Bio-based water-based light-cured nail polish and preparation method thereof
A bio-based, light-curing technology, used in manicure, cosmetic preparations, cosmetics, etc., can solve the problems of wear resistance and water resistance that need to be further improved, insufficient binding force of water-based nail polish, and easy peeling of nail polish. To achieve the effect of improving wear resistance and water resistance, good hydrophilicity and rich sources
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Embodiment 1
[0099]In this example, a biological aquiferic photocurable nail polish includes a bio-based aqueous polyurethane emulsion and auxiliary agent; the preparation of the biological aquiferous polyurethane emulsion is based on weight percentage. Includes the following components:
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[0102]Among them, the modified soybean oil polyol has a number average molecular weight of 1000; modified soybean oil polyols from South Korea SK Co., Ltd., catalyst Bicat 8118 is purchased from US leading chemical companies, allyl alcohols from DIC Co., Ltd., Irgacure- 184 purchased from Germany BASF.
[0103]The method of preparing the biological aquiferous polyurethane emulsion includes the following steps:
[0104](1) The modified soybean oil polyol is mixed with 2,2-dihydroxymethyl proppropate (DMPA) at 50 ° C for 15 min, followed by bicyclohexylmetane diisocyanate (HMDI), hexamethylene diisocyanate (HDI) ) And catalyst Bicat 8118, temperature rise to 85 ° C for 2.5 h, to a system viscosity of 4000 MPa...
Embodiment 2
[0116]In this example, a biological aquiferic photocurable nail polish includes a bio-based aqueous polyurethane emulsion and auxiliary agent; the preparation of the biological aquiferous polyurethane emulsion is based on weight percentage. Includes the following components:
[0117]
[0118]Among them, the number average molecular weight of the polytex hydrofuran is 2000, and the number average molecular weight of the modified soybean oil polyol is 1000; the modified soybean oil polyol is purchased from South Korea SK Co., Ltd., catalyst Bicat 8118 is purchased from the US leading chemical company Allyl alcohols were purchased from DIC Corporation, IRGAcure-184 was purchased from Germany BASF.
[0119]The method of preparing the biological aquiferous polyurethane emulsion includes the following steps:
[0120](1) The polytetrahydrofuranyl diol, the modified soybean oil polyol is mixed with 2,2-dihydroxymethylbutyric acid (DMBA) at 80 ° C for 30 min, followed by isophorone diisocyanate (IPDI), ...
Embodiment 3
[0131]In this example, a biological aquiferic photocurable nail polish includes a bio-based aqueous polyurethane emulsion and auxiliary agent; the preparation of the biological aquiferous polyurethane emulsion is based on weight percentage. Includes the following components:
[0132]
[0133]Among them, the number average molecular weight of the polytetilifuranol diol is 2000, the polycarbonate diol has a number average molecular weight of 2000, and the number average molecular weight of the modified castor oil polyol is 1000; the modified castor oil polyol is purchased from South Korea SK The club, catalyst Bicat 8118 was purchased from the US leading chemical company, IRGAcure-127 purchased from BASF in Germany.
[0134]The method of preparing the biological aquiferous polyurethane emulsion includes the following steps:
[0135](1) The polytetrahydrofuran nanol, the polycarbonate diol, and the modified castor oil polyol were mixed at 60 ° C at 60 ° C for 25 min at 60 ° C, followed by bicyclic...
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