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A kind of dispersion strengthened window glass and preparation method thereof

A window glass and dispersion strengthening technology, which is applied in glass manufacturing equipment, glass furnace equipment, glass tempering, etc., can solve the problems of poor strength and toughness improvement of window glass, achieve good light transmission performance, improve mechanical properties, Combined with good matching effect

Active Publication Date: 2022-02-08
CHINA BUILDING MATERIALS ACAD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to overcome the problem in the prior art that the strength and toughness of the window glass are not improved, so as to provide a dispersion strengthened window glass and its preparation method

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] This embodiment provides a method for preparing a dispersion-strengthened window glass, comprising the following steps:

[0047] 1) Components in the following percentages by weight: 32% SiO 2 ;15%Al 2 o 3 ;3%B 2 o 3 ; 8% MgO; 2% SrO; 2% BaO; 3% HfO 2 ; 9% ZrO 2 ; 10.5% La 2 o 3 ;15%Y 2 o 3 and 0.5% Sb 2 o 3 Weigh the corresponding weight of SiO 2 、Al 2 o 3 , B 2 o 3 , MgO, SrO, BaO, HfO 2 , ZrO 2 , La 2 o 3 , Y 2 o 3 and Sb 2 o 3 Raw materials, and mix the raw materials evenly, then put the evenly mixed raw materials into a melting furnace at 1560°C for high-temperature melting, and mechanically stir them to clarify them to obtain clarified molten glass;

[0048] 2) Cooling the clarified molten glass to 1350°C, adding 0.5wt.% MgAl with particle size ≤ 10nm to the molten glass 2 o 4 powder, and continuous mechanical gradient stirring to ensure that MgAl 2 o 4 The powder is evenly distributed in the molten glass to obtain a uniformly mixed mol...

Embodiment 2

[0052] This embodiment provides a method for preparing a dispersion-strengthened window glass, comprising the following steps:

[0053] 1) Components by weight percentage as follows: 35% SiO 2 ;17%Al 2o 3 ;2%B 2 o 3 ;5%MgO;2%BaO;1.5%ZnO;1%TiO 2 ; 3.5% ZrO 2 ;12% La 2 o 3 ;20%Y 2 o 3 and 1% Sb 2 o 3 Weigh the corresponding weight of SiO 2 、Al 2 o 3 , B 2 o 3 , MgO, BaO, ZnO, TiO 2 , ZrO 2 , La 2 o 3 , Y 2 o 3 and Sb 2 o 3 Raw materials, and mix the raw materials evenly, then put the uniformly mixed raw materials into a melting furnace at 1580°C for high-temperature melting, and mechanically stir them to clarify them to obtain clarified molten glass;

[0054] 2) Cooling the clarified molten glass to 1300°C, adding 2wt.% MgAl with particle size ≤ 5nm to the molten glass 2 o 4 powder, and continuous mechanical gradient stirring to ensure that MgAl 2 o 4 The powder is evenly distributed in the molten glass to obtain a uniformly mixed molten glass; the pr...

Embodiment 3

[0058] This embodiment provides a method for preparing a dispersion-strengthened window glass, comprising the following steps:

[0059] 1) Components in the following percentages by weight: 20% SiO 2 ;24.5%B 2 o 3 ;2%ZnO;13.2%ZrO 2 ;

[0060] 25% Ta 2 o 5 ;13%Na 2 O; 1% Li 2 O; 0.8% Nb 2 o 5 and 0.5% Sb 2 o 3 Weigh the corresponding weight of SiO 2 , B 2 o 3 , ZnO, ZrO 2 、 Ta 2 o 5 、Na 2 O. Li 2 O, Nb 2 o 5 and Sb 2 o 3 Raw materials, and mix the raw materials evenly, then put the evenly mixed raw materials into a melting furnace at 1500°C for high-temperature melting, and mechanically stir them to clarify them to obtain clarified molten glass;

[0061] 2) Cooling the clarified molten glass to 1300°C, adding 1wt.% MgAl with a particle size of ≤20nm to the molten glass 2 o 4 powder, and continuous mechanical gradient stirring to ensure that MgAl 2 o 4 The powder is evenly distributed in the molten glass to obtain a uniformly mixed molten glass; the pr...

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Abstract

The invention relates to the technical field of special glass, in particular to a dispersion-strengthened window glass and a preparation method thereof. The preparation method of the dispersion-strengthened sight glass provided by the present invention comprises the following steps: 1) melting and stirring each component raw material of the set sight glass to obtain a clarified molten glass; 2) making the clarified molten glass Cool down to below the melting temperature, then add nano-sized MgAl 2 o 4 powder, and continue stirring to obtain a uniformly mixed molten glass; 3) forming and annealing the uniformly mixed molten glass to obtain a dispersion-strengthened window glass. The preparation method of the dispersion strengthened window glass provided by the invention can effectively improve the mechanical properties of the window glass, and at the same time, the obtained window glass also has good light transmission performance.

Description

technical field [0001] The invention relates to the technical field of special glass, in particular to a dispersion-strengthened window glass and a preparation method thereof. Background technique [0002] With the development of science and technology, glass is more and more widely used in people's daily life. Glass is mainly divided into flat glass and special glass, among which special glass refers to glass for special purposes, including high pressure resistant glass, high temperature and high pressure resistant glass, high temperature resistant glass, fireplace glass, wave soldering glass, oven glass, temperature resistant High-pressure glass, ultraviolet glass, optical glass, blue cobalt glass, glass sight tube, etc., special glass requires higher compressive strength and fracture toughness than ordinary flat glass. [0003] At present, the biggest bottleneck faced by glass as a structural functional window material is its low strength and toughness. Therefore, streng...

Claims

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Application Information

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IPC IPC(8): C03C3/068C03C1/00C03C4/00C03C21/00C03B27/03C03B27/012C03B5/18
CPCC03C3/068C03C4/00C03C1/00C03B5/18C03B27/03C03B27/012C03C21/002
Inventor 王衍行祖成奎韩滔陈江
Owner CHINA BUILDING MATERIALS ACAD