Lubricating oil composition, method for defoaming lubricating oil, and defoaming agent composition
A technology of lubricating oil composition and defoaming agent, which is applied in the direction of lubricating composition, chemical instrument and method, separation method, etc. It can solve problems such as increased foaming, oil film rupture, poor oil pressure control, etc., and achieves inhibition of separation and sedimentation , The effect of suppressing the decline of defoaming performance
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manufacture example 1~3
[0214] (Measurement of average particle diameter of defoamer (A1))
[0215] In the following production examples, regarding the average particle diameter of the defoaming agent (A1), the dynamic light scattering method measuring device Photal ELSZ-0 (manufactured by Otsuka Electronics Co., Ltd.) was used to dilute the dispersion polymerization liquid with mineral oil. The sample (25° C.) was measured, and based on the measured result, it was calculated by cumulative analysis.
manufacture example 1
[0217] Antifoaming agent A corresponding to the first antifoaming agent (A1) was produced by dispersion polymerization in the following procedure.
[0218] Mineral oil (40° C. Kinematic viscosity when: 8.9mm 2 / s) 30 parts by mass, 3 parts by mass of KF2012 (methacrylate modified polydimethylsiloxane, produced by Shin-Etsu Chemical Industry Co., Ltd., functional group equivalent of 4,600 g / mol) as a defoamer monomer, and ethylene glycol 0.15 parts by mass of alcohol dimethacrylate and 1.5 parts by mass of polyalkylmethacrylate (weight-average molecular weight Mw=320,000) as a polymer dispersant were prepared into a homogeneous solution under stirring, and then a diaphragm pump was used to implement 5 parts by mass. Vacuum degassing and nitrogen purging of the secondary reaction system. Under nitrogen flow, PEROCTA O (1,1,3,3-tetramethylbutyl peroxy-2-ethylhexanoate: 1,1,3,3-tetramethylbutyl peroxy- 2-Ethylhexanoate, peroxide-based radical polymerization initiator, produced ...
manufacture example 2
[0220] Change the defoamer monomer to X22-2426 (methacrylate modified polydimethylsiloxane, produced by Shin-Etsu Chemical Co., Ltd., functional group equivalent 12,000g / mol) 3 parts by mass and ethylene glycol dimethyl Except having changed the quantity of a polymer dispersing agent into 0.06 mass part 0.15 mass parts of acrylates, it carried out similarly to manufacture example 1, and produced the defoamer B equivalent to the 1st defoamer (A1) by dispersion polymerization. The obtained antifoaming agent polymer had an average particle diameter of 0.5 μm.
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