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Treatment method of sulfur-containing waste gas

A treatment method and exhaust gas technology, applied in separation methods, chemical instruments and methods, and dispersed particle separation, etc., can solve problems such as high operating costs, complicated processes, and calcium sulfate consumption, and achieve investment saving, device investment saving, and huge social benefit effect

Active Publication Date: 2020-02-07
CHINA PETROLEUM & CHEM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The process is complicated and requires consumption of calcium sulfate, carbon-based reducing agents, etc., and the operation cost of the device is relatively high

Method used

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  • Treatment method of sulfur-containing waste gas

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] process such as figure 1 As shown, the sulfur recovery unit flue gas 1 (temperature is 315 ° C, SO 2 The content is 500mg / m 3 , O 2 Content is 3.2%) and S Zorb regeneration flue gas 2 (temperature is 125 ℃, SO 2 The content is 3.5%, O 2 The content is 3.8%) respectively into the catalytic cracking unit through the pipeline, mixed with the regeneration air 3 of the catalytic cracking unit introduced by the blower, and then introduced into the charred tank 4. In the coke tank 4, the catalytic cracking catalyst reacts with oxygen at a high temperature of 680°C to burn the catalyst and realize the regeneration of the catalyst. At the same time, the oxygen in the flue gas 1 of the sulfur recovery unit and the flue gas 2 of the S Zorb regeneration is reacted, The remainder contains SO 2 The gas is regenerated with the catalytic cracking flue gas, and the catalyst particles are separated through the cyclone separator provided in the regenerator 5 . The regenerated flue g...

Embodiment 2

[0029] process such as figure 1 As shown, the sulfur recovery unit flue gas 1 (temperature is 280 ℃, SO2 The content is 150mg / m 3 , O 2 Content is 5%) and S Zorb regeneration flue gas 2 (temperature is 160 ℃, SO 2 The content is 5%, O 2 content of 5%) are respectively introduced into the catalytic cracking unit through the pipeline, mixed with the regeneration air 3 of the catalytic cracking unit introduced by the blower, and then introduced into the charred tank 4. In the coke tank 4, the catalytic cracking catalyst reacts with oxygen at a high temperature of 720°C to burn the catalyst and realize the regeneration of the catalyst. At the same time, the oxygen in the flue gas 1 of the sulfur recovery unit and the flue gas 2 of the S Zorb regeneration is reacted, The remainder contains SO 2 The gas is regenerated with the catalytic cracking flue gas, and the catalyst particles are separated through the cyclone separator provided in the regenerator 5 . The regenerated flue ...

Embodiment 3

[0032] process such as figure 1 As shown, the flue gas 1 of the sulfur recovery unit (at a temperature of 350°C, SO 2 The content is 800mg / m 3 , O 2 Content is 2%) and S Zorb regeneration flue gas 2 (temperature is 110 ℃, SO 2 The content is 2%, O 2 content of 0.2%) are respectively introduced into the catalytic cracking unit through the pipeline, mixed with the regeneration air 3 of the catalytic cracking unit introduced by the fan, and then introduced into the charred tank 4. In the coke tank 4, the catalytic cracking catalyst reacts with oxygen at a high temperature of 650°C to burn the catalyst and realize the regeneration of the catalyst. At the same time, the oxygen in the flue gas 1 of the sulfur recovery unit and the flue gas 2 of the S Zorb regeneration is reacted, The remainder contains SO 2 The gas is regenerated with the catalytic cracking flue gas, and the catalyst particles are separated through the cyclone separator provided in the regenerator 5 . The rege...

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Abstract

The invention relates to a sulfur-containing waste gas treatment method, and belongs to the technical field of petrochemical waste gas treatment. The sulfur-containing waste gas treatment method comprises the following steps: one or both of sulfur recovery device flue gas and S Zorb regenerated flue gas and catalytic cracking device regenerated air are introduced into a regeneration unit of the above catalytic cracking device and undergo a charring reaction, unreacted SO2-containing gas and flue gas produced by the charring reaction sequentially undergo separation and heat exchange and enter a desulfurization and denitration unit in the catalytic cracking unit in order to obtain purified tail gas, and the purified tail gas is discharged. The method relies on a present apparatus to realize treatment of SO2-containing waste gas, especially sulfur device flue gas and the S Zorb regenerated flue gas, and has the advantages of low investment, low operating cost, and realization of environmental protection, standard reaching and waste gas treatment.

Description

technical field [0001] The invention relates to a treatment method for sulfur-containing waste gas, which belongs to the technical field of petrochemical waste gas treatment. Background technique [0002] SO 2 It is one of the most important environmental pollutants and the main cause of acid rain. SO 2 It can destroy the physiological functions of plants, slow down the growth of crops and forests, and the human body can inhale high concentrations of SO 2 Gas, will have a strong stimulating effect on the respiratory tract, so SO 2 As the main air pollutant emission control technology has been widely valued. In recent years, SO 2 The discharge has caused 40% of my country's land area to be harmed by acid rain, and the annual loss caused by it is as high as 110 billion yuan. According to the current emission control level, by 2020, the SO emissions from the petroleum refining industry 2 It will reach 126993t / a. Therefore, control pollution, reduce SO 2 Emissions are a...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D53/86B01D53/50
Inventor 宫超赵日峰达建文徐翠翠刘爱华刘剑利
Owner CHINA PETROLEUM & CHEM CORP