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A detection method for the degree of powder stringing of single cells of thermal batteries

A single battery and detection method technology, which is applied in the direction of measuring electricity, measuring devices, measuring electrical variables, etc., can solve the problem of not being able to quantitatively reflect the degree of powder stringing between positive and negative electrodes, and achieve fast measurement speed, low cost, and measurement. accurate effect

Active Publication Date: 2021-07-27
INST OF ELECTRONICS ENG CHINA ACAD OF ENG PHYSICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] The technical problem to be solved by the present invention is that the usually measured cell resistance is the result of the parallel connection between the internal resistance of the cell and the leakage resistance caused by series powder, the driving voltage or the driving current and the electrolyte when the resistance is measured. State influence, cannot accurately and quantitatively reflect the degree of powder crossing between positive and negative electrodes

Method used

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  • A detection method for the degree of powder stringing of single cells of thermal batteries
  • A detection method for the degree of powder stringing of single cells of thermal batteries
  • A detection method for the degree of powder stringing of single cells of thermal batteries

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Embodiment 1

[0051] like Figure 1 to Figure 6 As shown, the present invention is a method for detecting the degree of powder stringing of single cells of thermal batteries, including:

[0052] At room temperature, use a high input impedance voltmeter to measure the open circuit voltage V of the hot battery cell, and use an ohmmeter to measure the resistance R of the hot battery cell in constant voltage or constant current mode 3 , using an ammeter to measure the short-circuit current I of the hot battery cell 4 ;

[0053] According to the above measured open circuit voltage V, resistance R 3 and short-circuit current I 4 The value of any two parameters in the three parameters can be calculated to obtain the internal resistance R of the single cell of the thermal battery 1 , The leakage resistance R caused by string powder 2 ; and judge the degree of powder stringing of hot battery cells: when 02 4 Ω, the degree of powder accumulation is very serious, the battery may not be able to di...

Embodiment 2

[0065] Such as Figure 1 to Figure 6 As shown, the difference between this embodiment and Embodiment 1 is that this embodiment is based on the open-circuit voltage V and short-circuit current I of the thermal battery single cells 4 Two parameters, use the following formula to calculate the internal resistance R of the hot battery cell at room temperature 1 , The leakage resistance R caused by string powder 2 :

[0066] R 1 =U 0 / I 4 ,

[0067] R 2 =(U 0 / I 4 ) / (U 0 / V-1),

[0068] where U 0 It is the open-circuit electromotive force of the single cell of the hot battery at room temperature, which is determined by experiment.

[0069] During implementation: S10. Increase the thickness of the electrolyte to d, and prepare several single battery sheet samples A 1 、A 2 ,...,A m , so that it is possible to completely avoid the phenomenon of stringing powder between the positive and negative electrodes inside the cell, and use a blade to completely remove the stringin...

Embodiment 3

[0075] Such as Figure 1 to Figure 6 As shown, the difference between this embodiment and Embodiment 1 is that this embodiment is based on the open circuit voltage V of the hot battery cell and the resistance R measured in the constant voltage mode. 3 Two parameters, use the following formula to calculate the internal resistance R of the hot battery cell at room temperature 1 , The leakage resistance R caused by string powder 2 :

[0076] R 1 =R 3 × U 0 ×(1 / V-1 / U 10 ),

[0077] R 2 =R 3 ×(U 0 × U 10 -U 0 ×V) / (U 10 ×U 0 -U 10 ×V),

[0078] where U 10 is the driving voltage of the resistance meter in the constant voltage mode; U 0 It is the open-circuit electromotive force of the single cell of the hot battery at room temperature, which is determined by experiment.

[0079] During implementation: S10. Increase the thickness of the electrolyte to d, and prepare several single battery sheet samples A 1 、A 2 ,...,A m , so that it is possible to completely avoid...

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Abstract

The invention discloses a detection method for the degree of dusting of single battery sheets of a thermal battery, which solves the problem that the current detection method based on single measurement of the resistance of the single battery sheet cannot accurately and quantitatively reflect the degree of powdering between positive and negative electrodes. The invention uses a high input impedance voltmeter to accurately measure the open-circuit voltage of the thermal battery single cell at room temperature, uses an ammeter to measure the short-circuit current of the thermal battery single cell, uses a resistance meter to measure the resistance of the thermal battery single cell, and utilizes the open-circuit voltage Any two of the three parameters, short-circuit current and resistance, based on the thermal battery single cell circuit model, directly calculate the internal resistance of the thermal battery single cell at room temperature and the leakage resistance caused by series powder, and realize the heat dissipation based on the leakage resistance. Quantitative detection of the degree of powder contamination during battery production and inspection, and quick and accurate judgments.

Description

technical field [0001] The invention relates to the technical field of thermal battery detection, in particular to a detection method for the degree of powder stringing of single cells of a thermal battery. Background technique [0002] Thermal battery is a primary reserve battery widely used in various military or civilian equipment systems such as missiles, bombs, torpedoes, space exploration, emergency escape devices, etc. The internal generally obtains the required output voltage by connecting multiple single cells in series. And output power, each single battery sheet is made of three layers of positive electrode, electrolyte and negative electrode through powder pressing process, and the positive electrode and negative electrode are separated by electrolyte. However, during the pressing process of the single battery sheet, especially when the thickness of the electrolyte layer is small, due to the stringing of powder between the positive and negative electrodes, a smal...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01R31/389G01R31/396G01R31/385G01R31/378G01R31/367
CPCG01R31/367G01R31/378G01R31/3865G01R31/389G01R31/396
Inventor 张小强崔艳华赵宇高晨阳闫军崔益秀
Owner INST OF ELECTRONICS ENG CHINA ACAD OF ENG PHYSICS