A method for adjusting carbon-alkali material balance in alumina production process

A production process and material balance technology, applied in the direction of alumina/hydroxide, etc., can solve the problems of reducing the decomposition rate of seeds, failure to find carbon and alkali for recycling, and unfavorable production of carbon and alkali, so as to reduce production costs and save raw materials The effect of spending

Active Publication Date: 2018-05-29
中铝中州铝业有限公司 +1
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Problems solved by technology

The carbonation decomposition process will produce a large amount of carbon mother liquor. Usually, the above two methods cannot effectively solve the problem of carbon mother recycling, which directly restricts the improvement of the carbonation decomposition production capacity of the sintering method.
[0003] In the Bayer process system of beneficiation, a large amount of carbon soda is not conducive to production, especially it will reduce the decomposition rate of seeds. Therefore, in the evaporation and salt removal process, the carbon soda and a small amount of other sodium salts in the process will leave the system in the form of salt discharge filter cake. This part of carbon soda has not yet found an effective way to recycle it

Method used

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Effect test

Embodiment 1

[0023] Introducing CO into the sintered carbon master 2 , after the caustic alkali concentration was reduced to 0, the aeration was continued for 0.5 hours, and the alumina concentration in the solution decreased to 0.65 g / L. A plate and frame filter is used for primary filtration, and the filtrate is left to cool in a liquid storage tank for 30 hours. During this process, the residual alumina in the solution is gradually precipitated in the form of dawsonite. A filter bucket is used for secondary filtration, and the content of alumina in the secondary filtrate is 12 mg / L, and the content of other metal elements does not exceed the content of the alkaline water used in the current grinding and floating system. The pH value is determined to be 10.33, and the total alkali concentration is 101.3g / L. In the secondary filtrate, liquid caustic soda was added to make it react completely with the sodium bicarbonate in the solution. At the same time, the pH value of the solution was a...

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Abstract

The invention relates to a method for recycling carbon and alkali systematically during production of aluminum oxide, in particular to a method for adjusting balance of carbon-alkali materials in a production technology of the aluminum oxide. The method is characterized by sequentially including the steps that 1, CO2 gas is injected into sintering method carbonated mother liquor, in this way, caustic alkali in the sintering method carbonated mother liquor completely reacts with CO2, CO2 gas is injected into a solution, and then the aluminum oxide is sufficiently separated out; 2, slurry which the CO2 gas is injected into is filtered one time, filtrate stands and is cooled, and remaining aluminum oxide in the filtrate and other metal ions are further separated out and precipitate; secondary filtering is carried out, the pH value of secondary filtrate is determined, and chemical components of the solution are analyzed; 4, sodium hydroxide or solid sodium hydroxide is added into the secondary filtrate to obtain the pH value of the solution through blending so that requirements for alkaline water used for ore dressing can be met; 5, after the pH value is qualified through blending, the secondary filtrate is delivered to a floatation process of an ore dressing Bayer method.

Description

technical field [0001] A method for adjusting the material balance of carbon and alkali in an alumina production process relates to a method for recycling carbon and alkali in a system in the alumina production process. Background technique [0002] The carbon alkali in the sintering production system mainly comes from the carbon separation mother liquor. At present, the circulation route is that a part of the clinker is dissolved, and a part is returned to the ingredients after evaporation. The carbonation decomposition process will produce a large amount of carbon separation mother liquor. Usually, the above two methods cannot effectively solve the problem of carbon mother recycling, which directly restricts the improvement of the carbonation decomposition capacity of the sintering method. [0003] In the beneficiation Bayer process system, the presence of a large amount of carbon and alkali is not conducive to production, especially it will reduce the decomposition rate ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01F7/02
CPCC01F7/02
Inventor 白琳张占明黄昂刘占强卫星王素敏王永平侯国峰杨威李青云冯承志郭东峰陈军王庆玲
Owner 中铝中州铝业有限公司
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