Concentration distribution prediction model of water curtain diluted ammonia by considering water curtain liquid drop absorbing ammonia mass transfer

A technique for predicting the concentration and distribution of ammonia gas, which is applied to measuring devices, analytical materials, diffusion analysis, etc., and can solve problems such as not considering the effect of droplet absorption and dilution

Inactive Publication Date: 2018-06-29
TIANJIN UNIV
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Problems solved by technology

Based on the semi-empirical formula to describe the interaction between the medium-water curtain-air, many models have been developed in recent decades, such as the widely used RED conc

Method used

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  • Concentration distribution prediction model of water curtain diluted ammonia by considering water curtain liquid drop absorbing ammonia mass transfer
  • Concentration distribution prediction model of water curtain diluted ammonia by considering water curtain liquid drop absorbing ammonia mass transfer
  • Concentration distribution prediction model of water curtain diluted ammonia by considering water curtain liquid drop absorbing ammonia mass transfer

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Embodiment Construction

[0112] The model of the present invention will be further described below in conjunction with the accompanying drawings and specific embodiments.

[0113] Figure 4 It is the site layout diagram of the water curtain diluted ammonia cloud diffusion experiment carried out by Bara et al., as shown in the figure, and Table 2 is the experimental parameter settings.

[0114] Step 1: Calculate the ammonia gas concentration R absorbed by the droplets according to the parameter settings of the water curtain experiment;

[0115]

[0116] Step 2: Put Coupled to the plume radius r of the three areas respectively, a prediction model for the concentration distribution of ammonia diluted by the water curtain is constructed;

[0117] Ammonia natural diffusion area in front of the water curtain: r eq = r 0 +c atm x

[0118] Water curtain area where water curtain droplets interact with ammonia gas:

[0119] Gas diffusion zone behind the water curtain:

[0120] Step 3: Combining ...

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Abstract

The invention relates to a concentration distribution prediction model of water curtain diluted ammonia by considering water curtain liquid drop absorbing ammonia mass transfer. The mass transfer process between water curtain liquid drop and ammonia cloud cluster is researched based on a double-film mass transfer theory, a theoretical calculation equation of water curtain liquid drop absorbing ammonia is built, the liquid drop absorbing ammonia concentration R is built to represent the liquid drop absorbing effect, the square root of R is coupled into the smoke plume radius r on the basis thatthe parameter R is comprehensively assessed, and the concentration distribution prediction model of the water curtain diluted ammonia is built. The built concentration distribution prediction model is testified by adopting relevant experimental data, the model can accurately calculate the ground concentration of the ammonia leaked cloud cluster in the downwind direction at a natural spreading state and a forced spreading state respectively. The design method of water curtain diluted ammonia system projects is enriched, and the effect prediction errors of the water curtain diluted ammonia aredeclined. The result shows that the built prediction model can accurately predict the concentration of the water curtain diluted ammonia in the downwind direction, the deviation is within the range accepted by the project, and the prediction result is enabled to be reliable.

Description

Technical field [0001] The invention is used in chemical industry, fire protection and other industries, and relates to a water curtain dilution ammonia concentration distribution prediction model that considers the mass transfer of ammonia absorbed by water curtain droplets, and is mainly used in emergency plans and accident rescue guidance for liquid ammonia leakage accidents. Background technique [0002] As a commonly used industrial gas, ammonia is widely used in the chemical industry and food industry. It is often pressurized and stored in liquid form. These equipment (high-pressure vessels, storage tanks or pipelines, etc.) that store liquid ammonia may be damaged due to various reasons. Accidental rupture due to various reasons, such as corrosion, welding defects, poor sealing, valve damage or operating errors, can easily cause serious casualties and environmental hazards. As a measure to effectively dilute the leakage and spread of hazardous chemicals, water curtain...

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Application Information

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IPC IPC(8): G01N13/00
CPCG01N13/00G01N2013/003
Inventor 谭蔚程潮李超杰刘丽艳
Owner TIANJIN UNIV
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