Hydrocarbon oil desulfurization catalyst, preparation method therefor and hydrocarbon oil desulfurization process

A desulfurization catalyst, hydrocarbon oil technology, applied in molecular sieve catalysts, chemical instruments and methods, physical/chemical process catalysts, etc., can solve problems such as increasing operating costs, catalysts are prone to wear, etc., reducing operating costs and anti-wear performance. Good, high gasoline octane effect

Active Publication Date: 2019-05-07
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Moreover, this type of catalyst is prone to wear and tear during use, and the catalyst needs to be continuously replenished, which increases operating costs

Method used

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  • Hydrocarbon oil desulfurization catalyst, preparation method therefor and hydrocarbon oil desulfurization process
  • Hydrocarbon oil desulfurization catalyst, preparation method therefor and hydrocarbon oil desulfurization process
  • Hydrocarbon oil desulfurization catalyst, preparation method therefor and hydrocarbon oil desulfurization process

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preparation example Construction

[0033] The present invention also provides the preparation method of the hydrocarbon oil desulfurization catalyst provided by the present invention, the preparation method comprising: a, the sulfur-storing metal oxide and / or the precursor of the sulfur-storing metal oxide, the precursor of the zirconia binder, Boron nitride, molecular sieve with IMF structure, water and acidic liquid are mixed to obtain a carrier slurry; wherein, the pH value of the carrier slurry is 1-5; b, the obtained carrier slurry is spray-dried, formed, first dried and first Roasting to obtain a catalyst carrier; c, introducing the precursor of the metal promoter into the catalyst carrier and then performing the second drying and second calcination in sequence; optionally d, reducing the product obtained in step c under a hydrogen-containing atmosphere; Hydrocarbon oil desulfurization catalyst.

[0034] According to the present invention, the precursor of the zirconia binder is zirconia sol, zirconia gel...

Embodiment approach

[0044] One embodiment, the present invention specifically includes the following solutions:

[0045] 1. A desulfurization catalyst comprising:

[0046] 1) Sulfur-storage metal oxides, wherein the sulfur-storage metal is selected from one or more of the metals of Group IIB of the Periodic Table of the Elements, the metals of Group VB of the Periodic Table of the Elements, and the metals of Group VIB of the Periodic Table of the Elements, preferably selected from One or more of zinc, cadmium, niobium, tantalum, chromium, molybdenum, tungsten and vanadium, more preferably one or more selected from zinc, molybdenum and vanadium, more preferably zinc;

[0047] 2) Inorganic binder, preferably zirconia;

[0048] 3) The carrier component is boron nitride (preferably hexagonal phase boron nitride) or said boron nitride and oxides, nitrides, carbides, oxynitrides, carbonitrides, carbon oxides selected from element A and a combination of one or more of oxycarbonitride, wherein the elem...

Embodiment 1

[0096] 1.91kg of zirconium tetrachloride (Beijing Chemical Plant, analytically pure, 99% by weight) was slowly added to 3.0kg of deionized water, and 4.6kg of 5% by weight of nitric acid solution was added, slowly stirred to avoid the precipitation of zirconia crystals, and obtained Light yellow transparent zirconium sol pH=2.1;

[0097] With 4.43kg of zinc oxide powder (Headhorse company, purity 99.7% by weight), 0.75kg of HIM-5 molecular sieve (Sinopec Catalyst Changling Branch Company, containing dry basis 0.70kg, SiO 2 :Al 2 o 3 The molar ratio is 25), 2.06kg of hexagonal boron nitride (purity>99.0%, Qinhuangdao Yinuo High-tech Material Development Co., Ltd.) and 6.57kg of deionized water are mixed, and after stirring for 30 minutes, zinc oxide, HIM-5 molecular sieve and a mixed slurry of hexagonal boron nitride; then add the above-mentioned zirconium sol, mix and stir for 1 hour to obtain a carrier slurry;

[0098] The resulting carrier slurry was used in Niro Bowen No...

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Abstract

The invention relates to an IMF structure molecular sieve and zirconia binder containing hydrocarbon oil desulfurization catalyst, a preparation method therefor and a hydrocarbon oil desulfurization process. Based on the weight of the hydrocarbon oil desulfurization catalyst or the total weight of a sulfur storage metal oxide, a zirconia binder, boron nitride, IMF structure molecular sieves and ametal accelerant, the hydrocarbon oil desulfurization catalyst contains 10wt% to 80wt% (by oxide) of sulfur storage metal oxide, 3wt% to 35wt% (by oxide) of zirconia binder, 5wt% to 40wt% of boron nitride, 1wt% to 20wt% (by dry basis) of IMF structure molecular sieves and 5wt% to 30wt% (by metal element) of metal accelerant. When the hydrocarbon oil desulfurization catalyst provided by the invention is applied to the hydrocarbon oil desulfurization process, the hydrocarbon oil desulfurization catalyst has the advantages of high stability, good desulfurization activity and good wear resistance.

Description

technical field [0001] The invention relates to a hydrocarbon oil desulfurization catalyst containing an IMF structure molecular sieve and a zirconia binder, a preparation method thereof and a hydrocarbon oil desulfurization process. Background technique [0002] With the increasing scarcity of crude oil resources, how to effectively utilize limited resources to produce light products in a large amount has become the goal pursued by refinery technology developers. On the other hand, with the continuous improvement of environmental protection requirements, environmental protection regulations are becoming increasingly strict. The current gasoline quality standard GB17930-2013 requires that the sulfur content in gasoline must be less than 10ppm from January 1, 2017. Therefore, the clean product production technology that can simultaneously increase the yield of the target product has become the choice of many refiners. [0003] In my country, catalytic cracking has been widel...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J29/70C10G45/12
Inventor 林伟宋烨王磊刘俊田辉平
Owner CHINA PETROLEUM & CHEM CORP
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