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A process for preparing low residual thermal stress amorphous alloy

A technology of amorphous alloy and process method, applied in the field of preparing low residual thermal stress amorphous alloy, can solve the problems of not reducing the difference between the melt casting temperature and solidification temperature, reducing the residual thermal stress of amorphous alloy, etc. High maneuverability and repeatability, low cost and high efficiency

Active Publication Date: 2021-07-13
创明(韶关)绿色能源材料技术研究院有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Although this method reduces the casting temperature of the alloy melt, it does not reduce the difference between the casting temperature and the solidification temperature of the melt, so it does not help to reduce the residual thermal stress of the amorphous alloy.

Method used

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  • A process for preparing low residual thermal stress amorphous alloy
  • A process for preparing low residual thermal stress amorphous alloy
  • A process for preparing low residual thermal stress amorphous alloy

Examples

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Effect test

Embodiment 1

[0067] to prepare Fe 80 P X Si 15-X B 5 Amorphous alloy thin strip is example (the subscript number in the chemical formula is atomic percentage content at%), and the specific operation steps of a kind of processing method that the present invention proposes to reduce amorphous alloy thin strip thermal stress are as follows:

[0068] Step 1, reduce the viscosity of amorphous alloy melt:

[0069] (1) First prepare Fe according to the actual situation 80 Si 15 B 5 The requirements for the casting temperature of the alloy melt in the case of amorphous alloys determine that the casting temperature of the alloy melt is 1300°C. Will Fe 80 Si 15 B 5 The alloy melt was heated up to 1450°C, held for 1 hour, then cooled to 1300°C, held for another 1 hour, and then the viscosity of the alloy melt was measured by a high-temperature viscosity measuring instrument (product of GBX company, model: Viscodrop 2000) to obtain the alloy melt The viscosity value at the casting temperatur...

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Abstract

The invention provides a process method for preparing a low residual thermal stress amorphous alloy, comprising: step S1, select a reference alloy, and use a non-metallic element that forms a low-melting point alloy with a metal element to partially replace the non-metallic element that forms a high-melting point alloy with a metal element. Form a series of alloys with different components by means of metal elements, and measure their viscosity at different casting temperatures to establish the relationship between viscosity-casting temperature-composition; step S2, measure different cooling conditions for the series of alloy melts at different casting temperatures Set up the relationship of cooling condition-solidification temperature-casting temperature-composition; step S3, at first, according to the relationship obtained in step S1, select the alloy composition of low viscosity and set the casting temperature according to the viscosity standard; then, according to the selection The alloy composition, the set casting temperature and the relationship obtained in step S2, select the cooling conditions corresponding to the increase of the supercooled solidification temperature; finally, an amorphous alloy is obtained.

Description

technical field [0001] The invention belongs to the technical field of preparation of metal functional materials, in particular to a process for preparing amorphous alloys with low residual thermal stress. Background technique [0002] In essence, the process of preparing an alloy melt into an amorphous alloy is a supercooling solidification process of the alloy melt. In this process, the alloy melt first becomes a supercooled liquid, and as the supercooling degree of the melt increases, the melt The viscosity of the melt increases rapidly, causing the melt to lose its flow ability and finally solidify into a hard solid. When the alloy melt temperature is lower than its natural solidification temperature, it is called supercooled liquid. To make the melt a supercooled liquid, the viscosity change of the melt must lag behind the temperature change of the melt. Only in this way can the melt maintain the fluidity of the melt when the temperature is lower than the natural solid...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B22D11/06B22D11/22C22C33/04C22C1/02
CPCB22D11/0611B22D11/0682B22D11/22C22C33/003C22C33/04C22C1/02C22C1/11
Inventor 王岩国周少雄张广强董帮少李宗臻
Owner 创明(韶关)绿色能源材料技术研究院有限公司
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