Industrial pure tin with resistance to liquid surface oxidizing and application
A surface oxidation, industrially pure technology, applied in the direction of manufacturing tools, metal processing equipment, welding media, etc., can solve the problems of inclusion pollution in the solder pool, poor welding, and easy adhesion of tin slag to the soldered joints, etc. , to achieve the effect of improving the antioxidant properties
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Embodiment 1
[0016] The industrial No. 1 tin is used as a raw material, and a trace element of 0.05% Ge (weight percentage, the same below) is added to prepare a liquid-resistant surface oxide tin. Take 100g sample and place it in a graphite crucible with a diameter of 20mm to heat and melt it, and heat it up to 250°C to keep it warm. After gently scraping off a layer of film on the surface with a scraper, observe the oxidation on the surface of the liquid metal melt. Just after scraping off the surface film, the liquid metal surface is very bright. It is convenient to estimate its anti-oxidation degree from the brightness of the metal liquid surface, because once the oxide film is formed, this bright liquid surface will disappear quickly. Through observation, it can be found that the tin added with the above trace elements is heated and kept warm for a long time in the atmosphere, and the surface of the molten tin can still remain bright. When kept at 250°C for 5 hours, the center of the ...
Embodiment 2
[0018] The composition of the prepared sample is 0.03% P, and the rest is industrial pure tin. The test method and procedure are the same as in Example 1. Keep warm at 250°C, the melt surface remains bright for a long time, after 5 hours of oxidation, the center of the liquid surface is still bright, there is a thin oxide film on the edge surface, and there is no further change in color, so the oxidation resistance of this sample is good .
Embodiment 3
[0020] The composition of the prepared sample is 0.05% Sb and 0.02% Ge, and the rest is industrial pure tin. The test method and procedure are the same as in Example 1. Keep warm at 250°C, the melt surface remains bright for a long time, after 5 hours of oxidation, the center of the liquid surface is still bright, there is a thin oxide film on the edge surface, and there is no further change in color, so the oxidation resistance of this sample is good .
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