Preparation of resin microspheres of resin microspheres in printing and dyeing wastewater treatment and application thereof

A technology of resin microspheres and printing and dyeing wastewater, which is applied in textile industry wastewater treatment, water/sewage treatment, special compound water treatment, etc. It can solve the problems of low adsorption and removal efficiency of heavy metal ions and lower COD removal rate, and achieve ion diffusion resistance Small, enhances antioxidant performance, prevents oxidative degradation

Inactive Publication Date: 2020-08-11
闫娟
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology describes various methods used to improve the performance or durability of polymer microparticles (PM) made from specific materials called octadecyl quaternary ammonium salt. These techniques include modifying the particle surfaces during synthesis process, adding different types of compounds like epoxy acids onto these particles' surfaces, create porous structures containing sulfur atoms at their ends, and increasing oxygen permeabilities while reducing iron content. By doing this, PM becomes more resistant against environmental factors such as bacteria, dissolved metals, and other substance. Additionally, it allows for efficient removal of harmful elements without being washed away due to strong cations attached thereto. Overall, this new type of coating material improves the effectiveness and reuse potential of PMBs in treating water contamination problems.

Problems solved by technology

This patented technical solution described in this patent involves improving the purification performance of printed and dyed wastes (WC) containing various types of harmful compounds like heavy metallates. Current methods involve adding expensive specialty material(s), which increases costs associated with handling these hazardous contaminated solutions. To solve this issue, there exists a desire towards developing effective ways to decompose them into less dangerous forms without requiring costly disposable equipment.

Method used

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  • Preparation of resin microspheres of resin microspheres in printing and dyeing wastewater treatment and application thereof
  • Preparation of resin microspheres of resin microspheres in printing and dyeing wastewater treatment and application thereof
  • Preparation of resin microspheres of resin microspheres in printing and dyeing wastewater treatment and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0033] A preparation method of resin microspheres, specifically comprising the following steps:

[0034] 1) 5-chloromethyl-8-hydroxyquinoline is prepared by reacting 8-hydroxyquinoline as raw material with formaldehyde solution and concentrated hydrochloric acid;

[0035] 2) Dissolve the prepared 5-chloromethyl-8-hydroxyquinoline in acetonitrile, add N,N'-methylenebisacrylamide and potassium carbonate, 5-chloromethyl-8-hydroxyquinoline, N , The molar mass ratio of N'-methylenebisacrylamide and potassium carbonate is 4:1.5:2.0, stirred and reacted at 50°C for 20 hours, filtered while hot, filtered again and washed with distilled water to obtain alkylated The reaction product is dried for subsequent use;

[0036]3) Stir and mix hydroxyethyl methacrylate, ferulic acid, ethylene glycol dimethacrylate and deionized water, then add the alkylated product to it, heat up to 60°C, and react under nitrogen protection for 20 -30min, then add ammonium persulfate, continue to react for 20...

Embodiment 2

[0048] A preparation method of resin microspheres, specifically comprising the following steps:

[0049] 1) 5-chloromethyl-8-hydroxyquinoline is prepared by reacting 8-hydroxyquinoline as raw material with formaldehyde solution and concentrated hydrochloric acid;

[0050] 2) Dissolve the prepared 5-chloromethyl-8-hydroxyquinoline in acetonitrile, add N,N'-methylenebisacrylamide and potassium carbonate, 5-chloromethyl-8-hydroxyquinoline, N , The molar mass ratio of N'-methylenebisacrylamide and potassium carbonate is 3:1.5:2.0, stirred and reacted at 50°C for 20 hours, filtered while hot, filtered again and washed with distilled water to obtain alkylated The reaction product is dried for subsequent use;

[0051] 3) Stir and mix hydroxyethyl methacrylate, ferulic acid, ethylene glycol dimethacrylate and deionized water, then add the alkylated product to it, heat up to 60°C, and react under nitrogen protection for 20 -30min, then add ammonium persulfate, continue to react for 2...

Embodiment 3

[0063] A preparation method of resin microspheres, specifically comprising the following steps:

[0064] 1) 5-chloromethyl-8-hydroxyquinoline is prepared by reacting 8-hydroxyquinoline as raw material with formaldehyde solution and concentrated hydrochloric acid;

[0065] 2) Dissolve the prepared 5-chloromethyl-8-hydroxyquinoline in acetonitrile, add N,N'-methylenebisacrylamide and potassium carbonate, 5-chloromethyl-8-hydroxyquinoline, N , The molar mass ratio of N'-methylenebisacrylamide and potassium carbonate is 3:1.2:1.5, stirred and reacted at 50°C for 20 hours, filtered while hot, filtered again and washed with distilled water to obtain alkylated The reaction product is dried for subsequent use;

[0066] 3) Stir and mix hydroxyethyl methacrylate, ferulic acid, ethylene glycol dimethacrylate and deionized water, then add the alkylated product to it, heat up to 70°C, and react under nitrogen protection for 20 After -30 min, ammonium persulfate was added, and the reactio...

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Abstract

The invention provides a preparation method of resin microspheres, which comprises the following steps: preparing 5-chloromethyl-8-hydroxyquinoline by using 8-hydroxyquinoline as a raw material, reacting with N,N'-methylene bisacrylamide to obtain an alkylated monomer, and carrying out a cross-linking polymerization reaction on the alkylated monomer, hydroxyethyl methacrylate, ferulic acid and ethylene glycol dimethacrylate to obtain resin microspheres; the invention also provides a method for treating printing and dyeing wastewater by using the resin microspheres. The method specifically comprises the following steps: rough filtration, pH adjustment, coagulating sedimentation, sand filtration, oxidative degradation, heavy metal adsorption, activated carbon decolorization, pH adjustment again and discharge or reuse. The resin microsphere disclosed by the invention has a three-dimensional network structure, has strong oxidation resistance, can efficiently degrade organic matters when being applied to printing and dyeing wastewater treatment, does not cause secondary pollution, has high heavy metal ion adsorption capacity, is easy to desorb and recycle, and can be better applied to industrial wastewater treatment.

Description

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Claims

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Application Information

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Owner 闫娟
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