A kind of modifier for complex heavy metal polluted soil and its preparation and use method

A heavy metal-contaminated soil and amendment technology, applied in the restoration of polluted soil, chemical instruments and methods, applications, etc., can solve the problems of high greenhouse gas emissions, change of soil structure, high energy consumption of cement, etc., and achieve good durability , reduce contact, enhance the effect of curing effect

Active Publication Date: 2020-08-11
SOUTHEAST UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Commonly used modifiers mainly include materials such as cement, lime, and phosphate, which have a good effect on the solidification and stabilization of heavy metals, but there are also a large number of disadvantages, such as high energy consumption for cement production and high greenhouse gas emissions; lime and phosphate are Non-renewable natural minerals, high cost, etc.; and a large amount of phosphate will seriously change the soil structure and further cause phosphorus pollution of groundwater and surface water

Method used

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  • A kind of modifier for complex heavy metal polluted soil and its preparation and use method
  • A kind of modifier for complex heavy metal polluted soil and its preparation and use method
  • A kind of modifier for complex heavy metal polluted soil and its preparation and use method

Examples

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Embodiment 1

[0027] The present invention is applicable to the modifier of composite heavy metal polluted soil, and consists of the following materials in parts by mass: 45% of steel slag powder; 35% of calcium superphosphate powder; and 20% of biochar loaded with phosphate.

[0028] The steel slag powder is activated steel slag powder prepared by the following method: the converter slag is subjected to magnetic separation and then crushed and sieved; among the obtained products, materials with a particle size of less than 2mm are placed in an oven and dried by air flow at a temperature of 105°C until the water content is 1%; the obtained product is ground and passed through a 200-mesh sieve, and then calcined in an electric furnace at 700° C. for 2 hours. The basicity value of the steel slag powder is 2.07.

[0029] The main components and content of the steel slag are shown in Table 1. It should be noted that the steel slag applicable to the present invention is not limited to the data i...

Embodiment 2

[0041] The preparation process and curing process are the same as in Example 1, except that the dosage of the modifier is 10% (the modifier accounts for the dry weight of the heavy metal and organic compound polluted soil).

Embodiment 3

[0043] The preparation process and curing process are the same as in Example 1, except that the dosage of the modifier is 15% (the modifier accounts for the dry weight of the heavy metal and organic compound polluted soil).

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Abstract

The invention discloses an ameliorant for compound heavy metal polluted soil and preparation and an application method thereof. The ameliorant is composed of the following materials (by weight): 30-55% of steel slag powder, 20-50% of calcium superphosphate powder and 5-30% of phosphate-loaded biochar. The invention has the following advantages: firstly, the ameliorant can remarkably reduce mobility and toxicity leaching content of heavy metal in heavy metal polluted soil and is especially applicable to acidic pollution sites with high content of heavy metal and various kinds of pollutants; after the polluted soil is ameliorated, resource utilization of the soil as an environment-friendly material can be achieved, and the environmental risk of secondary development and utilization of the pollution sites is remarkably reduced; the raw materials of the ameliorant are easily available; cost is low; and the ameliorant is simple to prepare and convenient to use, has stable effects, and can be promoted and applied at large scale in solidification and stabilization restoration of composite pollution sites.

Description

technical field [0001] The invention relates to the field of environmental geotechnical engineering, in particular to a modifier for composite heavy metal polluted soil and a preparation and use method. Background technique [0002] With the adjustment of urban functions and urban layout in our country, enterprises originally located in urban centers and suburbs, such as chemical plants, metal smelting plants, and electroplating plants, have gradually shut down or retreated from cities to parks. However, the production process of industries and enterprises for many years , A large amount of pollutants have accumulated in the land left after their relocation, which not only brings resistance to the efficient use of the leftover land, but also brings serious safety hazards to the surrounding environment. In recent years, the "Soil Pollution Prevention and Control Action Plan" (Soil Ten Articles) promulgated by the government also regards the restoration of contaminated soil as...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K17/08B09C1/08C09K109/00
CPCB09C1/08C09K17/08C09K2109/00
Inventor 冯亚松杜延军夏威夷伍浩良李凯
Owner SOUTHEAST UNIV
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