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A carbon/silicon carbide dual continuous phase composite material and its preparation method

A dual-continuous phase and composite material technology is applied in the field of carbon/silicon carbide dual-continuous phase composite materials and their preparation, which can solve the problems of high price, high cost, and long composite process cycle of composite materials, and achieve excellent high-temperature mechanical properties. , high Young's modulus, excellent corrosion resistance

Active Publication Date: 2022-05-20
HUNAN KINGBO CARBON CARBON COMPOSITES CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the high cost of carbon fiber and its prefabricated body, the composite process cycle is very long, resulting in high prices for such composite materials

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment l

[0032] First, 20wt% of silicon carbide powder (0.5 micron), 15wt% of silicon carbide powder (30 microns), and 65wt% of silicon carbide powder (85 microns) were used as mixtures, plus 3wt% of sodium carbonate and 4wt% of polystyrene Ethylene glycol and 3wt% sodium cellulose were mixed for 1 hour, then 25wt% of pure water was added, kneaded for 2 hours, stale for 24 hours, and vacuum muddled three times. Shaped by extrusion, dried in a microwave drying oven at 100°C for 12 hours to obtain a silicon carbide green body, placed in a sintering furnace, controlled furnace pressure 2 As diluent gas, control carbon source gas and N 2 The volume ratio of the silicon carbide body is 1:3; the surface temperature of the silicon carbide body is controlled at 1200°C, the furnace pressure is 10kPa, and the deposition time is 120 hours. That is, a carbon / silicon carbide bicontinuous phase structure composite material is obtained.

[0033] The performance test is carried out to the finished sa...

Embodiment 2

[0035] The process of this example is the same as that of Example 1, except that some process parameters are changed: CVI carbon vapor deposition, the surface temperature of the silicon carbide body is controlled at 1000° C., and the deposition time is 100 hours.

[0036] The performance test identical to embodiment 1 is carried out to the finished sample of present embodiment, the result is as follows: bulk density 2.76g / cm 3 , porosity 4.6%, apparent porosity 0.8%, Young's modulus 308GPa, 1200°C flexural strength 106MPa, thermal expansion coefficient 2.6×10 -6 / K, thermal conductivity 28W / (m K), acid and alkali resistance 1~14, thermal shock resistance tested by air quenching method, repeated thermal cycle times 46, product impurity content 0.03%.

Embodiment 3

[0038] The process of this embodiment is the same as that of Example 1, except that some process parameters have changed: the raw and auxiliary materials adopt 30wt% silicon carbide powder (0.8 micron), 20wt% silicon carbide powder (20 microns), and 50wt% silicon carbide powder (55 microns) as a mixture, plus 2wt% of sodium carbonate, 0.5wt% of polyethylene glycol and 0.5wt% of cellulose sodium to prepare a silicon carbide green body with a porosity of 26%.

[0039] The performance test identical to embodiment 1 is carried out to present embodiment finished product sample, and the result is as follows: bulk density 2.87g / cm 3 , porosity 3.1%, apparent porosity 0.6%, Young's modulus 320GPa, 1200°C flexural strength 117MPa, thermal expansion coefficient 3.5×10 -6 / K, thermal conductivity 32W / (m·K), acid and alkali resistance 1~14, thermal shock resistance tested by air quenching method, repeated thermal cycle times 55, product impurity content 0.03%.

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PUM

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Abstract

The invention relates to a carbon / silicon carbide double continuous phase composite material and a preparation method thereof. The composite material is composed of recrystallized silicon carbide and pyrolytic carbon, wherein the mass fraction of recrystallized silicon carbide in the composite material is 80-83%: the mass fraction of pyrolytic carbon in the composite material is 17-20%, so The porosity of the composite material is less than or equal to 5%. The preparation method is as follows: the silicon carbide powder is mixed with a pore-forming agent and a forming agent to obtain a mixture, the mixture is pressed and formed to obtain a silicon carbide green body, and the silicon carbide green body is dried and sintered to obtain a silicon carbide green body with a porosity of 25% to 35%. The carbon / silicon carbide bicontinuous phase composite material is obtained by pyrolyzing the silicon carbide body through chemical vapor deposition. The obtained carbon / silicon carbide dual continuous phase composite material has good high temperature mechanical properties, good thermal shock resistance and excellent corrosion resistance.

Description

technical field [0001] The invention relates to a carbon / silicon carbide dual continuous phase composite material and a preparation method thereof, belonging to the technical field of composite material preparation. Background technique [0002] The hardness of silicon carbide ceramics is second only to that of diamond. It has outstanding physical and chemical properties such as small thermal expansion coefficient, high thermal conductivity, good chemical stability, high wear resistance, good mechanical properties and oxidation resistance at high temperatures. [0003] In the actual preparation process, the most important forming methods of silicon carbide ceramics are: reaction sintered silicon carbide (RBSiC), recrystallized silicon carbide (RSiC), and precursor transformation (PIP); [0004] Among them, the RBSiC process can prepare SiC parts with complex shapes, and the sintering temperature is low, but the purity of RBSiC is low, and there is a large amount of surplus s...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/565C04B35/622C04B35/64
CPCC04B35/565C04B35/622C04B35/64C04B2235/422C04B2235/614C04B2235/77C04B2235/96
Inventor 廖寄乔李军邓华峰龚智李丙菊石磊刘学文王跃军
Owner HUNAN KINGBO CARBON CARBON COMPOSITES CO LTD