This invention relates to the field of
lithium-
ion battery
cathode material technology, specifically a high-performance
lithium-rich
manganese-based
cathode material based on pretreated
boron nitride, its preparation method, and its application. The preparation method includes: introducing hydroxyl and amino groups onto the surface of
boron nitride nanosheets; preparing a composite precursor
powder by mixing a
nickel-
cobalt-
manganese hydroxide precursor, a
lithium source, TiO2, a
phosphorus source, and pretreated
boron nitride; sequentially performing conventional pre-
calcination, a first-segment
Joule heat treatment, and a second-segment
Joule heat treatment; performing a third-segment instantaneous
Joule heat treatment, followed by
quenching; by introducing a surface-functionalized high
thermal conductivity boron nitride network into the bulk phase of the material, and combining a programmed sequential heat treatment of "pre-
calcination-two-segment Joule heat treatment" with instantaneous surface melting and
quenching, this method effectively solves the inherent thermal gradient problem of the
Joule heating method, simultaneously achieving high bulk phase homogenization and surface stabilization, resulting in a product with excellent comprehensive electrochemical performance.