Unlock instant, AI-driven research and patent intelligence for your innovation.
A kind of preparation method of water glass curing agent
What is Al technical title?
Al technical title is built by PatSnap Al team. It summarizes the technical point description of the patent document.
A technology of curing agent and water glass, applied in the field of preparation of water glass curing agent, can solve the problems of poor durability and low strength of consolidated body
Active Publication Date: 2020-10-30
浙江盛捷包装科技有限公司
View PDF5 Cites 0 Cited by
Summary
Abstract
Description
Claims
Application Information
AI Technical Summary
This helps you quickly interpret patents by identifying the three key elements:
Problems solved by technology
Method used
Benefits of technology
Problems solved by technology
[0009] The technical problem to be solved by the present invention: Aiming at the problems of low strength and poor durability of the consolidated body after the current water glass curing agent is used, the invention provides a preparation method of the water glass curing agent
Method used
the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more
Image
Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
Click on the blue label to locate the original text in one second.
Reading with bidirectional positioning of images and text.
Smart Image
Examples
Experimental program
Comparison scheme
Effect test
preparation example Construction
[0027] A preparation method of water glass solidifying agent, comprises the steps:
[0028] (1) In parts by weight, take 60-65 parts of 1.2mol / L ethanol solution, 40-45 parts of toluene, 30-35 parts of vinyl benzoic acid, 28-34 parts of methacrylic acid, 22-26 parts of 1- Vinylimidazole, 18-23 parts of sodium acetate, 16-19 parts of zinc nitrate, 6-8 parts of crosslinking agent, 4-7 parts of catalyst, 3-9 parts of dispersant, 2-7 parts of initiator;
[0029] (2) First put 1.2mol / L ethanol solution, vinyl benzoic acid, 1-vinylimidazole, sodium acetate and zinc nitrate into the reactor, use nitrogen protection, preheat at 45-50°C for 30 minutes, and then Use nitrogen protection, heat up to 55-60°C, stir for 20-30min;
[0030] (3) After stirring, add toluene, methacrylic acid, cross-linking agent and catalyst, raise the temperature to 70-75°C, keep it warm for 15-20min, then add dispersant and initiator, increase the pressure to 0.3-0.6MPa, and react 8~12h;
[0031] (4) After ...
Embodiment 1
[0034] The crosslinking agent is prepared by mixing divinylbenzene and diethylenetriamine at a mass ratio of 2:1.
[0035] The catalyst is prepared by mixing platinum catalyst (Dongguan Maiteng Rubber and Plastic Material Co., Ltd.) and palladium carbon catalyst (Shaanxi Kaida Chemical Co., Ltd.) at a mass ratio of 1:2.
[0036] The choice of dispersant is HMPA.
[0037] The choice of initiator is azobisisobutyronitrile.
[0038] A preparation method of water glass solidifying agent, comprises the steps:
[0039] (1) In parts by weight, take 60 parts of 1.2mol / L ethanol solution, 40 parts of toluene, 30 parts of vinyl benzoic acid, 28 parts of methacrylic acid, 22 parts of 1-vinylimidazole, 18 parts of sodium acetate, 16 parts Parts of zinc nitrate, 6 parts of crosslinking agent, 4 parts of catalyst, 3 parts of dispersant, 2 parts of initiator;
[0040] (2) First put 1.2mol / L ethanol solution, vinyl benzoic acid, 1-vinylimidazole, sodium acetate and zinc nitrate into the re...
Embodiment 2
[0045] The crosslinking agent is prepared by mixing divinylbenzene and diethylenetriamine at a mass ratio of 2:3.
[0046] The catalyst is prepared by mixing platinum catalyst (Dongguan Maiteng Rubber and Plastic Material Co., Ltd.) and palladium carbon catalyst (Shaanxi Kaida Chemical Co., Ltd.) at a mass ratio of 1:2.
[0047] The choice of dispersant is fatty alcohol polyoxyethylene ether.
[0048] The choice of initiator is azobisisoheptanonitrile.
[0049] A preparation method of water glass solidifying agent, comprises the steps:
[0050] (1) In parts by weight, take 65 parts of 1.2mol / L ethanol solution, 45 parts of toluene, 35 parts of vinyl benzoic acid, 34 parts of methacrylic acid, 26 parts of 1-vinylimidazole, 23 parts of sodium acetate, 19 parts Parts of zinc nitrate, 8 parts of crosslinking agent, 7 parts of catalyst, 9 parts of dispersant, 7 parts of initiator;
[0051] (2) First put 1.2mol / L ethanol solution, vinyl benzoic acid, 1-vinylimidazole, sodium acet...
the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More
PUM
Login to View More
Abstract
The invention relates to a sodium silicate chemical grouting material, in particular a preparation method of a sodium silicate curing agent. The preparation method comprises the following steps: providing sodium ions and zinc ions by taking sodium acetate and zinc nitrate as an ion donor; binding vinyl benzoic acid and 1-vinyl imidazole with the ions under the action of hydrogen bonds; taking theions as central receptors; then mixing the ions with methylacrylic acid; carrying out a polymerization reaction under the action of a catalyst and the like; removing the ions in a polymer by means ofan ethanol and acetic acid compound solution, wherein the central receptors are hollowed in position and are combined with zinc oxide; and during use, forming zincic acid radicals by zinc oxide and being adsorbed to the hollowed positions of the receptors, wherein hydrogen ions in the polymer replace sodium ions in sodium silicate, so that the gelation action of the sodium silicate chemical grouting material is enhanced, and meanwhile, the sodium ions are adsorbed to the hollowed positions and are combined with the zincic acid radicals, so that the sodium silicate curing rate is improved, thestrength of a solid is enhanced, the material is placed in the solid permanently to keep a solid state, and the durability is enhanced.
Description
technical field [0001] The invention relates to a water glass chemical grouting material, in particular to a preparation method of a water glass curing agent. Background technique [0002] High-rise buildings generally have to dig deep foundation pits during construction, tunnels and tunnels have to be dug during the construction of subways and highways, and deep holes have to be dug in projects such as coal mines and oil fields. Water seepage and quicksand will be encountered in the environment. Especially in rainy areas, these water seepage and quicksand not only affect the progress of the project, bring danger to the construction process, but also endanger the quality of the project after completion. Therefore, these quicksands must be reinforced with chemical grouting materials and made into curtains to stop water and seepage, so as to achieve the effect of fixing quicksands and stably reinforcing foundation pits and tunnels. [0003] Sodium silicate, commonly known as...
Claims
the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More
Application Information
Patent Timeline
Application Date:The date an application was filed.
Publication Date:The date a patent or application was officially published.
First Publication Date:The earliest publication date of a patent with the same application number.
Issue Date:Publication date of the patent grant document.
PCT Entry Date:The Entry date of PCT National Phase.
Estimated Expiry Date:The statutory expiry date of a patent right according to the Patent Law, and it is the longest term of protection that the patent right can achieve without the termination of the patent right due to other reasons(Term extension factor has been taken into account ).
Invalid Date:Actual expiry date is based on effective date or publication date of legal transaction data of invalid patent.
Login to View More 
Login to View More