The invention discloses a preparation method, a product and application of a CuS/GO/MWCNTs composite nanoparticle modified electrode. The method includes the steps that a multi-wall carbon nanotube isactivated, wherein the multi-wall carbon nanotube is activated in an H2SO4/HNO3 mixed solution, diluted, filtered and dried; a CuS/GO/MWCNTs composite material is prepared, wherein the activated multi-wall carbon nanotube is weighed and dissolved in water, graphene oxide colloidal sol is added, a uniform solution is obtained through ultrasonic dispersion, copper nitrate, polyvinylpyrrolidone andthiourea are added, stirring is performed, heating is performed for a reaction, after the reaction is ended, cooling, rinsing and drying are performed, and the CuS/GO/MWCNTs composite material is obtained. With the CuS/GO/MWCNTs composite nanoparticle modified electrode, the effect of detecting hydrogen peroxide is quite good, the threshold of detection is 0.6 microns, the linear detection range is 0.45-60 millimeters, the application potential is lower than 0.31 V, and the detection sensitivity is up to 386 microamperes/{millimeter*centimeter <2>}.