Dyeing and printing additive and preparation method thereof

A technology of printing and dyeing auxiliaries and emulsifiers, which is applied in the field of textile printing and dyeing, can solve the problems of not easy resistance to acid, alkali, oxidant and high temperature, color enhancement, unsatisfactory color protection performance, and poor dye shedding effect, and achieves low price and printing and dyeing effect. Significant, less demanding effect of reaction equipment

Inactive Publication Date: 2018-12-21
HUNAN QIWEI TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In order to overcome the defects in the prior art, the present invention provides a printing and dyeing auxiliaries and a preparation method thereof. The printing and dyeing auxiliaries overcome the more or less high cost of the traditional printing and dyeing auxiliaries, the production process is cumbersome, and the effect on preventing dyes The shedding effect is not good, it will cause irritation to the skin, and the effect is relatively single. When multiple effects are required, a variety of additives need to be added, resulting in increased costs, reduced printing and dyeing effects, and it is not easy to resist acids, alkalis, oxidants and high temperatures. The color performance is not ideal, the color fastness is not enough, and the technical problems of easy fading. It has the advantages of various functions, remarkable printing and dyeing effects, high color fastness, good chemical resistance stability, and safe and environmentally friendly use.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A printing and dyeing auxiliary made from the following parts by weight of raw materials: 10 parts of modified trimethylol acrylamide-vegetable oil copolymer, 1020 parts of modified polyquaternary ammonium salt, 70 parts of water, and 93 parts of emulsifier AEO-93 .

[0033] The preparation method of the modified trimethylolacrylamide-vegetable oil copolymer includes the following steps:

[0034] Ⅰ. Add 20 g of N-trimethylol acrylamide, 5 g of peanut oil, and 0.3 g of azobisisobutyronitrile to 80 g of dimethyl sulfoxide, stir and react for 4 hours at 60°C under nitrogen atmosphere, and then precipitate in acetone , And washed with dichloromethane 3 times, and then placed in a vacuum drying oven at 70°C for 10 hours to obtain a copolymer;

[0035] Ⅱ. Add 10 g of the copolymer prepared in step I, 2 g of octadecyl isocyanate, and 2 g of dibutyl tin dilaurate to 40 g of dimethyl sulfoxide, stir and react at 85°C for 5 hours, and then settle in acetone It is filtered off with suc...

Embodiment 2

[0042] A printing and dyeing auxiliary agent, which is made of the following parts by weight of raw materials: 11 parts of modified trimethylol acrylamide-vegetable oil copolymer, modified polyquaternary ammonium salt-1021 parts, 72 parts of water, and emulsifier AEO-33.5 parts .

[0043] The preparation method of the modified trimethylolacrylamide-vegetable oil copolymer includes the following steps:

[0044] Ⅰ. Add 23g of N-trimethylolacrylamide, 5g of soybean oil, and 0.35g of azobisisoheptonitrile to 90g of N,N-dimethylformamide, and stir for 4.5 hours at 63°C under helium atmosphere. , Then precipitated in acetone, washed with dichloromethane 4 times, and then placed in a vacuum drying oven at 73°C for 11 hours to obtain a copolymer;

[0045] Ⅱ. Add 10 g of the copolymer prepared in step I, 2.3 g of octadecyl isocyanate, and 2 g of stannous octoate to 52 g of dimethyl sulfoxide, stir and react at 88°C for 5.5 hours, and then precipitate in acetone. Suction filtration, rotary e...

Embodiment 3

[0052] A printing and dyeing auxiliary made from the following raw materials by weight: 13 parts of modified trimethylol acrylamide-vegetable oil copolymer, modified polyquaternary ammonium salt-1023 parts, 76 parts of water, and emulsifier OP-104 parts .

[0053] The preparation method of the modified trimethylolacrylamide-vegetable oil copolymer includes the following steps:

[0054] Ⅰ. Add 25 g of N-trimethylol acrylamide, 5 g of linseed oil, and 0.41 g of azobisisobutyronitrile to 100 g of N-methylpyrrolidone, and stir and react for 5 hours at 65°C under a neon atmosphere. Precipitated in acetone, washed with dichloromethane 3 times, and then placed in a vacuum drying oven at 75°C for 13 hours to obtain a copolymer;

[0055] Ⅱ. Add 10 g of the copolymer prepared in step I, 2.6 g of octadecyl isocyanate, and 2 g of triethylamine to 62 g of dimethyl sulfoxide, stir and react at 90°C for 6.2 hours, and then precipitate in acetone. Suction filtration, rotary evaporation to remove t...

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PUM

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Abstract

The invention discloses a dyeing and printing additive. The dyeing and printing additive is prepared from the following raw materials in parts by weight: 10 to 15 parts of modified trimethylolacrylamide-vegetable oil copolymer, 20 to 25 parts of modified polyquaternary ammonium salt-10, 70 to 80 parts of water, and 3 to 5 parts of emulsifier. The invention also discloses a preparation method of the dyeing and printing additive. The preparation method comprises the following steps of uniformly mixing the raw materials according to a ratio, and stirring for 3 to 5h at the temperature of 50 to 60DEG C, so as to obtain a finished product of the dyeing and printing additive. The dyeing and printing additive has the advantages that the functions are diversified, the dyeing and printing effect is obvious, the color fastness degree is high, the chemical-resistant stability is good, and the safe and environment-friendly effects in use are realized.

Description

Technical field [0001] The invention relates to the technical field of textile printing and dyeing, in particular to a printing and dyeing auxiliary and a preparation method thereof. Background technique [0002] Printing and dyeing is a key link in the textile industry chain, carrying important functions such as creating added value and product differentiation. In recent years, with the rapid development of the printing and dyeing industry, the demand for dye textile chemicals is increasing. As one of the indispensable and important dye textile chemicals in the printing and dyeing industry, the printing and dyeing auxiliaries naturally have a huge market prospect. [0003] Textile printing and dyeing auxiliaries are auxiliaries used in the process of fabric printing and dyeing, which can improve the effect of printing and dyeing. They include printing auxiliaries and dyeing auxiliaries. Printing auxiliaries include thickeners, adhesives, and Chain agents, emulsifiers, dispersants...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06P1/52D06P1/66
CPCD06P1/525D06P1/66
Inventor 程旺生朱杭彭新良
Owner HUNAN QIWEI TECH CO LTD
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