The invention discloses a hydrophobic-surface treatment agent and a preparation method thereof. The preparation method comprises adding 1,1,1,3,5,5,5-heptamethyltrisiloxane and a catalyst into a reactor under 35-65 DEG C, adding vinyl trimethoxysilane or vinyl triethoxysilane in drops, after the reaction, adding active carbon for adsorption processing, filtering, and distilling filtrate under a reduced pressure to obtain the hydrophobic-surface treatment agent. According to the invention, the 1,1,1,3,5,5,5-heptamethyltrisiloxane with high-activity silicon-hydrogen bonds and the vinyl silane with double bonds are used as raw materials, a high-yield hydrosilylation reaction is utilized, and the product is prepared by a one-step synthesis method. The agent is high in reaction activity of function groups, low in surface energy, mild and controllable in reaction conditions, high in product yield and low in production cost.