A kind of water-absorbent resin used in wet method for manufacturing absorbent paper and its preparation method
A technology of water-absorbent resin and water-absorbent paper, which is applied in papermaking, paper machines, textiles, and papermaking, etc., and can solve the problems of performance degradation of polymer water-absorbent resin, water retention rate of polymer water-absorbent resin, and reduction of liquid-permeable absorption performance.
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[0022] In a first aspect, the present invention provides a method for preparing a water-absorbent resin for wet-process manufacturing of water-absorbent paper, the method comprising the following steps: (1) mixing acrylic acid, water, a cross-linking agent and hydrophobic silica Nitrogen deoxygenation (such as nitrogen deoxygenation so that the oxygen content is within 1ppm), then add an initiator to initiate the polymerization reaction, and then heat preservation treatment to obtain the polymer colloid; (2) Granulate the polymer colloid obtained in step (1), Obtain resin particles; (3) Neutralize the resin particles obtained in step (2) with an alkaline solution, then spray the first surface treatment liquid (surface treatment liquid ①) for the first surface treatment, and then dry and crush in sequence to obtain water-absorbent resin particles; (4) spraying a second surface treatment liquid (surface treatment liquid ②) on the surface of the water-absorbent resin particles obt...
Embodiment 1
[0052] Example 1: The raw materials for preparing the superabsorbent resin for wet papermaking according to the present invention are: in parts by weight, 100 parts by weight of acrylic acid, 700 parts of deionized water, 2 parts of hydrophobic silica, and 3 parts of trimethylolpropane Acrylic ester 3, tetraallyloxyethane 2.5, potassium persulfate 0.4, sodium bisulfite 0.6, 48wt% sodium hydroxide solution 104, 70wt% glycerol solution 29, polyglycerol polyglycidyl ether 5, 40wt % (total mass fraction of aluminum sulfate and sodium sulfate) aluminum sulfate sodium sulfate solution 5.5 (aluminum sulfate: sodium sulfate = 2:1), coating agent 5, liquid silicon dioxide 1.2; the coating agent is self-made by the present invention The amphiphilic oligomer coating agent, its preparation process is: 10 weight parts of acrylic acid and 20 weight parts of ethylene are put into the reaction kettle under the pressurized condition that pressure is 3MPa, add 0.5 weight part of azobisisobutyron...
Embodiment 2
[0054] Example 2: The raw materials for preparing the superabsorbent resin for wet papermaking according to the present invention are: in parts by weight, 200 parts by weight of acrylic acid, 600 parts of deionized water, 4 parts of hydrophobic silica, and three parts of trimethylolpropane Acrylic ester 5.5, potassium persulfate 0.7, ascorbic acid 1.3, 48wt% sodium hydroxide solution 196, 70wt% glycerin solution 48, polyglycerol polyglycidyl ether 10, 30wt% (total mass fraction of aluminum sulfate and sodium sulfate) Aluminum sulfate sodium sulfate solution 15 (aluminum sulfate: sodium sulfate=3:1), coating agent 7.5, liquid silicon dioxide 1.5; the coating agent is an amphiphilic oligomer coating agent obtained by the present invention, and its preparation process It is: put 15 parts by weight of acrylic acid and 15 parts by weight of ethylene into the reaction kettle under the pressure of 3MPa, add 0.3 parts of azobisisobutyronitrile, and heat it to 60°C under the pressure of...
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