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A kind of method of powder sintering preparation Al-SN base bearing alloy

A powder and alloy technology, which is applied in the field of Al-Sn-based bearing alloy preparation, can solve the problems of easy water absorption, high hardness of nanocrystalline powder, difficult bonding strength, etc., and achieve the effect of high activity and large specific surface area

Active Publication Date: 2018-01-02
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are two main problems in the Al-Sn alloy obtained by casting: (1) the strength of the alloy (HV30~50) is low, and it is difficult to meet the current demand for high strength of the bearing bush; (2) it is easy to serious problems such as gravity segregation
However, for Al-Sn-based bearing alloys, cast aluminum-tin-based ingots are mainly used in the industry, and then compounded with steel backs to form bearing strips. The easy oxidation of the powder leads to poor sintering performance between powder and powder, powder and steel back, and poor bonding strength, and there are four problems produced during the industrial application of Al-Sn-based bearing alloys prepared by mechanical alloying. Insufficient technology: (1) nanocrystalline powder has high hardness and poor fluidity, and it is difficult to combine with steel back rolling; (2) because Al powder particles are easy to oxidize, it is difficult to use hot rolling method, and at the same time, it is difficult to obtain cold rolling with steel back High bonding strength; (3) The surface of Al powder particles is easy to absorb water, and more air bubbles are generated during the composite rolling process, which seriously affects the bonding strength between the alloy layer and the steel back; (4) If the cold rolling Al powder and steel back are co-solidified and sintered at high temperature (above 500°C), and it is easy to form Al-Fe hard and brittle phase at the interface
The above problems, on the one hand, show that powder sintering of Al-based alloys faces many challenges, and the aluminum alloys commonly used in industry are mostly prepared by casting methods;

Method used

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  • A kind of method of powder sintering preparation Al-SN base bearing alloy
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  • A kind of method of powder sintering preparation Al-SN base bearing alloy

Examples

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Comparison scheme
Effect test

Embodiment 1

[0046] (1) The silicon powder with a particle size of 40-200 mesh and a purity of 99.5% is refined by a plasma discharge-assisted ball mill under the protection of argon, the discharge current is 1.5A, the ball milling time is 4h, and the abrasive ratio is 50:1 ; The surface morphology of the obtained Si powder is as follows figure 1 shown.

[0047] (2) the particle size is 200 orders, the aluminum powder that is 99.5% of purity, Si powder and the Si powder after step (1) process are mixed evenly by Al-12%Sn-2.5%Si mass percent, adopt under argon protection QM-2SP planetary ball mill is used for ball milling, the ball milling speed is 350rpm / min, the ball milling time is 40h, and the ball-to-material ratio is 15:1 to obtain nanocrystalline Al-12%Sn-2.5%Si alloy powder;

[0048] (3) taking by weighing 4g of the nanocrystalline Al-Sn alloy powder gained in step (1) and packing it into a mold with a diameter of 24mm, using a universal hydraulic material testing machine to pre-pr...

Embodiment 2

[0053] (1) The silicon powder with a particle size of 40-200 mesh and a purity of 99.5% is refined by a plasma discharge-assisted ball mill under the protection of argon, the discharge current is 1.5A, the ball milling time is 4h, and the abrasive ratio is 50:1 ; The surface morphology of the obtained Si powder is as follows figure 1 shown.

[0054] (2) the particle size is 200 orders, the aluminum powder that is 99.5% of purity, Si powder and the Si powder after step (1) process are mixed evenly by Al-12%Sn-2.5%Si mass percent, adopt under argon protection QM-2SP planetary ball mill is used for ball milling, the ball milling speed is 350rpm / min, the ball milling time is 40h, and the ball-to-material ratio is 15:1 to obtain nanocrystalline Al-12%Sn-2.5%Si alloy powder;

[0055] (3) taking 4g of the nanocrystalline Al-Sn alloy powder gained in step 1 and packing it into a mold with a diameter of 24mm, and using a universal hydraulic material testing machine to pre-press into a...

Embodiment 3

[0061] The procedure of this example is basically the same as that of Example 2, except that the cold-rolled alloy block is subjected to recrystallization annealing at 400°C, the heating rate is 3°C / min, the holding time is 1h, and it is cooled with the furnace to obtain sample 3. , the surface morphology is shown in Figure 5(c), and the fracture morphology is shown in Figure 6(c).

[0062] Test its mechanical properties: the density of the alloy is 99.3%, the hardness is 80HV, the tensile strength is 233MPa, and the elongation is 3.5%.

[0063] The performance characterization results of the Al-Sn-based bearing alloy prepared in this example are shown in Table 1.

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Abstract

The invention discloses a method for preparing an Al-Sn-based bearing alloy by powder sintering. Raw powders such as Al and Sn and powders such as pretreated Si are mixed according to a certain weight percentage, and then processed by ball milling to obtain Al-Sn-based bearing alloys. Si nanocrystalline alloy powder, the above alloy powder is prepared by "pre-cold pressing + sintering + cold rolling + recrystallization annealing" process to prepare a fully dense Al-Sn-based bearing alloy. The Al-Sn-based bearing alloy prepared by the invention has a dual-scale structure, that is, micron coarse-grained Al phases are distributed in an ultra-fine-grained Al matrix, and the dual-scale structure has the controllability of strength and plasticity. The invention solves the key problems such as difficulty in sintering and non-densification produced during the industrial application of powder sintered Al-Sn-based bearing alloys and bearing bush strips, and easily realizes industrial production.

Description

technical field [0001] The invention relates to a preparation method of an Al-Sn-based bearing bush alloy, in particular to a method for preparing an Al-Sn-based bearing bush alloy by powder sintering. Background technique [0002] With the rapid development of transportation equipment such as high-speed railways, light rails, subways and ships, as well as the trend of high compression ratio, compact design and weight reduction of engines, not only the application range of bearing alloys (such as Cu-based, Al-based, etc.) has been significantly expanded, It also puts forward higher requirements for its bearing capacity and tribological properties. Moreover, the European Union has banned the use of lead in engine bearings for light vehicles since July 1, 2011. This regulation has brought extensive changes to automotive bearing alloys and bearing coatings. Although there are no similar regulations for heavy-duty engines, it is only a matter of time. Therefore, it is an urgen...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C1/04C22C21/00C22F1/04B22F3/02B22F3/10B22F3/24B22F1/00
CPCC22C1/0416C22C21/003C22F1/04B22F3/02B22F3/1007B22F3/24B22F2003/248B22F2998/10B22F1/14B22F1/0003
Inventor 朱敏曾美琴鲁忠臣胡仁宗宋凯强
Owner SOUTH CHINA UNIV OF TECH
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