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A Catalytic Reactor Suitable for Strong Exothermic Volume Reduction

A catalytic reactor and reactor technology, used in chemical instruments and methods, chemical/physical processes, etc., can solve the problems of large temperature difference in the catalyst bed, large pressure drop, slow removal of reaction heat, etc., to achieve temperature uniformity, reduce The effect of pressure drop and preventing flying temperature

Active Publication Date: 2021-06-08
SHENYANG INSTITUTE OF CHEMICAL TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] The purpose of the present invention is to provide a catalytic reactor suitable for strong exothermic volume reduction. The present invention solves the problem of large pressure drop and slow removal of heat of reaction when raw material gas passes through the catalyst bed during the catalytic reaction process of strong exothermic volume reduction. As well as the problem of large temperature difference in the catalyst bed, a radial reactor suitable for catalytic reactions with strong exothermic volume reduction is provided

Method used

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  • A Catalytic Reactor Suitable for Strong Exothermic Volume Reduction
  • A Catalytic Reactor Suitable for Strong Exothermic Volume Reduction

Examples

Experimental program
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Effect test

Embodiment 1

[0027] Embodiment 1 takes the methanation reaction as an example:

[0028] (1) The catalyst bed can be divided into three areas in the radial direction as an example. The catalysts are packed in the catalyst bed I, II and III in the form of concentric circles, and the catalysts are loaded sequentially with 20Ni / Al 2 o 3 , 10Ni / Al 2 o 3 , 5Ni / Al 2 o 3 .

[0029] (2) Inert gas N 2 It enters the radial reactor from the gas inlet 4, passes through the catalyst bed layers III, II and I in sequence through the gas distribution cylinder 2, enters the inner gas cylinder 7, and is discharged from the gas outlet. Use an inert gas to remove air from the reactor and catalyst bed.

[0030] (3) The reducing gas enters the radial reactor through the air inlet 4, passes through the catalyst bed layer radially through the gas distribution cylinder 2, passes through the catalyst bed layer III, II and I in turn, and reduces the catalyst at a certain temperature, and then The inner gas cy...

Embodiment 2

[0032] Embodiment 2 is example with synthetic methanol reaction:

[0033] (1) The catalyst bed is divided into three areas in the radial direction as an example. The catalysts are packed in the catalyst beds I, II and III in the form of concentric circles, and the catalysts CuO / ZnO / Al are loaded in sequence. 2 o 3 、CuO / ZnO / Al 2 o 3 and Al2 o 3 (3:1) and CuO / ZnO / Al 2 o 3 and Al 2 o 3 (1:2).

[0034] (2)H 2 and CO mixture (volume ratio H 2 / CO=2:1) ​​enters the radial reactor from the gas inlet 4, passes through the catalyst bed layers III, II and I in sequence through the gas distribution cylinder 2 and reacts in the catalyst bed layer. In the catalyst bed III, the amount of reaction gas is relatively large, and the catalyst CuO / ZnO / Al is loaded 2 o 3 and Al 2 o 3 (1:2) mixture, by reducing the amount of catalyst to control the amount of reaction gas reaction, thereby reducing the heat of reaction, matching the arrangement of a larger heat exchange area, and preve...

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Abstract

A catalytic reactor suitable for strong exothermic volume reduction, relating to a catalytic reactor, the reactor axis is in a U-shaped structure, the U-shaped axis is an inner gas cylinder (7), and the inner gas cylinder (7) is surrounded by , symmetrically arranged from the inside to the outside, there are catalyst bed I (6), catalyst bed II (5), catalyst bed III (3), gas distribution cylinder (2), outer gas cylinder (1); and outer gas cylinder (1 ) is connected with an air inlet (4); the catalyst bed III (3) is equipped with a heat exchange tube (8); the reaction raw material gas enters the catalyst bed along the periphery of the reactor, and is discharged from the center of the reactor to match the gas The change of the volume and the area of ​​the flow path; the adjustment of the reaction volume at different radial positions; the matching of the gradient loading of the catalyst, the gradient heat transfer tube bundle in the catalyst bed, and the balance of the bed reaction heat and the heat exchange tube bundle heat transfer. The reactor of the present invention is especially suitable for a place where strong exothermic volume reduction reaction realizes homogenization of bed gas flow rate, bed temperature and the like.

Description

technical field [0001] The invention relates to a catalytic reactor, in particular to a catalytic reactor suitable for volume reduction of strong heat release. Background technique [0002] Fixed-bed reactors are widely used in gas-solid phase catalytic reactions in the chemical industry. For reactions with strong exothermic and volume reduction such as Fischer-Tropsch synthesis, ammonia synthesis, methanation, etc., traditional fixed-bed reactors have limited transfer Thermal properties lead to a certain temperature difference between the axis and the radial direction of the catalyst bed, which in turn leads to the formation of local hot spots in the catalyst bed or the overheating of the catalyst bed, causing catalyst sintering and even deactivation. In addition, the traditional fixed-bed reaction design also has the disadvantage of large pressure drop when the reactant gas passes through the catalyst bed. [0003] In the industrial tube-and-tube reactor, the catalyst is ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J8/02B01J8/04
CPCB01J8/0214B01J8/0285B01J8/0411B01J2208/00132
Inventor 许光文石磊韩振南李盼盼
Owner SHENYANG INSTITUTE OF CHEMICAL TECHNOLOGY