High-performance carbon paper for fuel cell and preparation method and application thereof

A fuel cell, high-performance technology, applied in fuel cells, synthetic cellulose/non-cellulose material pulp/paper, paper, etc., can solve the problem of high resistivity of carbon paper, achieve good physical properties, improve physical properties, reduce The effect of dosage

Active Publication Date: 2019-11-29
SOUTH CHINA UNIV OF TECH
View PDF6 Cites 19 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology solves problems associated with current methods that require expensive equipment such as chemicals and complicated processes while also producing stronger products compared to pure fibers alone. It combines different types of starting substances together into one molecular structure called polymer solution (PMS) which makes it easier to produce strong carbon papers without requiring excessive amounts of other ingredients like sizing agents. Additionally, modifying certain parts of PSA results in improved electric conduction and mechanical properties making them more suitable for use in various applications where they are needed.

Problems solved by technology

Technological Problem addressed in this patented technical problem relates to improving the quality and effectiveness of producing highly functional materials from renewable resources such as biomass or coal while reducing environmental pollution caused by fossil fuels used during combustion processes. Current techniques involve expensive equipment like palladium/platinum alloy systems due to their poor durability under harsh conditions. To address this issue, there have been developed new technologies involving alternative sources of electric current generating elements called ion exchangers. These alternatives include polymeric membranous receptors made up of strong acid groups attached to metal particles on top of which tiny holes pass through. By combining different types of metals together, they can create various properties including better electron conduction capabilities, stronger hydrone repelling ability, improved heat transfer capacity, enhanced electronic activity, reduced oxygen release rates, stable mechanisms for use in batteries, and superior long term storage capacities compared to existing battery manufacturing methods.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • High-performance carbon paper for fuel cell and preparation method and application thereof
  • High-performance carbon paper for fuel cell and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0053] The preparation method of the acid-modified carbon nanotubes involved in the present invention is as follows: carbon nanotubes (Nanjing Xianfeng Nano Material Technology Co., Ltd., multi-walled carbon nanotubes diameter 10 ~ 20nm, length 10 ~ 30μm) and mixed acid (mass Fraction 98% concentrated sulfuric acid and mass fraction 68% concentrated nitric acid (mass ratio 3:1) solution is added in the single-necked round bottom flask with condensation reflux device, wherein, carbon nanotube accounts for 2.5% of the mass fraction of mixed acid solution, is heated to 120 ℃ , kept for 5 hours, and then the carbon nanotubes were washed with deionized water to obtain acidified multi-walled carbon nanotubes.

[0054] The preparation method of carbon nanotubes involved in the present invention, boric acid-cardanol modified phenolic resin is as follows:

[0055] ① Add phenol, boric acid and acetic acid in a certain proportion to a three-necked flask equipped with a thermometer, agita...

Embodiment 1

[0059] (1) Get 10 parts by mass of viscose fiber (Hubei Chemical Fiber Factory, length 3mm), 2 parts by mass of cellulose nanofibrils (NFC, purchased from KEXLAN), 88 parts by mass of carbon fiber (Japan Teijin Corporation, polyacrylonitrile-based carbon fiber, Length 6mm, resistivity 1~10mΩ / cm) into the dispersion barrel with agitator, add appropriate amount of water to make the total mass fraction of viscose fiber, cellulose nanofibril and carbon fiber 0.15%, start stirring, the speed is 700rpm , first add 0.04wt% Tween-80, then add 0.12wt% polyethylene oxide (PEO, molecular weight 6,000,000), and add 0.13wt% polyvinyl alcohol solution (PVA, molecular weight 170,000 to 220,000) (the concentration of polyvinyl alcohol solution is 10% by mass), after mechanical stirring for 10 minutes, wet paper web is made by wet forming equipment, and dried in an oven (temperature 90 ~ 110 ° C, time 30 ~ 40 minutes), Made of quantitative 90g / m 2 carbon paper precursors.

[0060] (2) The ca...

Embodiment 2

[0062] (1) Get 15 parts by mass of viscose fiber (Hubei Chemical Fiber Factory, length 3mm), 1 part by mass of cellulose nanofibrils (NFC, purchased from KEXLAN), 84 parts by mass of carbon fiber (Teijin Corporation, polyacrylonitrile-based carbon fiber, Length 6mm, resistivity 1~10mΩ / cm) into the dispersion barrel with agitator, add appropriate amount of water to make the total mass fraction of viscose fiber, cellulose nanofibril and carbon fiber 0.15%, start stirring, the speed is 700rpm , first add 0.04wt% Tween-80, then add 0.12wt% polyethylene oxide (PEO, molecular weight 6,000,000), and add 0.13wt% polyvinyl alcohol solution (PVA, molecular weight 170,000 to 220,000) (the concentration of polyvinyl alcohol solution is 10% by mass), after mechanical stirring for 10 minutes, wet paper web is made by wet forming equipment, and dried in an oven (temperature 90 ~ 110 ° C, time 30 ~ 40 minutes), Made of quantitative 90g / m 2 carbon paper precursors.

[0063] (2) The carbon pa...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Diameteraaaaaaaaaa
Lengthaaaaaaaaaa
Resistivityaaaaaaaaaa
Login to view more

Abstract

The invention discloses high-performance carbon paper for a fuel cell and a preparation method and application thereof. The method comprises the following steps: (1) adding fiber raw materials into water, stirring and mixing uniformly to obtain mixed slurry I; then sequentially adding a surfactant, polyoxyethylene and a polyvinyl alcohol solution into the mixed slurry I and stirring evenly to obtain mixed slurry II; then making the mixed slurry II into a wet paper web and drying to obtain a carbon paper precursor, wherein the fiber raw materials include viscose fiber, cellulose nanofiber and carbon fiber; and (2) dipping the carbon paper precursor into an ethanol solution of modified phenolic resin, drying, coating the carbon paper precursor with a hydrophobic coating, and performing hot pressing and heat treatment to obtain the high-performance carbon paper for the fuel cell. The carbon paper obtained by the method has better electrical conductivity and physical properties, and can beapplied to the field of fuel cells.

Description

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Owner SOUTH CHINA UNIV OF TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products