Unlock instant, AI-driven research and patent intelligence for your innovation.

A kind of surface modification method of polyetheretherketone clamp

A polyetheretherketone, surface modification technology, applied in the direction of coating, etc., can solve the problems of large difference in molecular segment activity and surface energy, low bonding performance of fluorosilicone rubber, low surface energy, etc., and achieve good application. Prospects, enhanced wettability, improved adhesion effects

Active Publication Date: 2022-06-21
JILIN UNIV
View PDF0 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The molecular structure of fluorosilicone rubber is to introduce a large amount of -(CF 3 )-group, although the molecular chain is somewhat polar, but -(CF 3 )-is a very stable structure with low surface energy, which also leads to low bonding performance between fluorosilicone rubber and PEEK
In addition, the molecular chains of fluorosilicone rubber and polyether ether ketone are in a highly elastic state and a glass state, respectively, and the activity and surface energy of the molecular chain segments are very different, which makes the bonding of the two very difficult.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A kind of surface modification method of polyetheretherketone clamp
  • A kind of surface modification method of polyetheretherketone clamp
  • A kind of surface modification method of polyetheretherketone clamp

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] The injection-molded polyetheretherketone clamp (P type, such as figure 1 (shown) the surface was cleaned and dried, fixed on the workbench, the type of sandblasting was 200 mesh silicon carbide, and the blasting pressure was 1.5MPa to obtain a polyetheretherketone clamp after sandblasting, with a surface roughness of 24 μm; The polyether ether ketone clamp after sandblasting is rinsed in deionized water, dried in a blast drying oven, cooled to room temperature, and taken out for use; according to 10 mL of alkali per gram of sandblasted polyether ether ketone clamp The standard preparation of the aqueous alkali solution, the alkali is the mixed alkali of sodium hydroxide and sodium borohydride, the molar ratio of sodium hydroxide and sodium borohydride is 2:1.5, the concentration of the aqueous alkali solution is 0.8mol / L, the heating and mechanical stirring are turned on, The treatment temperature was 40 °C, the treatment time was 10 h, cooled to room temperature, and ...

Embodiment 2

[0048] The surface of the polyetheretherketone clamp (P type) was cleaned and dried, and then fixed on the workbench. The type of sandblasting was 200 mesh silicon carbide, and the blasting pressure was 1.5MPa to obtain the polyetheretherketone clamp after sandblasting. , the surface roughness is 24 μm; the polyetheretherketone clamp after sandblasting is rinsed in deionized water, dried in a blast drying oven, cooled to room temperature, and taken out for use; The standard preparation of 10mL alkali solution of polyetheretherketone clamps is an alkali aqueous solution. The alkali is a mixed alkali of sodium hydroxide and sodium borohydride, the molar ratio of sodium hydroxide and sodium borohydride is 2:1.5, and the concentration of the alkali aqueous solution is 0.8mol / L, turn on heating and mechanical stirring, the treatment temperature is 60°C, the treatment time is 10h, cooled to room temperature, the treated polyetheretherketone clamp is taken out, placed in dilute hydro...

Embodiment 3

[0050] The surface of the polyetheretherketone clamp (P type) was cleaned and dried, and then fixed on the workbench. The type of sandblasting was 200 mesh silicon carbide, and the blasting pressure was 1.5MPa to obtain the polyetheretherketone clamp after sandblasting. , the surface roughness is 24 μm; the polyetheretherketone clamp after sandblasting is rinsed in deionized water, dried in a blast drying oven, cooled to room temperature, and taken out for use; The standard preparation of 10mL alkali solution of polyetheretherketone clamps is an alkali aqueous solution. The alkali is a mixed alkali of sodium hydroxide and sodium borohydride, the molar ratio of sodium hydroxide and sodium borohydride is 2:1.5, and the concentration of the alkali aqueous solution is 0.8mol / L, turn on heating and mechanical stirring, the treatment temperature is 80 °C, the treatment time is 10 h, cooled to room temperature, the treated polyetheretherketone clamp is taken out, placed in dilute hyd...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle size (mesh)aaaaaaaaaa
surface roughnessaaaaaaaaaa
surface roughnessaaaaaaaaaa
Login to View More

Abstract

The invention provides a method for surface modification of a polyetheretherketone clamp, which belongs to the technical field of polymer materials. In the present invention, the polyether ether ketone clamp is subjected to surface sandblasting treatment, the surface roughness of the clamp is improved, the contact angle of the polyether ether ketone surface is improved, and its wettability is enhanced; on the basis of surface sandblasting treatment, further adoption Surface functionalization treatment with lye can increase the hydrophilic groups on the surface of the polyetheretherketone clamp, further reduce the contact angle, further improve its wettability, and thus improve the adhesion between the clamp and fluorosilicone rubber. After the surface-modified polyetheretherketone clamp prepared by the method of the invention is combined with the fluorosilicone rubber, the bonding strength is ≥3.4N / mm. The surface treatment method of the invention is simple to implement, strong in controllability, and has good application prospects.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a surface modification method of a polyetheretherketone clamp. Background technique [0002] Clamps are often used in the installation and fixing of pipelines, wires and cables, instruments and other products such as aircraft, automobiles and ships. environmental impact. Usually, the clamp is generally composed of a band and a rubber pad. Among them, the band material mainly includes metal band (such as aluminum alloy, structural steel or stainless steel, etc.) and plastic (generally nylon material), etc., while the rubber pad material Most of them are nitrile rubber, ethylene propylene rubber, silicone rubber or fluorosilicone rubber. The metal band material has the disadvantages of heavy weight, large vibration, and not resistant to fog corrosion and oil corrosion. In recent years, polymer materials represented by polyetheretherketone have the advantages of light w...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C08J7/12C08J7/06C08L61/16
CPCC08J7/12C08J7/06C08J2361/16
Inventor 张海博彭亚岚商赢双周晨义徐勤飞杨洋
Owner JILIN UNIV