A kind of porous composite catalyst material for air purification and preparation method thereof
A technology of composite catalysts and porous catalysts, applied in physical/chemical process catalysts, chemical instruments and methods, metal/metal oxide/metal hydroxide catalysts, etc. complex and other issues, to achieve the effect of improving synergistic catalytic effect, large and controllable doping amount, and simple preparation process
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Embodiment 1
[0036] Weigh 2.5g of copper sulfate pentahydrate and 43.1g of manganese nitrate hexahydrate and add water to form a 5280g mixed solution, and stir evenly to obtain a mixed solution, add 60g of mesoporous silica material to it, and stir at 20r / min at 0°C After reacting for 300 minutes, the porous catalyst material precursor material was obtained by filtration for use. Mix the above-mentioned porous catalyst material precursor material with 31.6g potassium permanganate and add water to configure a 6800g mixed solution and stir evenly, and transfer the above-mentioned mixed reaction solution to an 8L closed reaction kettle with a filling degree of 85%, and heat up to 100 react at ℃ for 20h, wash and filter, and dry at 50℃ for 30h to obtain a porous composite catalyst material product.
[0037] SEM tested, see figure 2 , indicating that the prepared porous composite catalyst material is a rod-like nanoscale porous material, the nanorod size range is 50-200nm, and the pore size r...
Embodiment 2
[0040] Weigh 3.4g of copper chloride dihydrate and 6.8g of manganese sulfate monohydrate and add water to form a 5100g mixed solution, and stir evenly to obtain a mixed solution, add 40.8g of mesoporous alumina material to it, at 99°C at 900r / min Stir the reaction for 10 minutes, and filter to obtain the precursor material of the porous catalyst material for use. Mix the above-mentioned porous catalyst material precursor material with 31.6g potassium permanganate and add water to configure a 5600g mixed solution and stir evenly, and transfer the above-mentioned mixed reaction solution to an 8L closed reaction kettle with a filling degree of 70% and heat up to 150 react at ℃ for 5 hours, wash and filter, and dry at 200 ℃ for 2 hours to obtain a porous composite catalyst material product.
[0041] SEM tested, see figure 2 , indicating that the prepared porous composite catalyst material is a rod-like nanoscale porous material, the nanorod size range is 50-200nm, and the pore s...
Embodiment 3
[0044] Weigh 25g of copper sulfate pentahydrate and 9.9g of manganese chloride tetrahydrate and add water to form a 5632g mixed solution, and stir evenly to obtain a mixed solution, add 48g of molecular sieve material to it, stir and react at 1200r / min for 200min at 30°C, filter The porous catalyst material precursor material is obtained for use. Mix the above-mentioned porous catalyst material precursor material with 23.7g potassium permanganate and add water to configure a 7500g mixed solution and stir evenly, and transfer the above-mentioned mixed reaction solution to a 10L closed reaction kettle with a filling degree of 75%, and heat up to 200 react at 100°C for 1 hour, wash and filter, and dry at 100°C for 12 hours to obtain a porous composite catalyst material product.
[0045] SEM tested, see figure 2 , indicating that the prepared porous composite catalyst material is a rod-like nanoscale porous material, the nanorod size range is 50-200nm, and the pore size range is...
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