Polypropylene resin composition for hot channel injecting formation and production thereof

A polypropylene resin, hot runner injection molding technology, applied in the field of hot runner injection molding, can solve the problems of difficult product brand conversion, poor processing fluidity, and reduced rigidity, so as to reduce melt anisotropy, improve strength and bending strength. Good results

Inactive Publication Date: 2005-07-27
洛阳石化吉润化工有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, foreign countries mainly use the same kind of special materials to be synthesized in the polymerization reactor. The initial investment of this process is huge, and the product grade conversion is difficult; the commonly used modification method in China is to simply blend the elastomer and polypropylene resin through simple blending, compatibilization blending, Reactive blending and other methods are used to toughen and modify polypropylene. However, while the toughness of the material is greatly improved, the processing fluidity of the material is significantly worse, and the rigidity (flexural modulus, tensile strength) is also significantly reduced.
There are even fewer reports on high fluidity and high toughness

Method used

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Examples

Experimental program
Comparison scheme
Effect test

specific Embodiment approach 2

[0025] Most of it is the same as Example 1, and the difference is that the raw material ratio is: homopolypropylene S820 930g; Ethylene-propylene rubber (EPDM) 31g, 3745P in the Norde1 IP series, superfine styrene-butadiene powder rubber Narpow VP101 31g; Nucleating agent Millad3988 2g; primary antioxidant Irganox1010 2g; secondary antioxidant Irgafos168 3g; rheology modifier Viton FreeFlow Z200 1g; screw speed 250 rpm, feeder speed 80 rpm.

[0026]Melt index MI: 18.1g / 10min; Tensile strength: 34.60MPa; Flexural strength: 33.9MPa; Flexural modulus: 1589MPa; Normal temperature notched impact strength: 80.05J / m; Longitudinal molding shrinkage: 1.03%, transverse molding Shrinkage, 0.93%, longitudinal molding shrinkage / transverse molding shrinkage 1.06.

[0027] While toughening and modifying polypropylene, the modified composition has significantly better processing flow properties than polypropylene base resin and other modified systems with similar composition ratios, and the m...

specific Embodiment approach 3

[0028] Most of it is the same as Example 1, except that the raw material ratio is: homopolypropylene S820 950g; ethylene-propylene rubber (EPDM) 21g, 3745P in the Nordel IP series, superfine styrene-butadiene powder rubber Narpow VP101 21g; Nucleating agent Millad3988 2g; main antioxidant Irganox1010 2g; secondary antioxidant Irgafos168 3g; rheology modifier Viton FreeFlow Z200 1g; screw speed 220 rpm, feeder speed 30 rpm.

[0029] Melt index MI: 19.3g / 10min; Tensile strength: 35MPa; Flexural strength: 38.3MPa; Flexural modulus: 1593MPa; Normal temperature notched impact strength: 77.2J / m; Longitudinal molding shrinkage: 1.02%, transverse molding shrinkage Rate, 0.95%, longitudinal molding shrinkage / transverse molding shrinkage 1.03.

[0030] While toughening and modifying polypropylene, the modified composition has significantly better processing flow properties than polypropylene base resin and other modified systems with similar composition ratios, and the melt flow rate is...

specific Embodiment approach 4

[0031] Most of it is the same as Example 1, and the difference is that the raw material ratio is: homopolypropylene S820 930g; Ethylene-propylene rubber (EPDM) 30g, 3745P in the Nordel IP series, superfine styrene-butadiene powder rubber Narpow VP101 28.5g; Nucleating agent Millad3988 2g; primary antioxidant Irganox1010 2.5g; secondary antioxidant Irgafos168 5g; rheology modifier Viton FreeFlow Z200 2g.

[0032] Melt index MI: 18.1g / 10min; Tensile strength: 34.9MPa; Flexural strength: 36.7MPa; Flexural modulus: 1571MPa; Normal temperature notched impact strength: 83.61J / m; Longitudinal molding shrinkage: 1.03%, transverse molding Shrinkage, 0.98%, longitudinal molding shrinkage / transverse molding shrinkage 1.04.

[0033] While toughening and modifying polypropylene, the modified composition has significantly better processing flow properties than polypropylene base resin and other modified systems with similar composition ratios, and the melt flow rate is stable; rigidity (fle...

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Abstract

A polypropylene resin composition for thermal runner injecting forming and its production are disclosed. The composition consists of polypropylene homopolymer 90-98 proportions, ternary rubber 1-5 proportions, super-thin butadiene styrene powdery rubber, nucleating agent 0.1-1 proportion, main antioxygen 0.1-0.25 proportion, assistant antioxygen 0.2-0.5 proportion, and rheological property improver 0.1-0.2. The production is carried out by mixing the matters for 3-5mins at normal temperature, adding into parallel double-screw extruder by feeder, and mixing and granulating. Its advantages include higher impact roughness, stretching intensity and rigidity.

Description

Technical field: [0001] The invention relates to the technical field of hot runner injection molding, in particular to a polypropylene resin composition for hot runner injection molding and a preparation method thereof. Background technique: [0002] With the development of the domestic home appliance industry and the increasing emphasis on environmental protection in the world, major refrigerator manufacturers have launched high-end air-cooled refrigerators that are competitive in the market and in line with international development trends. At the same time, the performance of polypropylene modified materials is increasing day by day and the status quo of gradually entering the field of engineering plastics makes polypropylene modified materials begin to replace traditional engineering plastics such as ABS in a wider range of applications. Among the plastic accessories in China, polypropylene accounts for a large proportion and is used for injection molding top covers, dra...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B29C45/03C08K5/524C08L23/12
Inventor 杨军忠郭丰平刘伟景振华王军王延伟孙春燕代振宇
Owner 洛阳石化吉润化工有限责任公司
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