Low-temperature-sintered silver paste and preparation method thereof
A low-temperature sintering and silver paste technology, which is applied in the field of solar cells, can solve problems such as unsuitability for large-scale production, complicated preparation methods, and expensive nano-silver powder, and achieve the effects of filling sintering voids, improving yield, and reducing damage
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Embodiment 1
[0062] Select the silver powder with a mass fraction of 83.6wt%, 10wt% organic vehicle, 6wt% low softening point glass powder, and 0.4wt% aluminum-silicon alloy powder to form the low-temperature sintered silver paste of this embodiment. Its comprehensive properties are as follows: As shown in Table 1, it can be seen that the sintering temperature of the low-temperature sintered silver paste obtained in this embodiment is 700°C, and the surface of the sintered silver paste is observed by a profiler to be smooth, with fewer voids and a contact resistivity of 0.5mΩ·cm -2 , the adhesion force is 4.3N, and the photoelectric conversion efficiency range is 21.35%.
Embodiment 2
[0064] Silver powder with a mass fraction of 90wt%, 7.1wt% organic vehicle, 2wt% low-softening point glass powder, and 0.9wt% aluminum-boron alloy powder additive form the low-temperature sintered silver paste of this embodiment. As shown in Table 1, it can be seen that the sintering temperature of the low-temperature sintered silver paste obtained in this example is 720°C, and the surface of the sintered silver paste is observed by a profiler to be smooth, with fewer voids and a contact resistivity of 0.5mΩ·cm -2 , the adhesion force is 4.1N, and the photoelectric conversion efficiency range is 21.25%.
Embodiment 3
[0066] Silver powder with a mass fraction of 80wt%, 9.99wt% organic vehicle, 10wt% low-softening point glass powder, and 0.01wt% aluminum-silicon-boron alloy powder were selected to form the low-temperature sintered silver paste of this embodiment. As shown in Table 1, it can be seen that the sintering temperature of the low-temperature sintered silver paste obtained in this example is 715°C, and the surface of the sintered silver paste is observed by a profiler to be smooth, with fewer voids and a contact resistivity of 0.5mΩ·cm -2 , the adhesion force is 4.2N, and the photoelectric conversion efficiency range is 21.45%.
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