Gradient composite bioactive ceramic coating material and preparation method thereof
A technology of bioactive ceramics and coating materials, which is applied in coatings and metal material coating processes, etc., can solve the problems of the reliability of bioactive ceramic coatings not meeting the requirements, thin coatings, and inflammatory reactions, and achieve good Application prospects, simple process flow, and the effect of reducing decomposition
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Embodiment 1
[0049] A gradient composite bioactive ceramic coating material of the present invention, the structure schematic diagram is as figure 1 As shown, it includes a titanium substrate 1 and a gradient composite bioactive ceramic coating covering the surface of the titanium substrate. The gradient composite bioactive ceramic coating includes Ag layer 2, HA / Ag composite layer 3, and HA layer 4 from bottom to top in sequence. Among them, the Ag content in the HA / Ag composite layer 3 accounts for 25%, the HA content accounts for 75%, the thickness of the Ag layer 2 is about 200-240um, the thickness of the HA / Ag composite layer 3 is about 180-200um, and the thickness of the HA layer 4 is about 220-260um.
[0050] The preparation method of the gradient composite bioactive ceramic coating material of this embodiment comprises the following steps:
[0051] (1) Preparation of raw materials and pretreatment of raw materials:
[0052] Use an electronic analytical balance to weigh 0.2g of Ag...
Embodiment 2 and Embodiment 3
[0077] The difference between Examples 2, 3 and Example 1 is that the broadband laser process conditions in steps (2), (3) and (4) are different (as shown in Table 1), and the other preparation processes are exactly the same as in Example 1.
[0078] The laser process parameters used in table 1 embodiment 1,2,3
[0079]
[0080] The XRD pattern of the gradient composite bioactive ceramic coating that embodiment 2,3 prepares is as Figure 16 Shown, from this XRD collection of illustrative plates composition phase as can be known, within the scope of protection of the present invention, under the condition of different laser process parameters, all can be prepared to contain HA (hydroxyapatite), TCP (tricalcium phosphate), TTCP ( Ceramic coatings of active substances such as tetracalcium phosphate); at the same time, from the diffraction peak intensity of the composition phase of the XRD spectrum, it can also be known that with the increase of the laser power parameter in ste...
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Abstract
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