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Citric acid aluminum-plastic composite packaging material separating agent as well as preparation and application method thereof

A composite packaging material, aluminum citrate technology, applied in the direction of plastic recycling, recycling technology, process efficiency improvement, etc., can solve the problems of high volatility of the separating agent, human and atmospheric hazards, etc. Simple, easy-to-use effects

Inactive Publication Date: 2018-05-29
SHAANXI UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The separating agent realizes the separation of aluminum-plastic composite packaging materials, and solves the technical problem that the existing separating agent is highly volatile and causes harm to the human body and the atmosphere; the preparation method is simple and the operation is convenient; the separating agent has no irritating volatile substances during use Formation, the separation agent has a wide temperature range, and the aluminum-plastic separation effect is good

Method used

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  • Citric acid aluminum-plastic composite packaging material separating agent as well as preparation and application method thereof
  • Citric acid aluminum-plastic composite packaging material separating agent as well as preparation and application method thereof
  • Citric acid aluminum-plastic composite packaging material separating agent as well as preparation and application method thereof

Examples

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Effect test

Embodiment 1

[0035] A citrate-aluminum-plastic composite packaging material separating agent in this embodiment is a citric acid solution prepared at a concentration of 3 mol / L at 85° C.; wherein the solute of the citric acid solution is citric acid, and the solvent is water.

[0036] The use method of the present invention is: add 1 kg of aluminum-plastic composite packaging material into the reactor, add 3 L of separating agent, put it into a constant temperature shaking reactor at 95°C, completely separate the plastic from the aluminum foil after 420 minutes, and separate the separated plastic and Wash the aluminum foil in clean water, dry and weigh it, and calculate its recovery rate p and loss rate p 1 .

[0037] Recovery rate p and loss rate p 1 Calculated as follows:

[0038]

[0039] p 1 =1-p

[0040] Among them, p is the recycling rate of aluminum and plastic; m 0 is the mass of aluminum-plastic before reaction; m 1 is the mass of aluminum foil after reaction; m 2 is the...

Embodiment 2

[0043] A citric acid separating agent for aluminum-plastic composite packaging materials in this embodiment is a citric acid solution with a concentration of 4 mol / L prepared at 88° C., wherein the solute of the citric acid solution is citric acid, and the solvent is water.

[0044] The method of use of the present invention is as follows: add 1kg of aluminum-plastic composite packaging material into the reactor, add 5L of separating agent, put it into a constant temperature oscillating reactor at 90°C, and after 387 minutes, the plastic and aluminum foil are completely separated, and the separated plastic and Wash the aluminum foil in clean water, dry and weigh it, and calculate its recovery rate p and loss rate p 1 .

[0045] Recovery rate p and loss rate p 1 Calculated as follows:

[0046]

[0047] p 1 =1-p

[0048] Among them, p is the recycling rate of aluminum and plastic; m 0is the mass of aluminum-plastic before reaction; m 1 is the mass of aluminum foil after...

Embodiment 3

[0051] A citric acid separating agent for aluminum-plastic composite packaging materials in this embodiment is a citric acid solution with a concentration of 5 mol / L prepared at 92° C., wherein the solute of the citric acid solution is citric acid, and the solvent is water.

[0052] The method of use of the present invention is: add 1 kg of aluminum-plastic composite packaging material into the reactor, add 8 L of separating agent, put it into a constant temperature oscillating reactor at 85°C, and after 343 minutes, the plastic and aluminum foil are completely separated, and the separated plastic and Wash the aluminum foil in clean water, dry and weigh it, and calculate its recovery rate p and loss rate p 1 .

[0053] Recovery rate p and loss rate p 1 Calculated as follows:

[0054]

[0055] p 1 =1-p

[0056] Among them, p is the recycling rate of aluminum and plastic; m 0 is the mass of aluminum-plastic before reaction; m 1 is the mass of aluminum foil after reactio...

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Abstract

The invention discloses a citric acid aluminum-plastic composite packaging material separating agent as well as a preparation and an application method thereof, which belongs to the technical field ofseparation of composite materials. The separating agent adopts citric acid as a solute and water as a solvent to prepare a citric acid solution with a concentration of 3 to 6 mol / L, the separating agent aids in the complete separation of the aluminum-plastic composite packaging material and is not volatile and is harmless to the atmosphere and human body, the separation of the aluminum-plastic composite packaging material is realized, and the technical problems that the existing separating agent is high in volatility and harmful to the human body and the atmosphere can be solved. The preparation method comprises the following steps: dissolving the citric acid in the water at 85 to 95 DEG C, wherein the method is simple, and the operation is convenient. The application method comprises thefollowing steps: (1) placing the aluminum-plastic composite packaging material into the separating agent; and (2) oscillating at a constant temperature of 85 to 95 DEG C until the aluminum-plastic composite packaging material is separated into aluminum and plastics. In the application process, no irritating volatile substance is generated, the application temperature range of the separating agentis wide, and the aluminum-plastic separating effect is good.

Description

technical field [0001] The invention belongs to the technical field of composite material separation, and in particular relates to a citrate-aluminum-plastic composite packaging material separation agent and a preparation and use method thereof. Background technique [0002] Aluminum-plastic composite packaging material is a multi-layer material composed of aluminum foil and plastic. Because of its excellent light-proof, gas-blocking and anti-corrosion properties, it is widely used in the packaging of food, cosmetics and daily necessities. However, at present, the main methods of recycling aluminum-plastic composite packaging materials in my country are landfill and incineration. When landfilling, aluminum foil will cause soil heavy metal pollution, plastic degradation is difficult, will destroy the soil geology of the area, and affect the ecological balance; and aluminum-plastic composite materials are prone to produce dioxin gas when incinerated, which is carcinogenic to t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J11/06C22B7/00C22B21/00
CPCC08J11/06C08J2323/06C22B7/006C22B21/0023Y02P10/20Y02W30/62
Inventor 张素风雷丹刘叶钱立伟孙洁轩候晨张璐璐修慧娟
Owner SHAANXI UNIV OF SCI & TECH
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