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258results about How to "Increase liquid absorption" patented technology

Polymer lithium ion battery and diaphragm thereof

The invention belongs to the technical field of polymer lithium ion batteries, in particular to a diaphragm for the polymer lithium ion battery. The diaphragm comprises a multihole base material, wherein an inorganic substance coating layer and an organic substance coating layer are coated on at least one surface of the multihole base material; and the organic substance coating layer is in island-type and / or linear distribution and coated on the surface of the multihole base material and / or the inorganic substance coating layer. Compared with the prior art, due to the inorganic substance coating layer, the diaphragm can keep relatively high heat stability and mechanical performance, so that the lithium ion battery has high safety performance; the organic substance coating layer has high imbibition swelling capacity, and an interface has high stability, so that the manufactured lithium ion battery has perfect mechanical performance; due to the distribution characteristic of the organic substance coating layer, spaces are provided for charging and discharging processes of a pole piece and a circulation process; and the problem of deformation of the polymer lithium ion battery is well solved. Furthermore, the invention also discloses a polymer lithium ion batter with the diaphragm.
Owner:NINGDE AMPEREX TECH +1

Composite coating lithium-ion battery separator and preparation method thereof

The invention relates to a composite coating lithium-ion battery separator. The composite coating lithium-ion battery separator is composed of a base film, an aramid fiber coating coated on one side of the base film and a PVDF coating coated on the other side of the base film; the aramid fiber coating is obtained by an aramid fiber sizing agent after coating, soaking and drying, and the thickness of the coating is 0.5-4 microns; the PVDF coating is obtained by a water-based PVDF sizing agent after coating and drying, and the thickness of the coating is 0.1-2 microns. The invention also provides a preparation method of the separator. According to the composite coating lithium-ion battery separator and the preparation method thereof, the separator has the characteristics that the aramid fiber coating is good in thermal performance and mechanical performance and the PVDF coating has good wettability and liquid retention property for electrolytes, can effectively adhere batteries and pole pieces and is little in environmental pollution, and is beneficial for preparing lithium-ion batteries with longer cycle life and higher safety. Tests indicate that the separator has good air permeability, liquid absorption rate, thermal contraction and tensile strength, so that the cycle life of the batteries can be obviously prolonged by using the lithium-ion batteries prepared by the separator.
Owner:CANGZHOU MINGZHU SEPARATOR TECH CO LTD

Electrolyte film and porous substrate and preparation thereof, lithium ion secondary battery

The invention relates to a gel-type polymer electrolyte film for a lithium ion secondary battery and a process for preparation, and a lithium ion secondary battery which contains the electrolyte film. The gel-type polymer electrolyte film for the lithium ion secondary battery can be obtained through the following method: preparing polyvinylidene fluoride nonwoven through the electrostatic spinning method, making the surface of the polyvinylidene fluoride nonwoven activate through radiating electron beams for the obtained the polyvinylidene fluoride nonwoven in air, contacting a methyl methacrylate monomer and the polyvinylidene fluoride nonwoven after the surface activation, thereby obtaining the polyvinylidene fluoride nonwoven whose surface is grafted with polymethyl methacryate. Furthermore, the lithium ion battery electrolyte film can be obtained through making the polyvinylidene fluoride nonwoven whose surface is grafted with polymethyl methacryate absorbs a certain amount of electrolytic solution. The invention develops the respective advantages in the lithium ion battery owing to using the polyvinylidene fluoride nonwoven whose surface is grafted with polymethyl methacryate, compared with singly using polyvinylidene fluoride or polymethyl methacryate or the both simple composite, and eliminates the disadvantages caused by singly using one material or several materials. The electrolyte film has high ion electrical conductivity under ambient temperature after absorbing the electrolytic solution, and can manifest excellent heavy-current discharge performance and circulation stability after being assembled in the batteries.
Owner:PANASONIC CORP +1

Synthetic method of anti-compression and anti-bacterial super absorbent polymer for physiology

The invention relates to a super absorbent polymer for physiology, in particular to an anti-compression and anti-bacterial super absorbent polymer still with high water absorbency under compression and with natural anti-bacterial property. The super absorbent polymer adopts the following technical scheme: taking polyvinyl alcohol with the polymer long chain rich in hydroxy as the interpenetrating polymer network (IPN), carboxymethyl chitosan with bioactivity and natural antibacterial property as the graft polymer and acrylate as the main comonomer, being combined with a cross-linking agent with molecular chains different in length, adopting the three-stage complex initiation system and realizing interpenetrating of polyvinyl alcohol and grafting of carboxymethyl chitosan by way of aqueous solution radical copolymerization to prepare the super absorbent resins with regular granularity, uniform crosslinking and less residual monomers. The invention develops multi-component composite surface treatment solution to carry out surface treatment on the super absorbent resins, thus further reducing the residual monomers, forming gradient crosslinking on the surfaces of the super absorbent resins and finally preparing the anti-compression and anti-bacterial super absorbent polymer for physiology. The super absorbent polymer is white without yellow spots, has regular granularity, inadherent surface, good liquidity, high absorption rate and absorption, excellent filtration property and less residual monomers and is against compression and tolerant to salt and free of gel plugging.
Owner:NANTONG KEYI CHEM

Non-woven fabric based multi-layer composite diaphragm for lithium ion battery and preparation method of multi-layer composite diaphragm

ActiveCN105470435AImprove high temperature closed cell performanceHigh tensile strengthCell component detailsEmulsionInorganic particle
The invention discloses a non-woven fabric based multi-layer composite diaphragm for a lithium ion battery and a preparation method of the multi-layer composite diaphragm. The non-woven fabric based multi-layer composite diaphragm comprises a non-woven fabric base material, an intermediate thermoplastic material coating and an outer-layer ceramic coating. The preparation method comprises the following steps of (1) mixing and uniformly stirring thermoplastic material particles, a binding agent and a solvent to form a mixed emulsion 1, and mixing and uniformly stirring inorganic particles, the binding agent and the solvent to form a mixed emulsion 2; and (2) uniformly applying the mixed emulsion 1 on one surface of the non-woven fabric base material, drying the mixed emulsion 1 to form the thermoplastic material coating, applying the mixed emulsion 2 on the thermoplastic material coating, drying the mixed emulsion 2 to form a ceramic coating, and rolling the ceramic coating to prepare a three-layer composite diaphragm. The three-layer composite diaphragm prepared according to the method has high-temperature obturator performance, favorable liquid absorption capability and mechanical property.
Owner:TIANNENG SAFT ENERGY JOINT CO

Preparation method of special composite coating diaphragm for lithium battery

The invention discloses a special composite coating diaphragm for a lithium battery. The special composite coating diaphragm comprises a microporous membrane, resin layers, ceramic layers and acrylicadhesive layers; the special composite coating diaphragm is characterized in that the resin layers coat the upper surface and the lower surface of the microporous membrane; one ceramic layer coats theouter side of each resin layer; one acrylic adhesive layer coats the outside of each ceramic layer; first micropores are formed in the microporous membrane; second micropores are formed in each resinlayer; third micropores are formed in each ceramic layer; and fourth micropores are formed in each acrylic adhesive layer. A preparation method of the special composite coating diaphragm for the lithium battery comprises the following steps of surface modification of boehmite alumina, preparation of the microporous membrane, preparation of a polymer composite membrane, preparation of modified boehmite alumina slurry, coating of the modified boehmite alumina slurry and bonding forming of an acrylic adhesive, thereby obtaining the special composite coating diaphragm for the lithium battery. According to the composite coating diaphragm, the security problem of a high-energy density battery core can be well solved.
Owner:桑顿新能源科技(长沙)有限公司

Heat-resisting lithium battery diaphragm and preparation method thereof

The invention provides a heat-resisting lithium battery diaphragm and a preparation method thereof. The method comprises the following steps: (a) weighing a component A, which comprises the following materials: polyether polyol, a foaming agent, a catalyst, a stabilizer and a fire retardant in weight ratio, pouring the materials into stirring equipment and mixing the materials evenly; (b) weighing a component B MDI in the weight ratio, respectively feeding the weighed materials of the component A and the material of the component B into a material jar A and a material jar B of a polyurethane foaming machine, stirring the materials in the polyurethane foaming machine, filling the materials into a rectangular or square mold, and carrying out foaming molding; and (c) putting a pelletized product which is molded in a foaming manner on a special foam horizontal cutting machine, cutting the pelletized product into slices according to the thickness requirement, and carrying out punch forming on the slices according to the size specification requirements, wherein the thicknesses of the slices are 5-41 microns; the porosity is 70%-75%; and the air permeability is 15-30 sec / 100cc. The heat-resisting lithium battery diaphragm has the advantages of high porosity, low thickness, high absorption amount, high ion permeability, low resistance, good compressive property, stable electrochemical properties, simplicity in manufacturing process, low cost, high quality and the like.
Owner:浙江清优材料科技有限公司

Composite negative electrode material and preparation method therefor and lithium ion battery

The invention relates to a composite negative electrode material and a preparation method therefor and a lithium ion battery. The composite negative electrode material comprises a carbonaceous material with an embedding structure and formed by embedding first carbon component small particles into a second carbon component framework carrier, wherein the first carbon component is converted by a small particle precursor (green coke and/or burning coke and/or carbon microspheres); and the second carbon component framework carrier is converted by a binder. The composite negative electrode materialdisclosed in the invention combines the "embedding type" structure and a "gradient type crystal form" structure; the small particles of different appearances are embedded in the relatively thick framework carrier to form a bigger particle; the small particles embedded in the interior adopt a graphite structure with the best crystal form; the framework carrier adopts a graphite structure with the ordinary crystal form; and the outermost layer also can be coated with an amorphous carbon structure with the worst crystal form. The composite negative electrode material provided by the invention hasstructural stability, high orientation, low expansion, high rate capability, excellent liquid absorption performance and cycle performance, and can satisfy various kinds of demands in the application.
Owner:贝特瑞(四川)新材料科技有限公司
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