Positive electrode active material for lithium ion secondary battery, method for manufacturing positive electrode active material for lithium ion secondary battery, and lithium ion secondary battery

A positive electrode active material and secondary battery technology, which is applied in the direction of secondary batteries, battery electrodes, chemical instruments and methods, etc., can solve the problems of thermal stability reduction and achieve the effect of inhibiting oxygen release

Pending Publication Date: 2021-10-01
SUMITOMO METAL MINING CO LTD
View PDF1 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, if the nickel ratio is increased, as a negative effect, thermal stability decreases

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Positive electrode active material for lithium ion secondary battery, method for manufacturing positive electrode active material for lithium ion secondary battery, and lithium ion secondary battery
  • Positive electrode active material for lithium ion secondary battery, method for manufacturing positive electrode active material for lithium ion secondary battery, and lithium ion secondary battery

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0162] (1) Preparation of positive electrode active material

[0163] The general formula with Ni as the main component: Ni 0.90 co 0.07 Al 0.03 (OH) 2 The metal composite hydroxide shown was dried by heating at 120° C. for 6 hours in air (oxygen concentration: 21% by volume) airflow (drying step).

[0164] Next, the dried metal composite hydroxide obtained in the drying step was heat-treated at 600° C. for 6 hours in an air current (heat treatment step). Thus, as a heat-treated metal complex compound, the general formula: Ni 0.90 co 0.07 Al 0.03 The metal composite oxide represented by O.

[0165] Next, Li / Me, which is the ratio of the number of atoms of lithium (Li) to the number of atoms of metals other than lithium (Me) in the resulting lithium mixture, was set to 1.01 for the heat-treated metal complex compound and lithium hydroxide obtained in the heat treatment step. The method was weighed and mixed sufficiently to obtain a lithium mixture (mixing process).

[...

Embodiment 2

[0198] In the crushing process, the particle size distribution is adjusted so that [(d90-d10) / volume average particle diameter] becomes 1.21, except that, the same operation as in Example 1 is carried out to obtain a positive electrode active material and a secondary battery, and carry out its evaluation. The results are shown in Table 1.

Embodiment 3

[0200] In the crushing process, the particle size distribution is adjusted so that [(d90-d10) / volume average particle diameter] becomes 0.88, except that, the same operation as in Example 1 is carried out to obtain a positive electrode active material and a secondary battery, and carry out its evaluation. The results are shown in Table 1.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
thicknessaaaaaaaaaa
thicknessaaaaaaaaaa
particle sizeaaaaaaaaaa
Login to view more

Abstract

A positive electrode active material for a lithium ion secondary battery contains a lithium metal composite oxide containing lithium (Li), nickel (Ni), cobalt (Co), and an element M (M) in the mass ratio Li : Ni : Co : M = 1+a : 1-x-y : x : y (where -0.05 <= a <= 0.50, 0 <= x <= 0.35, 0 <= y <= 0.35, and the element M is at least one chosen from the group consisting of Mg, Ca, Al, Si, Fe, Cr, Mn, V, Mo, W, Nb, Ti, Zr, and Ta). If a grain of the lithium metal composite oxide during charging at 4.3V(vs. Li+ / Li) is measured by STEM-EDS, the thickness of an NiO layer is 200 nm or less and [(d90-d10) / volume-average particle diameter], indicating the spread of granularity distribution, is 1.25 or less.

Description

technical field [0001] The present invention relates to a positive electrode active material for a lithium ion secondary battery, a method for producing the positive electrode active material for a lithium ion secondary battery, and a lithium ion secondary battery. Background technique [0002] In recent years, with the popularization of portable electronic devices such as mobile phones and notebook personal computers, the development of small and lightweight non-aqueous electrolyte secondary batteries with high energy density has been strongly desired. In addition, as batteries for electric vehicles (xEV) such as electric vehicles, various hybrid vehicles, and fuel cell vehicles, the development of secondary batteries excellent in capacity density is strongly desired. [0003] As a secondary battery satisfying such a request, there is a lithium ion secondary battery. A lithium-ion secondary battery is composed of a negative electrode, a positive electrode, an electrolyte, ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/525C01G53/00H01M4/36H01M4/505
CPCH01M4/525Y02E60/10C01P2004/54C01P2004/61C01P2006/12C01G53/40C01P2002/54C01G53/42C01P2006/11H01M10/0525C01G53/44C01P2004/04C01P2004/51
Inventor 东间崇洋小川贵裕松浦祥之渔师一臣
Owner SUMITOMO METAL MINING CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap