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A polyimide resin composition and molded body

A technology of polyimide resin and polyetherimide resin, which is applied in the field of vibration plates for electroacoustic transducers, can solve the problems of difficult impact resistance, low flexibility, high rigidity, etc., and achieve excellent secondary processability and high durability excellent impact resistance

Active Publication Date: 2021-11-16
MITSUBISHI CHEM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, polyetherimide resin is a very brittle material, and there is a problem that it is difficult to use it for applications requiring impact resistance
Moreover, since the rigidity is high and the flexibility is low, it is difficult to be used in applications that require the original flexibility (flexibility) of plastic films.

Method used

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  • A polyimide resin composition and molded body
  • A polyimide resin composition and molded body
  • A polyimide resin composition and molded body

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0186] (A)-1, which is a crystalline polyimide resin (A), was melt-kneaded at 340°C using a Φ40mm single-screw extruder, and then extruded through a T-die, followed by casting at about 200°C. The roll was heated and crystallized to form a crystallized film with a thickness of 25 μm. The measurements of (1) to (5) above were performed on the obtained film. The results are shown in Table 1.

Embodiment 2

[0196] The mixing mass ratio ((B) / (A)) of (B)-1 and (A)-1 was dry-mixed at a ratio of 80 / 20, and then used a Φ40mm co-rotating twin-screw extruder at 340°C After kneading, it extruded through a T-die, and then quenched with a casting roll at about 200° C. to produce a film with a thickness of 0.1 mm. The glass transition temperature, tensile modulus, tensile elongation at break, and flexural strength of the obtained film were evaluated. The results are shown in Table 1.

Embodiment 3

[0198] Production and evaluation of the film were performed in the same manner as in Example 1 except that the mixing mass ratio ((B) / (A)) of (B)-1 and (A)-1 was set to 60 / 40. . The results are shown in Table 1.

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Abstract

The present invention provides an edge material for a vibrating piece for an electroacoustic transducer, which contains a crystalline polyimide resin (A), and the crystalline polyimide resin (A) is composed of a tetracarboxylic acid component (a-1) It consists of a diamine component (a-2) mainly composed of aliphatic diamine. In addition, the present invention provides a polyimide resin composition containing a polyetherimide resin (B) and a crystalline polyimide resin (A), and the crystalline polyimide resin (A) ) contains a tetracarboxylic acid component (a-1) and an aliphatic diamine component (a-2), wherein, on a mass basis, the polyetherimide resin (B) and the crystalline polyimide The content ratio of the amine resin (A) is (B) / (A)=1 / 99 to 99 / 1.

Description

technical field [0001] The present invention relates to an edge material for a diaphragm for an electroacoustic transducer used in various acoustic devices, and more specifically, to a material suitable for a diaphragm of a speaker, which has heat resistance, durability at high output power, and bass to treble A vibrating piece for an electroacoustic transducer with excellent playability and secondary processability. Also, the present invention relates to a film suitable for use in a vibrating piece for an electroacoustic transducer or the like. Furthermore, the present invention relates to a polyimide-based resin composition excellent in heat resistance, rigidity, and impact resistance, and a molded article obtained by molding the polyimide-based resin composition, especially a film. Background technique [0002] Due to the popularity of small electronic devices (such as mobile phones, PDAs, notebook computers, DVDs, LCD TVs, digital cameras, portable music devices, etc.),...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H04R7/18H04R7/02H04R7/12H04R7/20
CPCH04R7/18H04R7/12H04R7/02H04R7/20H04R2307/025H04R2307/023
Inventor 莲池真保
Owner MITSUBISHI CHEM CORP