Negative electrode active material for nonaqueous electrolyte secondary batteries and negative electrode
A negative electrode active material, non-aqueous electrolyte technology, applied in non-aqueous electrolyte battery electrodes, non-aqueous electrolyte batteries, active material electrodes and other directions, can solve the problem of low charging and discharging efficiency, and achieve the effect of inhibiting capacity reduction
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Embodiment 1
[0079] [Production of negative electrode active material]
[0080] The preparation included equimolar amounts of Si and Li 2 SiO 3 (average primary particle diameter of composite particles: 10 μm, average primary particle diameter of Si: 100 nm). As a result of measuring the amount of Si in the composite particles using ICP (manufactured by SII NanoTechnology Inc., ICP emission spectrometer SPS3100), it was 42 wt%. The average primary particle diameter of the particles is a value measured using a particle size distribution meter (manufactured by Shimadzu Corporation, particle size distribution analyzer SLAD2000). The cross-section of the composite particles was observed by SEM, and it was confirmed that the Si particles in the Li 2 SiO 3 roughly evenly dispersed in the phase.
[0081] By mixing 3-aminopropyltriethoxysilane and pure water (mass ratio 50:50), and then standing for more than 1 day, a 3-aminopropyltriethoxysilane solution (hereinafter SC solution) was prepare...
Embodiment 2
[0085] The negative electrode slurry a2 and the slurry package A2 were produced under the same conditions as in Example 1 except that the composite particles and the SC solution were mixed at a mass ratio of 100:2. In the negative electrode active material of Example 2, the content of 3-aminopropyltriethoxysilane was 1% by mass based on the composite particles.
Embodiment 3
[0087] The negative electrode slurry a3 and the slurry package A3 were produced under the same conditions as in Example 1 except that the composite particles and the SC solution were mixed at a mass ratio of 100:4. In the negative electrode active material of Example 3, the content of 3-aminopropyltriethoxysilane was 2% by mass based on the composite particles.
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Abstract
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