Polymeric plasticizer compositions

A technology of composition and plasticizer, which is applied in the field of plasticized polymer composition and manufacture of the polymer plasticizer composition, can solve the problems that plasticizer is not easy to leach or evaporate, and is not suitable for health or environment

Inactive Publication Date: 2017-08-01
RESINATE MATERIALS GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Importantly, these plasticizers do not readily leach or evaporate from the plasticized polymer and do not pose undue health or environmental concerns

Method used

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  • Polymeric plasticizer compositions
  • Polymeric plasticizer compositions
  • Polymeric plasticizer compositions

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0187] Example 1: General Procedure for Preparation of Polymeric Plasticizer Compositions

[0188] Polymeric plasticizer compositions were made using the general procedure described below.

[0189] Procedure when the source of aromatic acid is an aromatic diacid or ester or anhydride

[0190] Aromatic acid source, dihydric alcohol and C 4 -C 36 The monocarboxylic acid or its ester or anhydride was charged into a 4 neck round bottom flask reactor which was then placed in a heating mantle connected to a temperature controller. Connect the nitrogen inlet, thermocouple, and mechanical stirrer to the reactor. The reaction was carried out at 189-250°C under a nitrogen purge. When the appropriate acidity was reached by sampling and measuring the acid ester, the reaction was terminated and property studies were performed.

[0191] Procedure: Aromatic polyester or polycarbonate as aromatic acid source

[0192]A solid polymeric thermoplastic polyester such as PET is used as ...

Embodiment 2

[0219] Example 2: Plasticized polyvinyl chloride polymer composition

[0220] Plasticized polymer compositions are made using the polymeric plasticizer compositions of the present invention and the desired polymers using standard manufacturing techniques.

[0221] The plasticized polymers can be used, for example, as rubber substitutes and have applications in fields including cable insulation, flooring, coatings, pipes, intumescent products and artificial leather.

[0222] The formulations below are examples of plasticized polymer compositions that can be used for wire and cable coatings.

[0223] Plasticized polymer formulations for wire and cable applications

[0224] Polyvinyl chloride (PVC) resin: 100PHR

[0225] Polymeric plasticizer of the present invention: 35PHR

[0226] Additional low molecular weight plasticizer: 30PHR

[0227] Ca / Zn: 4.5PHR

[0228] Stearic acid: 0.2PHR

[0229] Calcined clay: 12PHR

[0230] Antimony oxide: 3PHR

[0231] In the above fo...

Embodiment 3

[0245] Example 3: Plasticized polyethylene terephthalate (PET) composition

[0246] 100 grams each of the PET pellets and the polymeric plasticizer composition 6 described in Example 1 were charged into a 500 mL 4 necked round bottom flask. The mixture was placed under a nitrogen atmosphere and heated at a temperature of 220°C with slow stirring until the particles were completely dissolved. The temperature of the reaction mixture was cooled to 200°C and poured into a Teflon pan to form an opaque tan material.

[0247]

[0248]

[0249] incorporated by reference

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Abstract

The present invention relates to polymeric plasticizer compositions made from an aromatic acid source, a glycol, and a C4 - C36 monocarboxylic acid, or ester or anhydride thereof. The aromatic acid source can include polymeric materials such as recycled polyethylene terephthalate (PET). The present invention also relates to methods for making the polymeric plasticizer compositions, to methods of plasticizing polymeric materials, and to plasticized polymeric compositions. The polymeric plasticizers are useful for plasticizing various polymers, such as thermoplastic polymers, including, for example, polyvinyl chloride (PVC). The polymeric plasticizers provide a sustainable alternative to conventional phthalate ester plasticizers, such as diisooctyl phthalate (DOP).

Description

[0001] related application [0002] This application claims priority to U.S. Provisional Patent Application Serial No. 62 / 072,074, filed October 29, 2014, and U.S. Provisional Patent Application Serial No. 62 / 099,930, filed January 5, 2015, the publications of each of said provisional applications The entire contents are incorporated herein by reference. technical field [0003] The present invention relates to aromatic acid source, dihydric alcohol and C 4 -C 36 Polymeric plasticizer compositions of monocarboxylic acids or their esters or anhydrides. The aromatic acid source may comprise a polymeric material such as recycled polyethylene terephthalate (PET). The invention also relates to methods for making said polymeric plasticizer compositions, methods of plasticizing polymeric materials and plasticized polymeric compositions. The polymeric plasticizers are useful for plasticizing a variety of different polymers such as thermoplastic polymers including, for example, pol...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08K5/00C08K5/12C08K5/092C08K5/09C08K5/05
CPCC08K5/0016C08K5/05C08K5/09C08K5/092C08L27/06C08L67/02C08G63/46C08G63/916
Inventor 乌-圣·白瑞克·塔波尔凯文·安东尼·罗杰斯沙克蒂·L·慕克吉
Owner RESINATE MATERIALS GRP
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