A kind of patterned color solar cell and its preparation method
A technology for solar cells and solar cells, applied in circuits, photosensitive equipment, photovoltaic power generation, etc., can solve the problems of fading of color solar modules, affect the appearance, complicated preparation process, etc., and achieve a wide range of colors and patterns. Wide and simple preparation process
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[0020] A preferred embodiment of the method for preparing a patterned colored solar cell of the present invention includes the following steps: stacking and assembling together an upper encapsulating glass A, a first colored perovskite quantum dot adhesive film B, a solar cell sheet C, and / or Or the second colored perovskite quantum dot film D and the lower packaging glass E are placed in a laminator for lamination.
[0021] Specifically, the patterns of the upper encapsulation glass A and the lower encapsulation glass E are respectively prepared by the following methods:
[0022] The pattern is processed by laser etching method, and the depth of laser etching is 5nm~20µm, or,
[0023] A film layer is deposited by one of UV printing method, 3D printing method, evaporation method, atomic layer deposition method, sputtering method, plasma chemical vapor deposition method and screen printing method, and the thickness of the film layer is 20nm~1mm , the composition of the film la...
Embodiment 1
[0039] As the first method for preparing a patterned color perovskite solar cell of the present invention, the steps are as follows:
[0040] 11. After mixing 0.5g cesium carbonate, 5mL oleic acid and 50mL oleylamine, vacuumize the reaction bottle for 10min, then heat to 120°C, react for 1h, then heat to 150°C under nitrogen protection, keep for 2h, and then get clarification cesium oleate solution.
[0041] 12. Mix 10mL oleylamine and 0.5mmol lead chloride (PbCl 2 ) or lead bromide (PbBr 2 ) or lead iodide (PbI 2 ) to mix, vacuumize and heat to 120°C for 1h, then under the protection of nitrogen, add 50uL oleic acid, then raise the temperature to 140°C, then inject the cesium oleate solution prepared in step 11 heated to 100°C, and then quickly use Cool in an ice-water bath to room temperature, precipitate with a centrifuge at a speed of 5000 rpm for 10 min, wash twice with octane, and dry under vacuum to obtain blue CsPbCl 3 , Green CsPbBr 3 and red CsPbI 3 Perovskite ...
Embodiment 2
[0047] As the second preparation method of the patterned colored perovskite solar cell of the present invention, the steps are as follows:
[0048] 21. Preparation of upper encapsulation glass with stripe pattern: After cleaning the glass, put it into the plasma enhanced chemical vapor deposition (PECVD) equipment, and place such as image 3 The strip template, the shaded part is the shielded area, and the glass will not deposit SiO in the covered area 2 film. Then high-purity silane and nitrous oxide are introduced, the frequency is 13.56MHz, the distance between the sample and the reaction area is 3cm, the gas flow rate is 80sccm, the air pressure is 92mTorr, the power is 150W, and the vacuum degree of the chamber is 1x10 -5 Pa, the reaction time is 5min, and finally the deposited silicon dioxide (SiO2) with a thickness of 1µm 2 ) coated upper encapsulating glass 1' with a stripe pattern.
[0049] 22. Preparation of cesium oleate: same as step 12.
[0050] 23. Preparatio...
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