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Composite glass fibers and preparation method thereof

A glass fiber and pretreatment technology, applied in the field of glass fiber, can solve the problems of poor wear resistance and popularization and use

Inactive Publication Date: 2017-02-15
安徽金生金世电子科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the poor abrasion resistance of currently commercially available glass fibers limits its widespread use

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] (1) Place 1 glass fiber with a volume length of 65 μm in 1.1 volume concentration of 0.05 mol / L hypochlorous acid solution, and heat it at 65°C for 20 minutes to carry out oxidation treatment;

[0020] (2) soak 1 volume of the glass fiber after oxidation treatment in 2 volumes of silane coupling agent with a temperature of 40° C. and a volume concentration of 25% for 1 hour, then filter, wash, and dry to obtain pretreated glass fibers;

[0021] (3) 2 parts by weight of pretreated glass fiber and 1 part by weight of polylactic acid were mixed and heated at 155° C. for 35 minutes to prepare composite glass fiber A1.

Embodiment 2

[0023] (1) Place 1 glass fiber with a volume length of 78 μm in a hypochlorous acid solution with a volume concentration of 0.05 mol / L, and heat at 83°C for 28 minutes to perform oxidation treatment;

[0024] (2) soak 1 volume of the glass fiber after oxidation treatment in 5 volumes of silane coupling agent with a volume concentration of 43% and a temperature of 65°C for 1.8 hours, then filter, wash, and dry to obtain pretreated glass fibers;

[0025] (3) 5 parts by weight of pretreated glass fiber and 1 part by weight of polylactic acid were mixed and heated at 170° C. for 55 minutes to prepare composite glass fiber A2.

Embodiment 3

[0027] (1) Put a glass fiber with a volume length of 72 μm in a hypochlorous acid solution with a volume concentration of 0.1mol / L, and heat it at 70°C for 25 minutes to perform oxidation treatment;

[0028] (2) soak 1 volume of the glass fiber after oxidation treatment in 3 volumes of silane coupling agent with a temperature of 55° C. and a volume concentration of 35% for 1.5 hours, then filter, wash, and dry to obtain pretreated glass fibers;

[0029] (3) Mix 2 parts by weight of pretreated glass fiber with 1 part by weight of polylactic acid and heat at 160° C. for 45 minutes to prepare composite glass fiber A3.

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Abstract

The invention discloses a preparation method of composite glass fibers. The method comprises the following steps: (1) putting glass fibers in hypochlorous acid solution to be heated and then carrying out oxidation treatment; (2) soaking the glass fibers subjected to the oxidation treatment in a silane coupling agent to obtain pretreated glass fibers; (3) mixing the pretreated glass fibers with polylactic acid and heating to obtain the composite glass fibers, wherein the lengths of the glass fibers are 65-80 mum; the volume concentration of the silane coupling agent is 25 to 45%. The composite glass fibers prepared through the method are high in toughness and large in elongation, and capable of reaching a wear resistant effect.

Description

technical field [0001] The invention relates to glass fibers, in particular to composite glass fibers and a preparation method thereof. Background technique [0002] Glass fiber is an inorganic non-metallic material with excellent performance. There are many kinds of it. It has good insulation, strong heat resistance, good corrosion resistance and high mechanical strength. Glass fiber is made of glass balls or waste glass through high-temperature melting, wire drawing, winding, weaving and other processes. The diameter of its single filament is several microns to more than 20 microns. All are composed of hundreds or even thousands of monofilaments. The glass fiber is often used as reinforcing material of composite material, electrical insulation and heat insulation materials, substrate and other national economy fields. However, the poor wear resistance of currently commercially available glass fibers limits its popularization. Contents of the invention [0003] One of ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B26/18C04B20/10
CPCC04B20/1051C04B26/18C04B14/42C04B20/023C04B20/006
Inventor 倪伟
Owner 安徽金生金世电子科技有限公司
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