Color coating, photovoltaic module with color coating and preparation method of photovoltaic module

A color coating and photovoltaic module technology, applied in photovoltaic power generation, multi-color effect coatings, luminous coatings, etc., can solve the problem of low energy conversion efficiency of colored solar cells, long time-consuming synthesis of light-absorbing layers, fading of colored solar modules, etc. problems, to achieve a wide range of options, improve the utilization rate of light energy, and reduce the loss of energy conversion efficiency

Inactive Publication Date: 2020-06-23
HANGZHOU MICROQUANTA SEMICON CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although organic or polymer solar cells can be prepared in color, it is necessary to change the structure of the light-absorbing layer and reasonably match the energy levels of each functional layer of the battery, but the general energy conversion efficiency is low, and the synthesis of the light-absorbing layer The process is time-consuming and difficult to purify, so the commercialization of this type of colored solar cells is still a long way off
Some thin-film solar cells such as grating structure or double prism structure can also obtain colored patterned solar cell modules, but because the preparation process is relatively complicated, if you need to prepare patterned solar modules, you need the assistance of laser scribing. The energy conversion efficiency of color solar cells is generally low
Lay a patterned polymer film (such as colored polyethylene terephthalate film, polyvinyl chloride film, polycarbonate film and polystyrene film, etc.) on the surface of the packaged three-glass solar cell module, or use UV printing method, 3D printing method and other methods to prepare color film layer, after long-term use outdoors, the polymer will degrade after being exposed to light and rain, and the dyes, pigments and other substances on the surface will also decompose and be released into the environment Cause pollution, and color solar modules will fade, affecting the appearance

Method used

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  • Color coating, photovoltaic module with color coating and preparation method of photovoltaic module
  • Color coating, photovoltaic module with color coating and preparation method of photovoltaic module
  • Color coating, photovoltaic module with color coating and preparation method of photovoltaic module

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preparation example Construction

[0053] The present invention also discloses a method for preparing the color coating as described above, comprising the following steps:

[0054] Step 1. Dissolving colored nanoparticles in a solvent containing additives by means of ultrasound or stirring to form a precursor solution containing colored pigments.

[0055] Step 2. Use the precursor solution by hydrothermal method, in-situ growth method, spin coating method, scrape coating method, coating method, spray coating method, screen printing method, 3D printing method, electrospinning method, inkjet printing method Any one of the processing methods is coated or deposited on the surface of the attachment.

[0056] Step 3: Place the attachment with the precursor solution coated or deposited on its surface in a vacuum, an inert environment or air, and anneal to obtain a colored coating on the surface of the attachment.

[0057] The present invention also discloses a method for preparing the color coating as described above...

Embodiment 1

[0065] The first embodiment of the preparation method of the photovoltaic module of the present invention comprises the following steps:

[0066]Step 11, use a ball mill to grind cobalt nitrate hexahydrate into fine powder particles, cobalt nitrate hexahydrate is the red pigment component, and mix cobalt nitrate hexahydrate fine powder particles, tetraethoxysilane, ethanol, hydrogen peroxide, and water in a molar ratio Mix at 255:4:1:6:9 to prepare a precursor solution of red pigment containing cobalt nitrate.

[0067] Step 12, mix 0.2g of cesium carbonate, 10mL of octadecene and 1mL of oleic acid, stir in a vacuum environment for half an hour and heat at 120°C, then take 0.2g of lead chloride, 10mL of octadecene, oil Mix and stir 1mL of acid and 1mL of oleylamine evenly, heat and react at 90°C for 1h, vacuumize during the reaction, then fill the reaction system with nitrogen, and then inject the cesium-containing solution of the first step into the solution containing lead ch...

Embodiment 2

[0073] The second embodiment of the preparation method of the photovoltaic module of the present invention comprises the following steps:

[0074] Step 21, use a ball mill to grind copper chloride into fine powder particles, copper chloride is a green pigment component, use tetraethoxysilane, silane cross-linked polyethylene, ethanol, distilled water, 1M hydrochloric acid, 1M ammonium hydroxide, chloride Copper fine powder particles and polystyrene are mixed at a molar ratio of 1:6:50:50:1:1:20 to form a precursor solution containing copper chloride green pigment, which is a hybrid sol-gel solution. colloidal liquid.

[0075] Step 22. Dissolve 0.1mmol of methylamine bromide in 0.2mL of N,N-dimethylformamide, then dissolve 0.2mmol of lead bromide in 0.5mL of N,N-dimethylformamide, and dissolve 10mL hexane, 0.5mL of oleic acid, and 0.1mL of oleylamine were mixed together, then the solution of methylamine bromide and lead bromide was added to the mixed system, and then a white s...

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Abstract

The invention relates to a color coating. A precursor solution containing a color pigment is coated or deposited on an attachment, and then annealing is performed, wherein the precursor solution contains a solvent, color nanoparticles and an additive. The invention further discloses a photovoltaic module using the color coating and a preparation method of the photovoltaic module. The stable colorcoating is formed on the structural layer of the photovoltaic module, the inherent color of the photovoltaic module is changed, the attractive requirement of the photovoltaic module is met, the photovoltaic module has high light stability, corrosion resistance, abrasion resistance and heat stability, and meanwhile the photovoltaic efficiency can be improved.

Description

technical field [0001] The invention belongs to the technical field of solar photovoltaic cell preparation, and in particular relates to a color coating, a photovoltaic module with the color coating and a preparation method thereof. Background technique [0002] With the rapid development of the photovoltaic industry in recent years, the aesthetic requirements for building photovoltaic integration are also higher. Preparation of colored solar photovoltaic modules has also received extensive attention in recent years. Common methods for preparing colored solar cells are mostly based on preparing colored solar cells first and then encapsulating them. Most of the materials suitable for building integrated photovoltaics are glass substrates because of their outdoor durability and light weight. However, glass is mostly transparent and colorless, so in order to change the appearance of colored solar cells, it is necessary to prepare the color of the cells themselves to be colore...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L31/048H01L31/055C09D5/22C09D5/29
CPCH01L31/0481H01L31/0488H01L31/055C09D5/22C09D5/29Y02E10/542Y02E10/52
Inventor 不公告发明人
Owner HANGZHOU MICROQUANTA SEMICON CO LTD
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