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Preparation method of damp-proof PVC injection molding material

A technology of injection molding and muscovite, which is applied in the field of moisture-proof PVC injection molding preparation. It can solve the problems of damp, dull and rough surface of wires, and affect production speed, etc., and achieve the effect of good softness and smooth and delicate surface of the product.

Inactive Publication Date: 2018-02-27
ZHEJIANG WELLSCOM PLASTIC CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] PVC cable material is easy to get damp. The surface of the wire made of damp cable material is dull, rough and dull. There are many honeycomb pores on the surface and cross-section of the wire, which greatly reduces the mechanical properties and insulation properties of the wire.
Before using the damp cable material, it needs to be dried, which adds a process, which not only affects the production speed, but also wastes manpower and energy
Conventional PVC insulating materials are usually filled with ordinary calcium carbonate. The surface of insulating cable particles made of ordinary calcium carbonate looks uneven and has pinhole-like gaps under a microscope. These gaps are very easy to absorb water vapor, which leads to moisture.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A preparation method for moisture-proof PVC injection molding, comprising the following steps:

[0026] a) Muscovite modification: mix muscovite with absolute ethanol 0.3 times the weight of muscovite, and PVP 0.1 times the weight of muscovite, and add them together to a high-speed shearing machine for 0.5 hours, and calcined at 550 ° C for 0.5 hours after cooling Prepare the exfoliated muscovite; mix the exfoliated muscovite with a titanate coupling agent 0.5 times the weight of the exfoliated muscovite and perform ultrasonic treatment for 1 hour to obtain the modified muscovite;

[0027] b) Ingredients: 80 parts of PVC resin, 20 parts of PE resin, 120 parts of modified muscovite, 25 parts of composite rubber, 2 parts of fluidity modifier, 10 parts of plasticizer, 5 parts of lubricant, and 6 parts of heat stabilizer The weight portion proportioning weighs each component; Composite rubber comprises the component of following weight percentage, nitrile rubber 35wt%, EPDM...

Embodiment 2

[0031] A preparation method for moisture-proof PVC injection molding, comprising the following steps:

[0032] a) Muscovite modification: mix muscovite with absolute ethanol 0.4 times the weight of muscovite, and PVP 0.13 times the weight of muscovite, and add them together to a high-speed shearing machine for 0.7 hours, and calcined at 560 ° C for 0.6 hours after cooling Prepare the exfoliated muscovite; mix the exfoliated muscovite with a titanate coupling agent 0.6 times the weight of the exfoliated muscovite and perform ultrasonic treatment for 1.2 hours to obtain a modified muscovite;

[0033] b) Ingredients: 82 parts of PVC resin, 25 parts of PE resin, 125 parts of modified muscovite, 27 parts of composite rubber, 2.2 parts of fluidity modifier, 10.5 parts of plasticizer, 5.5 parts of lubricant, and 6.5 parts of heat stabilizer The weight portion proportioning weighs each component; Composite rubber comprises the component of following weight percentage, nitrile rubber 3...

Embodiment 3

[0037] A preparation method for moisture-proof PVC injection molding, comprising the following steps:

[0038] a) Muscovite modification: mix muscovite with absolute ethanol 0.45 times the weight of muscovite, and PVP 0.15 times the weight of muscovite, and add them together to a high-speed shearing machine for 1.0 hour, and calcined at 575 ° C for 0.75 hours after cooling Prepare the exfoliated muscovite; mix the exfoliated muscovite with a titanate coupling agent 0.75 times the weight of the exfoliated muscovite and perform ultrasonic treatment for 1.5 hours to obtain the modified muscovite;

[0039] b) Ingredients: 85 parts of PVC resin, 30 parts of PE resin, 130 parts of modified muscovite, 27.5 parts of composite rubber, 2.5 parts of fluidity modifier, 11 parts of plasticizer, 6 parts of lubricant, 7 parts of heat stabilizer The weight ratio of each component is weighed; the compound rubber comprises the following components in weight percentage, 37.5wt% of nitrile rubber...

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Abstract

The invention belongs to the technical field of preparation of cable injection molding materials, and discloses a preparation method of a damp-proof PVC injection molding material. The preparation method comprises the steps of white mica modification, dosing, mixing, granulating and the like, wherein the white mica modification comprises the following steps: mixing the white mica with absolute ethyl alcohol which being 0.3-0.6 time of the white mica in weight and PVP which being 0.1-0.2 time of the white mica in weight, adding into a high-speed shearing machine, and treating for 0.5-1.5 hours;calcining for 0.5-1 hour at 550-600 DEG C, and cooling to obtain peeling white mica; mixing the peeling white mica with a titanate coupling agent which being 0.5-1.0 time of the peeling white mica inweight, and performing ultrasonic treatment for 1-2 hours to obtain modified white mica. According to the preparation method disclosed by the invention, the prepared damp-proof PVC injection moldingmaterial has the characteristics of moisture and damp proofing, smooth and delicate surface, relatively high softness, etc.

Description

technical field [0001] The invention relates to the technical field of cable injection molding, in particular to a method for preparing moisture-proof PVC injection molding. Background technique [0002] PVC cable material is easy to get damp. The surface of the wire made of damp cable material is dull and rough. There are many honeycomb pores on the surface and cross-section of the wire, which greatly reduces the mechanical properties and insulation properties of the wire. Before using the damp cable material, it needs to be dried, which adds a process, which not only affects the production speed, but also wastes manpower and energy. Conventional PVC insulating materials are usually filled with ordinary calcium carbonate. The surface of insulating cable particles made of ordinary calcium carbonate looks uneven and has pinhole-like gaps under a microscope. These gaps are very easy to absorb water vapor, which leads to moisture. Contents of the invention [0003] In order ...

Claims

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Application Information

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IPC IPC(8): C08L27/06C08L23/06C08L9/02C08L23/16C08L83/04C08L11/00C08K13/06C08K9/04C08K3/34C08K5/12C08K5/098C08K5/09
CPCC08L27/06C08L2205/02C08L2205/035C08L23/06C08L9/02C08L23/16C08L83/04C08L11/00C08K13/06C08K9/04C08K3/34C08K5/12C08K5/098C08K5/09
Inventor 李晓东余立峰赵亚琼
Owner ZHEJIANG WELLSCOM PLASTIC CO LTD
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