Treatment and recovery process for alkaline etching wastewater
A technology for etching wastewater and alkalinity, applied in multi-stage water treatment, water treatment parameter control, water/sewage multi-stage treatment, etc., can solve problems such as unfavorable promotion, high treatment cost, unsatisfactory effect, etc., and achieve recovery effect Good, low operating cost, low production cost effect
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Embodiment 1
[0039] Copper recycling
[0040] The recovery of the copper includes the following steps:
[0041] (1) Pre-reduction: The alkaline etching wastewater is pumped to the reduction recovery tank, and the water is fed to the pre-filled line of the reduction recovery tank, and sodium hydroxide is added to adjust the pH value of the reduction recovery tank. The pH value is 11-12, put glucose into the reduction recovery tank for pre-reduction, the concentration of glucose is 1.20-1.30 mol / L, and the pre-reduction time is 10-30 min;
[0042] (2) Reduction: add polyvinylpyrrolidine copper and thiourea dioxide to the reduction recovery tank for reduction, the molar concentration of thiourea dioxide in the alkaline etching wastewater and the molar concentration of copper ions are in a ratio of 3:2, add Na 2 CO 3 The solution adjusts the pH value of the inlet water, the pH value is 9-10, the reaction temperature is 70-80°C, and the reaction time is 10-20 min;
[0043] (3) Separation, water washin...
Embodiment 2
[0046] In addition to a large amount of copper ions, the alkaline etching waste solution also contains a high concentration of ammonia nitrogen, generally 150~200 g / L. After the waste liquid is recovered by copper, urea will be produced during the reduction process of the recovery of copper. The urea concentration reaches 6-8g / L, and the ammonia nitrogen concentration in the tail liquid is about 10-50g / L. Therefore, the tail liquid must be recycled.
[0047] The reuse of the tail liquid sequentially includes the recovery of copper ions in the tail liquid, the recovery of ammonia nitrogen in the tail liquid, and the treatment of the remaining tail liquid.
[0048] The recovery of copper ions in the tail liquid includes the following steps:
[0049] (1) Water inflow: pump the above-mentioned tail liquid to the micro electrolytic cell, and inject water to the pre-full line of the micro electrolytic cell, add hydrochloric acid to adjust the pH value of the micro electrolytic cell, and t...
Embodiment 3
[0054] The recovery of ammonia nitrogen in the tail liquid includes the following steps:
[0055] (1) Water inflow: pump the primary tail liquid to the chemical sedimentation tank, enter the water to the pre-filled line of the chemical sedimentation, add sodium hydroxide to adjust the pH value of the chemical sedimentation tank, the pH value is 9.5 ~10;
[0056] (2) Chemical precipitation: Put a precipitation agent into the chemical precipitation tank, the precipitation agent is magnesium salt, the Mg in the magnesium salt 2 + , NH 4+ , PO 4 3- The molar ratio of is 1.5:1:1.5, the reaction temperature is 25~28℃, and the reaction time is 25~30min;
[0057] (3) Effluent: standing for precipitation, solid-liquid separation to obtain a secondary tail liquid, the secondary tail liquid is discharged to obtain magnesium ammonium phosphate crystals, which are dried and recovered.
[0058] Operational effect: the recovery of ammonia nitrogen in the tail liquid, the recovery of ammonia nitrogen...
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