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Preparation method of fuel cell membrane electrode

A fuel cell membrane and preparation method technology, applied in the direction of fuel cells, battery electrodes, circuits, etc., to achieve the effects of reducing ohmic impedance loss, reducing waste of catalyst slurry, and reducing production costs

Inactive Publication Date: 2019-11-15
KUSN INNOVATION INST OF NANJING UNIV +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem to be solved by the present invention is to overcome the defects of the prior art and provide a method for preparing a fuel cell membrane electrode, which avoids the difficulty of flipping the membrane in the single ultrasonic spraying method and the easy curling of the proton exchange membrane. The problem of improving production efficiency, avoiding the problem of large interface resistance between the catalytic layer and the proton exchange membrane in the single transfer method, and reducing the loss of ohmic impedance

Method used

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  • Preparation method of fuel cell membrane electrode

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Embodiment 1

[0029] Preparation of CCM cathode by spraying method: cut out a proton exchange membrane of suitable size, place the spraying surface up on the heating platform of the ultrasonic sprayer, turn on the vacuum pump to flatten and adsorb the proton exchange membrane, and then spray the first catalyst slurry to control the Pt loading 0.48mg / cm 2 , only one side of the proton exchange membrane is sprayed.

[0030] Doctor blade coating: Take a 50 μm thick PTFE film and wash the transfer medium with absolute ethanol before coating the slurry. After cleaning and drying, the transfer medium was adsorbed on the vacuum platform, and the second catalyst slurry was coated on the transfer medium using a doctor blade coating device. Controlled at 0.20 mg / cm 2 , and dry after coating.

[0031] The CCM anode is prepared by the transfer method: the coated and dried transfer medium is attached to the above-mentioned proton exchange membrane with only one side sprayed, wherein the side of the t...

Embodiment 2

[0033] Preparation of CCM anode by spraying method: cut out a proton exchange membrane of suitable size, place the spraying surface up on the heating platform of the ultrasonic sprayer, turn on the vacuum pump to flatten and adsorb the proton exchange membrane, and then spray the first catalyst slurry to control the Pt loading 0.24mg / cm 2 , only one side of the proton exchange membrane is sprayed.

[0034] Doctor blade coating: Take a 50 μm thick PTFE film and wash the transfer medium with absolute ethanol before coating the slurry. After cleaning and drying, the transfer medium was adsorbed on the vacuum platform, and the second catalyst slurry was coated on the transfer medium using a doctor blade coating device. Controlled at 0.48 mg / cm 2 , and dry after coating.

[0035] The CCM cathode is prepared by the transfer method: the coated and dried transfer medium is attached to the above-mentioned proton exchange membrane with only one side sprayed, wherein the side of the t...

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Abstract

The invention discloses a preparation method of a fuel cell membrane electrode, which comprises the following steps: first catalyst slurry is applied to a side A of a proton exchange membrane by spraying; a transfer medium is coated with second catalyst slurry and dried; the dried transfer medium is attached to the proton exchange membrane spray-coated with the first catalyst slurry, the side, spray-coated with the second catalyst slurry, of the transfer medium faces an uncoated side B of the proton exchange membrane, the side A, spray-coated with the first catalyst slurry, of the proton exchange membrane is covered with a protective film, a heat transfer printing process is adopted, and after hot pressing, the transfer medium is peeled off to obtain a fuel cell membrane electrode. Throughspray coating first and then transfer printing, the problem that it is not easy to turn over and lay a membrane and the proton exchange membrane is easy to roll up in a single ultrasonic spray coating method is avoided, the production efficiency is improved, the problem of high interface resistance between the catalytic layer and the proton exchange membrane in a single transfer printing method is avoided, and the ohmic impedance loss is reduced.

Description

technical field [0001] The invention relates to a preparation method of a membrane electrode of a fuel cell, belonging to the technical field of membrane electrodes of a fuel cell. Background technique [0002] In recent years, Proton Exchange Membrane Fuel Cells (PEMFC), as a new type of clean energy, have attracted worldwide attention due to their low pollution or even non-polluting properties. The membrane electrode (Membrane Electrode Assembly, MEA), the core component of PEMFC, is the main place where redox occurs in fuel cells, and it is also the focus of researchers' research, especially the research on its manufacturing process. [0003] According to the characteristics of different structures, traditional membrane electrode preparation methods can be divided into GDE method (Gas Diffusion Electrode, GDE) and CCM method (Catalyst Coated Membrane, CCM). The so-called GDE method is mainly to coat the catalyst slurry on the gas diffusion layer to form a catalyst layer,...

Claims

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Application Information

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IPC IPC(8): H01M4/86H01M4/88H01M4/90H01M8/1004
CPCH01M4/8657H01M4/8647H01M4/8828H01M4/9041H01M8/1004Y02P70/50Y02E60/50
Inventor 李丹刘建国黄林吴聪萍邹志刚麦立强田娟贾爽周亮
Owner KUSN INNOVATION INST OF NANJING UNIV
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