A kind of hydrotalcite-assisted method for preparing vanadium phosphorus oxygen catalyst
A technology of hydrotalcite and vanadium phosphorus oxide, which is applied in the direction of chemical instruments and methods, catalyst activation/preparation, physical/chemical process catalysts, etc., can solve the problems of insignificant effect, achieve selectivity and conversion rate improvement, low cost, Improve the effect of activity and selectivity
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[0017] An embodiment of the present invention provides a method for preparing a hydrotalcite-assisted vanadium-phosphorus-oxygen catalyst, which includes the following steps:
[0018] Preparation of vanadium phosphorus oxide precursor: vanadium source, benzyl alcohol and C 3 ~C 8 The monohydric alcohol is mixed to obtain a mixture, then a phosphorus source is added, the temperature is raised to 100°C to 200°C, the reaction is continued, the product is filtered and dried, and the vanadium phosphorus oxide precursor is obtained;
[0019] Preparation of hydrotalcite additive: Dissolve water-soluble inorganic zinc source, inorganic magnesium source, and inorganic aluminum source in water, add alkali source, heat to 65-200°C for reaction, age for 6-12 hours after cooling down, filter, wash, dry, and Roasting at 350-550°C to obtain the hydrotalcite additive;
[0020] The hydrotalcite additive is mixed with the vanadium phosphorus oxygen precursor according to a mass ratio of 1-10:...
Embodiment 1
[0031] Preparation of Vanadium Phosphate Precursor
[0032] Weigh 13.5g V 2 o 5 Mix with benzyl alcohol and isobutanol, heat and reflux at 135°C for 3h under mechanical stirring, then cool down to 80°C, add 9.4mL of phosphoric acid with a mass fraction of 85wt%, raise the temperature to 135°C, and heat to reflux for 16h under continuous stirring Afterwards, the obtained product is filtered and dried to obtain a solid and dried to obtain a vanadium phosphorus oxide precursor.
[0033] Preparation of hydrotalcite additives: Zn 2 Mg 0.2 Al 1 -LDO
[0034] Molebi Zn 2+ :Mg 2+ :Al 3+ Weigh Zn(NO 3 ) 2 ·6H 2 The mass of O is 11.91g, Mg(NO 3 ) 2 ·6H 2 The mass of O is 1.03g, Al(NO3 ) 2 9H 2 The quality of O is 7.5g, the metal salt that weighs is put into 500mL there-necked flask, then adds 12.68g urea (n 尿素 =3.3×n(Zn 2+ +Mg 2+ +Al 3+ )) Then add 200mL of water, react at 120°C for 6h under magnetic stirring, then age for 12h, filter with suction, wash, and dry to o...
Embodiment 2
[0038] Preparation of Vanadium Phosphate Precursor
[0039] Weigh 13.5g V 2 o 5 Mix with benzyl alcohol and isobutanol, heat and reflux at 135°C for 3h under mechanical stirring, then cool down to 80°C, add 9.4mL of phosphoric acid with a mass fraction of 85%wt, raise the temperature to 135°C, and heat to reflux for 16h under continuous stirring Afterwards, the obtained product is filtered and dried to obtain a solid and dried to obtain a vanadium phosphorus oxide precursor.
[0040] Preparation of hydrotalcite additives: Zn 2 Mg 0.5 Al 1 -LDO
[0041] Molebi Zn 2+ :Mg 2+ :Al 3+ Weigh Zn(NO 3 ) 2 ·6H 2 The mass of O is 11.91g, Mg(NO 3 ) 2 ·6H 2 The mass of O is 2.56g, Al(NO 3 ) 2 9H 2 The quality of O is 7.5g, the metal salt that weighs is put into 500mL there-necked flask, then adds 13.87g urea (n 尿素 =3.3×n(Zn 2+ +Mg 2+ +Al 3+ )), reacted at 120°C for 6h under magnetic stirring, then aged for 12h, suction filtered, washed, and dried to obtain Zn 2 Mg 0....
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