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Slurry mixing method for silicon-carbon negative electrode

A negative electrode slurry, silicon carbon technology, applied in the direction of negative electrode, battery electrode, active material electrode, etc., can solve the problems of easy to cause climbing rod effect, low solid content of slurry, high powder viscosity, etc., to avoid damage and Climbing pole phenomenon, solving the effect of low solid content and good dispersion

Inactive Publication Date: 2019-08-30
HEFEI GUOXUAN HIGH TECH POWER ENERGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The steps of the traditional dry mixing process are relatively complicated. The dry mixing process in the early stage will cause certain wear and tear on the mixing cylinder, and the viscosity of the powder is relatively high during the mixing process, which may easily lead to the rod climbing effect. The most important thing is the dry mixing process. The solid content of the slurry is low, and there are certain requirements for the process parameters of the slurry during the wetting process of the powder
However, the traditional wet slurry mixing process generally has the problem of low solid content of the slurry, which brings a lot of inconvenience to the industrial production of silicon carbon negative electrodes.

Method used

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  • Slurry mixing method for silicon-carbon negative electrode

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The concrete steps of the method for mixing the slurry of the silicon-carbon negative electrode in this embodiment are as follows:

[0029] S1. Stir 1 kg of polyacrylic acid binder with a mass fraction of 12.8% and 1.3 kg of water under vacuum conditions for 100 min to obtain glue A. The stirring parameters are 30 rpm for rotation and 30 rpm for revolution;

[0030] S2. Add 0.5 kg of liquid conductive agent CNT with a solid content of 0.4% to glue A and stir for 240 minutes to obtain glue B. The stirring parameters are 1000 rpm for rotation and 1000 rpm for revolution;

[0031] S3. Add 2kg negative electrode powder SiOx / C-600A, 0.04kgSP, 0.02kgKS-6 and 0.3kg water to the glue B, first stir at low speed for 10min (rotation 30rpm, revolution 30rpm), then high-speed stirring (rotation 1000rpm, After revolution (1000rpm) for 240min, add water and rotate at 20rpm for 30min under vacuum to defoam and adjust viscosity to obtain silicon carbon negative electrode slurry.

Embodiment 2

[0033] The concrete steps of the method for mixing the slurry of the silicon-carbon negative electrode in this embodiment are as follows:

[0034] S1. Stir 1kg of polyacrylic acid binder with a mass fraction of 12.8%, 0.4kg of liquid conductive agent CNT with a solid content of 0.5%, and 1.3kg of water under vacuum conditions for 240min to obtain glue B. The stirring parameter is 40rpm , revolution 40rpm;

[0035] S2. Add 2kg of negative electrode powder SiOx / C-600A, 0.04kg of SP, 0.02kg of KS-6 and 0.3kg of water to the glue B, first stir at low speed for 10min (rotation 30rpm, revolution 30rpm), then stir at high speed (rotation 1200rpm, After revolution (1200rpm) for 240min, add water and rotate at 25rpm for 30min under vacuum to defoam and adjust viscosity to obtain silicon carbon negative electrode slurry.

Embodiment 3

[0037] S1. Stir 0.85kg of styrene-butadiene rubber (SBR) / carboxymethyl cellulose sodium (CMC) binder with a mass fraction of 12.8% and water for 0.5h under vacuum to obtain a solid content of 5% to 8%. Glue A, the stirring parameters are rotation 10rpm, revolution 10rpm;

[0038] S2. Add 1.08 kg of liquid conductive agent CNT with a solid content of 0.2% to the glue A and stir for 3 hours to obtain the glue B. The stirring parameters are 400 rpm for rotation and 400 rpm for revolution;

[0039] S3. Add 2kg negative electrode powder SiOx / C-600A, 0.03kgSP, 0.02kgKS-6 and water to the glue B, first stir at low speed (rotation 100rpm, revolution 100rpm) for 0.1h, then stir at high speed (rotation 400rpm, revolution 400rpm) 5h, then add water and rotate at 30rpm under vacuum for 0.15h to defoam and adjust viscosity to obtain a silicon-carbon negative electrode slurry with a solid content of 35%~45%.

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Abstract

The invention discloses a slurry mixing method of a silicon-carbon negative electrode. The method comprises the following steps: dissolving a binder in water, and uniformly stirring to prepare a gluesolution A; adding a liquid conductive agent into the glue solution A, and uniformly stirring to prepare a glue solution B; and adding a negative electrode active substance, a solid conductive agent and a solvent into the glue solution B, continuously stirring, and carrying out viscosity adjustment to complete slurry mixing so as to obtain the silicon-carbon negative electrode slurry. According tothe invention, the binder and the liquid conductive agent are mixed, are uniformly dispersed and then are continuously mixed with other negative electrode raw materials, so that the damage to a slurry mixing cylinder and the pole climbing phenomenon in a dry slurry mixing process are avoided, and the problem of quite low solid content in common wet slurry mixing is also solved.

Description

technical field [0001] The invention belongs to the technical field of lithium ion batteries, and in particular relates to a method for mixing silicon-carbon negative electrodes. Background technique [0002] With the improvement of people's requirements for energy density, the active materials of positive and negative electrodes of lithium-ion batteries are constantly updated, which makes new requirements for the combination of positive and negative electrodes. [0003] Silicon has a high theoretical specific capacity of up to 3572mAh / g energy density, but in the charge and discharge process, there is a large volume expansion (about 300%). SiO has attracted new attention due to its small volume expansion rate (150%) and high theoretical specific capacity of 1200mAh / g. In order to make the negative electrode obtain better cycle stability, ionic and electronic conductivity during use, the negative electrode is often used as a SiOx / C composite system. [0004] The steps of t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/36H01M4/38H01M4/587H01M10/0525
CPCH01M4/362H01M4/386H01M4/587H01M10/0525H01M2004/027Y02E60/10
Inventor 任明秀任森曹勇王磊许涛
Owner HEFEI GUOXUAN HIGH TECH POWER ENERGY
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