Compared with nickel-cadmium batteries and nickel-hydrogen batteries, lithium-ion batteries have the advantages of small size, light weight, high working voltage, high volume and mass specific energy, no memory effect, small self-discharge, wide operating temperature range, and long life. Already dominated the small portable electronics market. For example: communication phones, cameras, portable notebooks, etc. With the continuous development of society and the emergence of climate, energy and environmental issues, lithium-ion batteries have been widely used in the field of electric vehicles. [0003] In 2013, among t...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M10/54C22B7/00C22B26/12
CPCC22B7/00C22B26/12H01M10/54Y02P10/20Y02W30/84
Inventor 李子瑞刘伟朱育丹
Owner 贵州中伟资源循环产业发展有限公司
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