Multifunctional high-strength composite fabric coating agent, coating, and preparation method and application of multifunctional high-strength composite fabric coating agent
A composite fabric, multi-functional technology, applied in the field of materials, can solve the problems of wear resistance, high strength, waterproof and moisture permeability, achieve good burst resistance, suitable for large-scale promotion and application, and enhance the effect of bonding force
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[0047] In some embodiments, the preparation method includes: adding the enhancer, synergist, and solvent into the reactor at a mass ratio of 1:0.025-2.5:20-50 and reacting at 20-100°C for 1- After 10 hours, after the reaction product is cooled, the solid matter is separated (for example, by vacuum filtration, etc.) and dried at room temperature for 10-30 hours, and then milled and sieved to finally obtain a reinforcing agent with active groups on the surface.
[0048] In some embodiments, the synergist includes a silane coupling agent and / or a polymer compound. Since the reinforcing agent has undergone surface modification treatment, it has -OH, -NH 3 and other active functional groups, which enhance the binding force between the coating and the fabric, thereby greatly improving the strength of the coating compared with the prior art.
[0049] Preferably, the silane coupling agent includes 3-aminopropyltrimethoxysilane, γ-(2,3-glycidoxy)propyltriethoxysilane, γ-methacryloxypr...
Embodiment 1
[0067] (1) Add 9g nanometer tungsten carbide (particle size about 200nm), 22.5g 3-aminopropyltrimethoxysilane and 450g ethanol into the reaction kettle and react at 100°C for 10h. After the reaction product is cooled, filter it under reduced pressure The product was dried at room temperature for 30 h, then milled and sieved to obtain a surface with a large amount of -NH 3 nano tungsten carbide.
[0068] (2) Weigh 15 g of polyurethane resin and 30 g of xylene respectively in a 250 mL beaker, and stir for 40 min with a magnetic stirrer at 1500 rpm.
[0069] (3) add 9g surface to have a large amount of-NH in the dispersion liquid that step (2) makes 3 Nano-tungsten carbide, 7.5g isophorone, 6g sodium lauryl sulfate, 4.5g dodecyl alcohol ester, 6g pentaerythritol fatty acid ester, 4.5g nano-zinc oxide, then stirred with a magnetic stirrer at 2000rpm for 20min to obtain a stable The dispersion liquid, promptly obtains described multifunctional high-strength composite fabric coati...
Embodiment 2
[0073] (1) Add 2g of black gemstone (particle size about 50nm), 0.5g of polyacrylic acid and 90g of deionized water into the reactor and react at 60°C for 2 hours. After the reaction product is cooled, filter the product under reduced pressure and dry it at room temperature 14h, followed by grinding and sieving to finally obtain black gemstones with a large amount of -COOH on the surface;
[0074] (2) Weigh 20g of polyacrylic resin, 50g of n-butanol and 50g of xylene in a 250mL beaker respectively, and stir for 45min with a magnetic stirrer at 1500rpm;
[0075] (3) Add 2g of black gemstone with a large amount of -COOH on the surface, 0.3g of octyltriethoxysilane, 0.20g of polyacrylamide, 0.15g of ethylene glycol monopropylene to the dispersion liquid prepared in step (2). Ether, 3g of triethanolamine ammonium stearate, 1g of nano-copper oxide, and then stirred with a 2000rpm magnetic stirrer for 20min to obtain a stable dispersion, that is, to obtain the multifunctional high-s...
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