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A kind of dry granule glaze, dry granule glaze slurry and dry granule glaze porcelain brick

A dry granule glaze and porcelain tile technology, applied in the field of ceramics, can solve the problems of increasing costs, uneven distribution of dry granules, increasing rod nails, etc., and achieves the effects of low equipment requirements, reduced production costs, and reduced production difficulty

Active Publication Date: 2022-05-20
广东道氏陶瓷材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The dry granules of this product stick to the glaze surface through the bonding effect of glue, suspending agent, etc., but this method is limited by the type of additives such as glue and suspending agent, and it is prone to uneven distribution of dry granules , The fluidity of the glaze slurry becomes poor, the dry particles are not firmly bonded, and the glaze slurry is prone to bubbles, etc.
When entering the kiln, the dry particles bonded on the brick surface will be more or less sucked away by the kiln, resulting in lack of glaze and dry particles.
The dry particles that are sucked into the kiln will adhere to the roller table to increase the risk of rod nails, adhere to the top of the kiln, and fall during the production of other products, causing product defects
In addition, some suspending agents also affect the color of dry granules, which greatly affects the performance of the surface of dry granulated glazed porcelain tiles, the overall aesthetics and the excellent rate of tile products, and the application of dry granules increases the cost.
[0004] The existing dry glaze needs to be applied with the help of binders, etc., which increases the difficulty of the process and makes it more difficult to obtain high-quality products, which also leads to high production costs of dry glaze porcelain tiles

Method used

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  • A kind of dry granule glaze, dry granule glaze slurry and dry granule glaze porcelain brick
  • A kind of dry granule glaze, dry granule glaze slurry and dry granule glaze porcelain brick
  • A kind of dry granule glaze, dry granule glaze slurry and dry granule glaze porcelain brick

Examples

Experimental program
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Effect test

preparation example Construction

[0063] In some examples of dry grain glazed porcelain tiles, the preparation method includes:

[0064] Apply base glaze on the green body;

[0065] Apply dry granular glaze slurry on the bottom glaze, and described dry granular glaze slurry is as described in the second aspect of the present invention;

[0066] After the glazing is completed, it is fired and post-treated to obtain dry-grain glazed porcelain tiles.

[0067] In some examples of dry granule glaze porcelain tiles, the thickness of the dry granule glaze layer is 0.2-0.3 mm.

[0068] Below in conjunction with example, further illustrate the technical scheme of the present invention.

[0069] For convenience of comparison, unless otherwise specified, the parts in the following examples all refer to parts by mass. The glaze slurry contains 0.2% to 0.3% sodium tripolyphosphate and 0.1% sodium carboxymethyl cellulose.

Embodiment 1

[0071] A dry grain glaze glaze consisting of frit and raw material, wherein:

[0072] The composition of the frit is: Al 2 o 3 14 parts, SiO 2 55 parts, CaO 8 parts, MgO 3 parts, K 2 O 10 parts, Na 2 1 part of O, 3 parts of ZnO, 6 parts of BaO;

[0073] The composition of the raw material is: Al 2 o 3 9 parts, SiO 2 51 copies, K 2 O 3 parts, Na 2 2 parts of O, 7 parts of ZnO, 12 parts of BaO, 4 parts of MgO, 8 parts of CaO, SO 2 4 parts;

[0074] Mix the frit and the raw material according to the mass ratio of 10:100 and ball-mill it into a glaze slurry, and adjust the specific gravity of the dry glaze slurry to 1.85g / ml;

[0075] Apply a layer of bottom glaze on a 930mm×2930mm biscuit, adopt the glaze pouring process, and apply a glaze amount of 180g; wherein, the composition of the bottom glaze is: Al 2 o 3 30 parts, SiO 2 55 parts, CaO 2 parts, K 2 O 2 parts, Na 2 O 6 parts, ZrO 2 5 parts, adjust the specific gravity of the bottom glaze slurry to 1....

Embodiment 2

[0079] A dry grain glaze glaze consisting of frit and raw material, wherein:

[0080] The composition of the frit is: Al 2 o 3 13 parts, SiO 2 56 parts, CaO 9 parts, K 2 O 9 parts, Na 2 1 part of O, 3 parts of ZnO, 3 parts of MgO, 6 parts of BaO;

[0081] The composition of the raw material is: Al 2 o 3 10 parts, SiO 2 50 copies, K 2 O 2 parts, Na 2 2 parts of O, 7 parts of ZnO, 12 parts of BaO, 4 parts of MgO, 9 parts of CaO, SO 2 4 parts;

[0082] Mix the frit and the raw material according to the mass ratio of 15:100 and ball-mill it into a glaze slurry, and adjust the specific gravity of the dry glaze slurry to 1.86g / ml;

[0083] Apply a layer of bottom glaze on a 930mm×2930mm biscuit, adopt the glaze pouring process, and apply a glaze amount of 180g; wherein, the composition of the bottom glaze is: Al 2 o 3 30 parts, SiO 2 54 parts, CaO 3 parts, K 2 O 3 parts, Na 2 O 6 parts, ZrO 2 4 parts, adjust the specific gravity of the bottom glaze slurry to ...

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Abstract

The invention belongs to the field of ceramics and discloses a dry glaze, a dry glaze slurry and a dry glaze porcelain tile. The dry glaze is composed of frit and raw material with a mass ratio of (10-30):100, wherein the chemical composition of the frit is Al 2 o 3 , SiO 2 , CaO, K 2 O, BaO, ZnO, MgO, Na 2 O composition; the chemical composition of the raw meal is Al 2 o 3 , SiO 2 , CaO, K 2 O, BaO, ZnO, MgO, Na 2 O and SO 2 . The dry glaze can be directly made into glaze slurry for application, which is beneficial to simplify the process requirements and reduce the difficulty of production; the firing time is 50-60 minutes, and the firing temperature is low. Lower, lower energy consumption; more stable formula, adapt to different process conditions and kiln temperature. Compared with ordinary dry granule glaze porcelain tiles or ceramic tiles with dry granule effect, it simplifies the production requirements, reduces the production cost, breaks the complicated process of dry granule + glue / suspending agent, and combines the production process of dry granule glaze with full polishing The process of glaze is synchronized.

Description

technical field [0001] The invention belongs to the field of ceramics, and in particular relates to a dry glaze, a dry glaze slurry and a dry glaze porcelain tile. Background technique [0002] Compared with ordinary full-polished glaze, the glaze surface of dry-granulated glaze is more transparent, which is more suitable for the production of dark products, and the glaze amount of dry-granulated glaze is more than that of ordinary full-polished glaze, so that the polished dry-granulated glaze Glazed ceramic tiles have a smoother glaze surface and smaller water ripples, which is conducive to improving the texture of the glazed surface after polishing, and is more conducive to obtaining high-end ceramic tiles. In the field of bright surface products such as anchor rock slabs and ceramic slabs, dry glaze is more widely used. [0003] At present, the production process of ordinary dry-grain glazed porcelain tiles or tiles with dry-grain effect is to mix pre-made frit particles...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C8/14C03C8/04C03C8/00C04B41/89C04B41/86
CPCY02P40/60
Inventor 李森林刘晶陈奕
Owner 广东道氏陶瓷材料有限公司