Method for adjusting balance of carbon-alkali materials in production technology of aluminum oxide

A production process and material balance technology, applied in the direction of alumina/aluminum hydroxide, etc., can solve the problems of reducing the decomposition rate of seeds, failure to find carbon and alkali for recycling, and unfavorable production of carbon and alkali, so as to save raw material expenses and reduce production cost effect

Active Publication Date: 2017-05-31
中铝中州铝业有限公司 +1
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Problems solved by technology

The carbonation decomposition process will produce a large amount of carbon mother liquor. Usually, the above two methods cannot effectively solve the problem of carbon mother recycling, which directly restricts the improvement of the carbonation decomposition production capacity of the sintering method.
[0003] In the Bayer process system of beneficiation, a large amount of carbon soda is not conducive to production, especially it will reduce the decomposition rate of seeds. Therefore, in the evaporation and salt removal process, the carbon soda and a small amount of other sodium salts in the process will leave the system in the form of salt discharge filter cake. This part of carbon soda has not yet found an effective way to recycle it

Method used

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Examples

Experimental program
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Effect test

Embodiment 1

[0023] Introduce CO into sintered carbon mother 2 After the concentration of caustic soda drops to 0, the aeration is continued for 0.5 hours, and the concentration of alumina in the solution drops to 0.65 g / L. Filtrate once through a plate and frame filter, and the filtrate is left to cool in the liquid storage tank for 30 hours. During this process, the residual alumina in the solution is gradually precipitated in the form of frasonite. Use the filter barrel to carry out secondary filtration, analyze the aluminum oxide content in the secondary filtrate to be 12mg / L, and the content of other metal elements is not more than the content of alkaline water used in the current mill-floating system. The measured pH value is 10.33, and the total alkali concentration is 101.3g / L. In the secondary filtrate, liquid caustic soda is added to make it react completely with the sodium bicarbonate in the solution, while the pH value of the solution is adjusted to 11.37, and the total alkali...

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Abstract

The invention relates to a method for recycling carbon and alkali systematically during production of aluminum oxide, in particular to a method for adjusting balance of carbon-alkali materials in a production technology of the aluminum oxide. The method is characterized by sequentially including the steps that 1, CO2 gas is injected into sintering method carbonated mother liquor, in this way, caustic alkali in the sintering method carbonated mother liquor completely reacts with CO2, CO2 gas is injected into a solution, and then the aluminum oxide is sufficiently separated out; 2, slurry which the CO2 gas is injected into is filtered one time, filtrate stands and is cooled, and remaining aluminum oxide in the filtrate and other metal ions are further separated out and precipitate; secondary filtering is carried out, the pH value of secondary filtrate is determined, and chemical components of the solution are analyzed; 4, sodium hydroxide or solid sodium hydroxide is added into the secondary filtrate to obtain the pH value of the solution through blending so that requirements for alkaline water used for ore dressing can be met; 5, after the pH value is qualified through blending, the secondary filtrate is delivered to a floatation process of an ore dressing Bayer method.

Description

technical field [0001] The invention discloses a method for adjusting carbon-alkali material balance in an alumina production process, and relates to a method for systemic carbon-alkali recycling in the alumina production process. Background technique [0002] The carbon base in the sintering production system mainly comes from the carbon mother liquor. At present, its circulation path is to remove a part of the clinker for dissolution, and a part returns to the ingredients after evaporation. The carbonation decomposition process will produce a large amount of carbon mother liquor. Usually, the above two methods cannot effectively solve the problem of carbon mother recycling, which directly restricts the improvement of the carbonation decomposition production capacity of the sintering method. [0003] In the Bayer process system of beneficiation, a large amount of carbon soda is not conducive to production, especially it will reduce the decomposition rate of seeds. Therefor...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01F7/02
CPCC01F7/02
Inventor 白琳张占明黄昂刘占强卫星王素敏王永平侯国峰杨威李青云冯承志郭东峰陈军王庆玲
Owner 中铝中州铝业有限公司
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