Preparation method of flame-retardant artificial stone containing nano perovskite oxide MTiO3

An oxide and nano-calcium technology, applied in the field of building materials, can solve the problems of weak flame retardant and heat resistance, poor surface gloss, poor surface wear resistance, etc. The effect of the volume index

Inactive Publication Date: 2018-08-10
JINHUA ZHICHAN MAOYUAN INFORMATION TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the current artificial stone still has the disadvantages of low strength, poor surface abrasion resistance, weak flame retardancy and heat resistance, and poor surface gloss.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] (1) Preparation of BaTiO 3 With ZIF-90:

[0025](a) Preparation of nano titanate template: Dissolve 0.1mol / l tetraisobutyl titanate in 10ml ethylene glycol monomethyl ether, ultrasonically disperse, stir evenly, add 25% ammonia water to obtain titanium hydroxide precipitation, Deionized wash. Then add 1mol / l KOH aqueous solution, stir for 10-20 minutes, mix well, transfer to a hydrothermal crystallization kettle, and react at 140-200°C for 1-4h. After the reaction is finished, wash and dry to obtain a nano-titanate template;

[0026] Add 15ml of barium nitrate solution with a concentration of 0.2mol / l and 10ml of an aqueous solution of tetramethylammonium hydroxide with a concentration of 0.1mol / l to 2g of nano-titanate nano-template, stir for 2h, mix well, and then carry out 180-220°C hydrothermal reaction for 1-4h, then cooling and precipitation. The finally obtained product was washed with deionized water and methanol respectively. BaTiO 3 The average particle ...

Embodiment 2

[0030] (1) Preparation of SrTiO 3 With ZIF-90:

[0031] (a) Preparation of nano-titanate template: 0.3mol / l tetraisobutyl titanate was dissolved in 10ml ethylene glycol monomethyl ether, ultrasonically dispersed, stirred evenly, and 25wt% ammonia water was added to obtain titanium hydroxide precipitation, Deionized wash. Then add 2mol / l KOH aqueous solution, stir for 10-20 minutes, mix evenly, transfer to a hydrothermal crystallization kettle, and react at 140-200°C for 1-4h. After the reaction is finished, wash and dry to obtain a nano-titanate template;

[0032] Add 20ml of strontium nitrate solution with a concentration of 0.2mol / l and 10ml of an aqueous solution of tetramethylammonium hydroxide with a concentration of 0.1mol / l to 2g of nano titanate template, and stir for 2 hours. Thermal reaction for 4h, then cooling and precipitation. The finally obtained product was washed with deionized water and methanol respectively. The size of the product SrTiO3 is 40-60nm.

...

Embodiment 3

[0036] (1) Preparation of CaTiO 3 With ZIF-90:

[0037] (a) Preparation of nano-titanate template: 0.5mol / l tetraisobutyl titanate was dissolved in 10ml ethylene glycol monomethyl ether, ultrasonically dispersed, stirred evenly, and 25wt% ammonia water was added to obtain titanium hydroxide precipitation, Deionized wash. Then add 1mol / l KOH aqueous solution, stir for 10-20 minutes, mix well, transfer to a hydrothermal crystallization kettle, and react at 200°C for 3h. After the reaction is finished, wash and dry to obtain a nano-titanate template;

[0038] Add 15ml of 0.5mol / l calcium nitrate solution and 15ml of 0.3mol / l tetramethylammonium hydroxide aqueous solution to 3g of nano titanate template, stir for 2h, mix well, and then carry out 180℃ water Thermal reaction for 4h, then cooling and precipitation. The finally obtained product was washed with deionized water and methanol respectively. ProductCaTiO 3 The average diameter is 35-55nm.

[0039] (b) Preparation of ...

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Abstract

The invention relates to a preparation method of flame-retardant artificial stone containing nano perovskite oxide MTiO3. The preparation method has the advantages that nano perovskite oxide and a metal organic framework ZIF material are jointly added into a ternary polyene ester material (talcum powder quartz / phenolic resin) to increase the heat resistance and strength of the artificial stone, the aging time of the artificial stone is lowered, the artificial stone cannot be degraded under high temperature for a long time, a good flame retardant effect can be kept, and LOI (loss on ignition) index is increased greatly.

Description

technical field [0001] The present invention relates to a kind of nano-perovskite oxide MTiO 3 The invention discloses a method for preparing flame-retardant artificial stone, which belongs to the field of building materials. Background technique [0002] With the improvement of people's living standards and living conditions, the interior decoration industry is developing rapidly, and the amount of decoration building materials is huge. Among them, stone is one of the most commonly used and most basic building materials, widely used in floors, walls and The paving of the countertop. The mining cost of natural stone is high, the pollution is large, and it contains a large amount of natural radioactive substances, which is harmful to human health. With the continuous development of the material field, the performance of artificial stone has gradually improved, approaching or even surpassing natural stone, and it is more and more accepted by the market and users, and is wide...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L61/06C08K13/02C08K3/24C08K5/3445C08K3/34C08K3/36C08K5/315C08K5/521C08K3/32
CPCC08K3/24C08K3/32C08K3/34C08K3/36C08K5/3155C08K5/3445C08K5/521C08K13/02C08K2003/325C08K2201/011C08K2201/014C08L2201/02C08L2201/08C08L61/06
Inventor 骆佳豪
Owner JINHUA ZHICHAN MAOYUAN INFORMATION TECH CO LTD
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