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A kind of porous composite catalyst material for air purification and preparation method thereof

A technology of composite catalysts and porous catalysts, applied in physical/chemical process catalysts, chemical instruments and methods, metal/metal oxide/metal hydroxide catalysts, etc. complex and other issues, to achieve the effect of improving synergistic catalytic effect, large and controllable doping amount, and simple preparation process

Active Publication Date: 2019-11-22
UCHEER PURIFICATION & POLLUTION CONTROL TECH ZHEJIANG CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, physical adsorption technology mainly uses porous materials or solvents for adsorption, and its treatment capacity is limited and it is difficult to achieve the purpose of eradication.
Photocatalytic oxidation technology uses the oxidation-reduction reaction on the surface of titanium dioxide under photocatalytic conditions to achieve the purpose of degrading VOC pollutants. There are three problems in this method: one is the ultraviolet light in the process of catalytic reaction. The utilization efficiency is limited, the second is that the material itself is easily deactivated during the reaction process, and the third is that the condition that light is always needed during the reaction process is difficult to apply under indoor conditions
The above-mentioned impregnation doping is to adsorb doping substances after the product is formed, and can only rely on surface adsorption to adsorb a small amount of doped metal ions to its surface, the doping effect is limited, and deep doping at the lattice level cannot be achieved.
Moreover, the synthesis process for generating doped catalysts is complicated and the impregnation time is long.

Method used

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  • A kind of porous composite catalyst material for air purification and preparation method thereof
  • A kind of porous composite catalyst material for air purification and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Weigh 2.5g of copper sulfate pentahydrate and 43.1g of manganese nitrate hexahydrate and add water to form a 5280g mixed solution, and stir evenly to obtain a mixed solution, add 60g of mesoporous silica material to it, and stir at 20r / min at 0°C After reacting for 300 minutes, the porous catalyst material precursor material was obtained by filtration for use. Mix the above-mentioned porous catalyst material precursor material with 31.6g potassium permanganate and add water to configure a 6800g mixed solution and stir evenly, and transfer the above-mentioned mixed reaction solution to an 8L closed reaction kettle with a filling degree of 85%, and heat up to 100 react at ℃ for 20h, wash and filter, and dry at 50℃ for 30h to obtain a porous composite catalyst material product.

[0037] SEM tested, see figure 2 , indicating that the prepared porous composite catalyst material is a rod-like nanoscale porous material, the nanorod size range is 50-200nm, and the pore size r...

Embodiment 2

[0040] Weigh 3.4g of copper chloride dihydrate and 6.8g of manganese sulfate monohydrate and add water to form a 5100g mixed solution, and stir evenly to obtain a mixed solution, add 40.8g of mesoporous alumina material to it, at 99°C at 900r / min Stir the reaction for 10 minutes, and filter to obtain the precursor material of the porous catalyst material for use. Mix the above-mentioned porous catalyst material precursor material with 31.6g potassium permanganate and add water to configure a 5600g mixed solution and stir evenly, and transfer the above-mentioned mixed reaction solution to an 8L closed reaction kettle with a filling degree of 70% and heat up to 150 react at ℃ for 5 hours, wash and filter, and dry at 200 ℃ for 2 hours to obtain a porous composite catalyst material product.

[0041] SEM tested, see figure 2 , indicating that the prepared porous composite catalyst material is a rod-like nanoscale porous material, the nanorod size range is 50-200nm, and the pore s...

Embodiment 3

[0044] Weigh 25g of copper sulfate pentahydrate and 9.9g of manganese chloride tetrahydrate and add water to form a 5632g mixed solution, and stir evenly to obtain a mixed solution, add 48g of molecular sieve material to it, stir and react at 1200r / min for 200min at 30°C, filter The porous catalyst material precursor material is obtained for use. Mix the above-mentioned porous catalyst material precursor material with 23.7g potassium permanganate and add water to configure a 7500g mixed solution and stir evenly, and transfer the above-mentioned mixed reaction solution to a 10L closed reaction kettle with a filling degree of 75%, and heat up to 200 react at 100°C for 1 hour, wash and filter, and dry at 100°C for 12 hours to obtain a porous composite catalyst material product.

[0045] SEM tested, see figure 2 , indicating that the prepared porous composite catalyst material is a rod-like nanoscale porous material, the nanorod size range is 50-200nm, and the pore size range is...

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Abstract

The invention provides an air purifying porous composite catalyst material and a preparation method thereof. The preparation method comprises the following steps: adding an inorganic porous material in a mixed solution of Mn II salt and Cu II salt, heating, fully stirring and carrying out adsorption reaction, and filtering to obtain a porous catalyst material precursor; and mixing the porous catalyst material precursor with an oxidizing agent, reacting in a reactor at high temperature under high pressure, cleaning, filtering and drying to obtain the porous composite catalyst material. The preparation process is simple, and the cost is low; the doping level is high, and fibrous manganite of which crystal lattices are horizontally doped with metal ions can be obtained; and by a high-temperature and quenching process, a large number of cracks are formed in particles, specific surface area is large, the number of active sites is large, and catalysis reactivity is high.

Description

technical field [0001] The invention relates to the field of environmental protection and air purification materials, in particular to an air purification porous composite catalyst material and a preparation method thereof. Background technique [0002] Among the current outstanding air pollution problems, the volatile harmful gases in it seriously endanger human health. The harmful volatile organic compounds in the air are referred to as VOC (Volatile organic compounds), including benzene, toluene, ethylbenzene, xylene, benzene Ethylene, propylene glycol, ethane, phenols, formaldehyde, etc. VOC in the air has great harm to human health, some have stimulating effect on human body, some have poisonous effect on human body, easily cause acute and chronic poisoning of human body, and some have carcinogenic effect or gene mutation effect. When in a room where VOC reaches a certain concentration, there will be symptoms such as nausea, vomiting, fatigue and headache in a short pe...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/889B01D53/86B01D53/44
CPCB01D53/8687B01D2257/708B01J23/002B01J23/8892B01J2523/00B01J2523/17B01J2523/72B01J2523/41B01J2523/31
Inventor 黄建国王康肖鸽
Owner UCHEER PURIFICATION & POLLUTION CONTROL TECH ZHEJIANG CO LTD